新型环氧树脂潜伏性促进剂的合成、表征及性能研究

合成了新型环氧树脂潜伏性促进剂三(乙酰乙酸十八酯)铝,采用DSC,FT-IR,H-NMR、元素分析分别对其热分解机理、化学结构、物质纯度进行了表征.研究了以环氧ZH92-21∶双酚S∶三(乙酰乙酸十八酯)铝=l00∶3∶0.5为配比的树脂体系的固化制度、潜伏性和力学性能,树脂体系的表观粘度在室温储藏7个月后基本没有变化,相分离是其具有优异潜伏性的主要原因.     

三氢化铝的合成及性能研究

采用LiAlH4还原AlCl3的方法制备了AlH3,产品的产率大于90%。采用不同的稳定剂对合成的样品进行了稳定化处理,将经处理的样品通过在70℃进行放气量测试比较了热稳定性,发现经稀酸处理的AlH3样品稳定性最好。研究了AlH的安全性能,并通过DSC法研究了AlH与常用推进剂组分的相容性。     

基于模糊机会约束规划的机会阵雷达方向图综合

针对机会阵雷达方向图综合的不确定问题,提出了一种基于模糊机会约束规划的方向图综合规划模型。该模型基于可信性理论,综合考虑天线单元分布的随机性以及激励状态的不确定性,将参与方向图综合时激励打开的天线数目看做一个梯形模糊变量,用以描述综合时的复杂不确定环境。随后,将规划模型转化为清晰等价形式,再结合遗传算法和灰关联综合评价法则设计了一种混合智能优化算法,用于求解该模型。以一维任意非均匀线阵为例,对主瓣宽度和最大副瓣电平进行了优化。仿真表明:优化后结果的可信性高于置信水平,验证了该算法的有效性。     

波形合成的方向处理

波形合成中方向问题的核心是相位计算。本文作了分析     

弹性飞行器敏感元件位置设置与参数优化综合

本文研究了弹性飞行器敏感元件位置的设置问题，分析了敏感元件位置对弹性飞行器稳定性的影响，提出了几类飞行器自动驾驶仪敏感元件可能合适位置的选择准则。从飞行器弹性振动闭环系统方程出发研究了弹性飞行器参数优化综合的某些方法。通过算例得到控制系统返馈系数，陀螺位置，舵面位置优化综合的数值模拟结果。这些结果与该飞行器实际采用的值符合较好。     

模具约束条件对H96黄铜双脊矩形管E弯截面变形的影响

 双脊矩形管的绕弯成形受内外侧模具的共同约束,不同模具约束下管坯的受力不同,使得其截面变形情况也不相同,而截面变形严重地影响弯管件的成形质量和使用性能。因此,基于ABAQUS有限元平台建立了双脊矩形管E弯成形三维有限元模型,并通过实验验证了模型的可靠性。采用所建模型,研究了内外侧模具约束条件对双脊矩形管E弯截面变形的影响规律,发现当只有内腹板脊槽受约束时,内腹板脊槽的内缩变形可得到较好的控制,而其他部位的变形则有增大的趋势;当只有外腹板脊槽受约束时,内腹板脊槽宽度变形基本不发生变化,而其他部位的变形则有减小的趋势;当内外腹板脊槽均受约束时,可较好地控制双脊矩形管E弯过程中的截面变形。芯头个数对整管截面高度、宽度、外腹板脊槽宽度与两脊槽底部的间距的变形影响较大,但对内腹板脊槽宽度的变形影响不显著。     

酚醛树脂炭的合成及力学性能研究

为了表征多孔炭泡沫材料基体的结构与力学性能,采用碱催化法制备热固性酚醛树脂,经固化、高温炭化处理合成多孔炭泡沫材料的基体——酚醛树脂炭。研究酚醛树脂炭的微观结构、压缩强度及压缩断裂韧性。结果表明:酚醛树脂炭结构以树脂炭基体、微孔和微裂纹为主,其碳元素以sp3杂化的非晶炭形式存在;压缩强度为8.58 MPa,压缩断裂特征为脆性断裂模式;酚醛树脂炭的压缩断裂韧性较差,断裂过程中吸收的总能量为0.135 MJ/m3。     

NiAl合金的热爆合成及其反应机制

本文研究了NiAl合金的热爆合成,其反应过程为液相控制,产物为β-NiAl,密度较高。本文给出了不同条件下合成的起爆时间及主要影响因素。     

Comparison of vertical E × B drift velocities and ground-based magnetometer observations of DELTA H in the low latitude under geomagnetically disturbed conditions

In the present work, we analyzed the daytime vertical E × B drift velocities obtained from Jicamarca Unattended Long-term Ionosphere Atmosphere (JULIA) radar and ΔH component of geomagnetic field measured as the difference between the magnitudes of the horizontal (H) components between two magnetometers deployed at two different locations Jicamarca, and Piura in Peru for 22 geomagnetically disturbed events in which either SC has occurred or Dst_max < ?50 nT during the period 2006–2011. The ΔH component of geomagnetic field is measured as the differences in the magnitudes of horizontal H component between magnetometer placed directly on the magnetic equator and one displaced 6–9° away. It will provide a direct measure of the daytime electrojet current, due to the eastward electric field. This will in turn gives the magnitude of vertical E × B drift velocity in the F region. A positive correlation exists between peak values of daytime vertical E × B drift velocity and peak value of ΔH for the three consecutive days of the events. It was observed that 45% of the events have daytime vertical E × B drift velocity peak in the magnitude range 10–20 m/s and 20–30 m/s and 20% have peak ΔH in the magnitude range 50–60 nT and 80–90 nT. It was observed that the time of occurrence of the peak value of both the vertical E × B drift velocity and the ΔH have a maximum (40%) probability in the same time range 11:00–13:00 LT. We also investigated the correlation between E × B drift velocity and D_st index and the correlation between delta H and D_st index. A strong positive correlation is found between E × B drift and D_st index as well as between delta H and D_st Index. Three different techniques of data analysis – linear, polynomial (order 2), and polynomial (order 3) regression analysis were considered. The regression parameters in all the three cases were calculated using the Least Square Method (LSM), using the daytime vertical E × B drift velocity and ΔH. A formula was developed which indicates the relationship between daytime vertical E × B drift velocity and ΔH, for the disturbed periods. The E × B drift velocity was then evaluated using the formulae thus found for the three regression analysis and validated for the ‘disturbed periods’ of 3 selected events. The E × B drift velocities estimated by the three regression analysis have a fairly good agreement with JULIA radar observed values under different seasons and solar activity conditions. Root Mean Square (RMS) errors calculated for each case suggest that polynomial (order 3) regression analysis provides a better agreement with the observations from among the three.     

三芳基均三氮杂苯环（TSTR）耐高温树脂的研究

从制备最主要的原材料入手,研究了ＴＳＴＲ树脂的合成,并对树脂进行了红外光谱分析（ＩＲ）以及差示扫描量热法（ＤＳＣ）和热重量分析法（ＴＧＡ）等热分析,其中４－氰基苯酐的一步合成法已申请了国家专利。试验结果表明：该树脂的最高工作温度可达４００℃,接近美国先进的ＰＭＲ－Ⅱ－５０ 高温树脂的工作温度。