溶胶-凝胶法制备复合材料用氧化铝基体及涂层研究

采用溶胶—凝胶法,分别研究了用三种起始物异丙醇铝［Ａｌ（ＯＣ３Ｈ７ｉ）３］、氯化铝（ＡｌＣｌ３·６Ｈ２Ｏ）、硝酸铝［Ａｌ（ＮＯ３）３·９Ｈ２Ｏ）］,制备碳纤维三维编织物增强复合材料用氧化铝基体及涂层的工艺,考察了三种体系反应物配比、水解温度、反应时间等因素对制得的三种溶胶体系性能的影响,获得了较佳的溶胶配制参数;还考察了三种溶胶体系在通常情况下和在编织物中的凝胶化情况,获得了较佳的凝胶化条件;同时还研究了不同条件下三种凝胶的裂解产物及其晶体类型。结果表明,不管经过何种途径,凝胶在经１２６０℃裂解后均可获得α－Ａｌ２Ｏ３。     

Microstructure and Properties of Low-pressure Cold Sprayed Al-based Composite Coatings on Magnesium Alloy Surface

Pure Al and Al-30% Al2O3 composite coatings are prepared on the surface of AZ31B magnesium alloy by low-pressure cold spraying. The morphology and structure of the coatings are analyzed by scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD), and the effects of the addition of Al2O3 on the microstructure of the Al-based coatings are discussed. The mechanical properties and corrosion resistance of the coatings are fully evaluated by the micro-hardness tester, electronic tensile machine, and electrochemical workstation. The results show that the coating structure is more uniform and denser, and the porosity is significantly reduced after the addition of Al2O3. The interfaces between the coatings and the magnesium alloy substrate are distinct, and the coatings and the substrate are mechanically combined. Compared with the pure Al coating, the microhardness of the Al-Al2O3 composite coating is increased to 61.1 HV0.2, and the bonding strength reaches above 53.1 MPa. The self-corrosion potential of the two coatings is higher than that of the magnesium alloy, and the self-corrosion current density is significantly lower than that of the magnesium alloy substrate. The Al-based coatings prepared by low-pressure cold spraying have high hardness, good bonding strength, and good corrosion resistance, which can be used for the repair and protection of magnesium alloy structural parts.     

波形垫圈自动装配的结构设计

波形垫圈由于其形状特点形如波浪,厚度薄且具有弹性,因此上料及准确装配到位有一定难度.为此介绍了装配此工件的上料及装配机构的工作原理,并给出了结构设计方案.实际应用表明,所设计的机械结构结构简单,成本低,实用性好.并且该设备调整方便,各运动环节都具有可调节机构,方便维修.     

Effects of Atomic Oxygen Irradiation on Transparent Conductive Oxide Thin Films

作为一种功能薄膜,透明导电氧化物(TCO)薄膜在飞行器的抗原子氧(AO)涂层和太阳能电池领域有着巨大的应用价值。ZnO:Al(ZAO)和In2O3:Sn(ITO)薄膜是目前研究和应用最广泛的TCO。本文对ITO薄膜和ZAO薄膜进行了不同通量的AO辐照。通过对辐照前后样品的X射线衍射、扫描电镜及霍耳效应的表征及测试,研究了AO辐照对这两种TCO薄膜的结构、性能及电学特性的影响。研究表明AO辐照对ZAO薄膜表面有明显的侵蚀作用,但对其结构和导电性能没有明显影响。对于ITO薄膜,随着AO通量的增大,其载流子浓度逐渐下降从而导致了电阻率的提高,电阻率的最大变化达到了21.7%。     

热障涂层用Dy2Zr2O7陶瓷粉末制备及其热物理性能研究

采用共沉淀-煅烧法制备了热障涂层用Dy2Zr2O7陶瓷粉末.通过电感耦合等离子体原子发射光谱(ICPAES)、X射线衍射,SEM,DSC及霍尔流速计等分析方法,对粉末的化学组成、相组成、微观结构、高温相稳定性和流动性能进行了研究.通过高温膨胀仪、DSC和激光热导仪分别测定其热膨胀系数、比热系数和导热系数.结果表明,所制备粉末的组成与锆酸镝氟石结构的组成相近;高温下Dy2Zr2O7无明显相变;在高于1400℃的温度下煅烧后,Dy2Zr2O7的流动性得到显著改善;Dy2Zr2O7具有比8YSZ更高的热膨胀系数和更低的导热系数.     

Effects of Different Molten-salt on the Synthesis of Hexagonal Barium Ferrite

Hexagonal-plate BaFe12O19 nano-particles were prepared by combining the co-precipitation and molten-salt method. The effects of molten-salt NaCl on the products have been compared with those of KCl. The X-ray diffraction analysis, the environment scanning electron microscopy and the vibrating sample magnetometer were used to measure their characteristics. The results show that the mol- ten-salt KCl is helpful to obtain pure phase while the molten-salt NaCl will prompt the crystallinity of particles to increase. It is also found that, given the molten-salt of NaCl and that of KCl of the same quantity, the particles formed are also the same size. The size of particles slightly increases as the quantity of the salt increases. Moreover, the sample prepared under 200% NaCl salt system has magnetization of 71.5 emu/g.     

Al2O3/YAG共晶自生复合陶瓷的激光熔凝实验研究

开展了Al2O3/YAG共晶自生复合陶瓷的激光熔凝制备技术的实验研究,研究结果表明(1)激光扫描速率与功率密度的匹配对激光熔凝实验起着决定性的作用.调整工艺参数,可以获得表面光滑、平整、致密的熔凝层,且无宏观孔隙及裂纹.随扫描速率的增大,熔凝层变薄;(2)激光熔凝Al2O3/YAG共晶自生复合陶瓷由Al2O3相和YAG相两相组成,具有典型的快凝层状共晶组织,共晶间距非常细小.     

一起主滑油泵消沫网出现金属异物的故障分析

针对某型发动机主滑油泵消沫网出现金属块异物这一故障,对滑油系统油路、金属块来源、保险锁爪断爪原因进行分析,提出了避免锁爪断裂的改进措施。     

基于DFL的拦截导弹非线性导引律研究

在研究拦截导弹质心运动特点以及考虑一些实际因素的情况下，建立了一种拦截导弹系统的二维简化运动模型，并给出了该模型的状态方程一般表达式。根据这一状态方程的表达形式，应用非线性系统的直接反馈线性化（DFL）理论，得出了一个导弹加速度的线性补偿律，并根据该线性补偿律和PN导引律，设计出了一种基于I／O描述和PN导引律综合的变结构控制律。本文的末尾给出了应用该综合控制律的一些仿真结果，这些仿真结果表明：该控制是拦截导弹导引的一种有效处理方法，所设计的系统具有良好的跟踪性能，具有一定的研究应用前景。     

GaN基白光LED电流加速老化特性研究

本文对三组Al2O3衬底上生长GaN基蓝光激发黄色荧光粉的白光LED进行了对比电流加速老化实验,老化电流分别是30 mA5、0 mA和70 mA。随着老化电流的增大,GaN基白光LED的光输出功率随时间的衰减速率相对较快;随老化时间的加长,30 mA电流驱动下,GaN基白光LED相对光谱中黄光比重先增加再减小。其原因归结为荧光粉受热降解导致转换量子效率降低和荧光粉本身对短波长的光散射共同作用的结果。最后计算出用于实验的白光LED寿命为457 h。