基于湿热环境下的碳纤维复合材料力学性能研究及老化寿命预测

对T700/TDE-86碳纤维复合材料开展人工加速湿热老化试验,通过对比分析复合材料老化前后剖面形貌和物理化学特性,探讨了复合材料的吸湿扩散行为,研究了复合材料力学性能演变规律;并构建剩余强度计算模型,结合环境系数预测了湿热环境下复合材料的老化寿命。结果表明：复合材料吸湿率随老化时间延长而逐渐增大直至趋于平缓,符合Fick扩散定律;相对于未进行湿热老化的复合材料,经60℃、95%RH湿热环境老化后的复合材料各力学性能均有所下降,其中剪切强度最为严重,老化64 d后其强度下降率高达25%;基于剩余强度与环境系数预估的T700/TDE-86碳纤维复合材料寿命期限约为30年,为树脂基复合材料未来服役可靠性奠定了基础。     

褶皱对碳纤维复合材料层合板压缩性能的影响

为研究纤维褶皱对碳纤维复合材料层合板压缩性能的影响,参考ASTM D6641—2014完成了含纤维褶皱碳纤维层合板压缩性能试验;同时采用基于Hashin失效准则及性能逐渐退化的渐进损伤方法进行了有限元分析。结果表明：褶皱程度为30%的凹陷试验件压缩极限载荷相比完好试验件降低了58.48%;同等褶皱程度下凹陷试验件比凸起试验件抗压强度更低;褶皱程度为30%的凹陷试验件刚度相比完好试验件降低了35.80%;有限元分析结果与试验吻合良好,试验件的损伤最初为基体损伤,经过扩展导致试验件在褶皱处断裂。     

Machining of SiC ceramic matrix composites: A review

Continuous fiber reinforced SiC ceramic matrix composites (FRCMCs-SiC) are currently the preferred material for hot section components, safety–critical components and braking components (in the aerospace, energy, transportation) with high value, and have triggered the demand for machining. However, the high brittleness, anisotropy, and heterogeneity of materials bring great challenges to machining, due to high mechanical and thermal loads, severe tool wear, and poor machining quality. With the increasing demand of FRCMCs-SiC parts, high-quality and high-efficient machining has become a hot issue. This review paper provides a detailed literature survey on the machining of FRCMCs-SiC. The material removal mechanism, defect form, and interfacial mechanical properties of FRCMCs-SiC were summarized. The machining processes of FRCMCs-SiC were introduced, and their respective advantages and disadvantages were compared. Given the low machinability (high hardness, high brittleness, anisotropy, and heterogeneity) of FRCMCs-SiC, preliminary experiments have proved that ultrasonic-assisted machining and laser-assisted machining have shown unique advantages in reducing force and tool wear, improving machining quality and machining efficiency. The machined surface integrity was discussed, the influence of process parameters on the machined surface quality was analyzed, and the machining defects of FRCMCs-SiC were summarized. But for FRCMCs-SiC, the existing quantitative evaluation of the machined surface integrity was weak and unsystematic.     

复合材料不同截面空心柱体压溃吸能特性研究

对圆形截面和正六边形截面碳纤维复合材料空心柱体的压溃吸能特性优劣进行研究。以约束相同质量、相同铺层的方式,分别研究单胞及按蜂窝阵列排列多胞结构2种情况下的吸能特性,并通过 ANSYS 有限元分析及实物试验辅证,得出相同铺层方式不同截面的复合材料空心柱体性能优劣。单胞结构性能结果为,圆截面单胞空心柱体的压溃吸能效果优于正六边形截面的效果:按蜂窝阵列排列多胞结构性能结果为,正六边形截面蜂窝结构压溃吸能能力优于圆截面类蜂窝结构。     

陶瓷基复合材料高精度宏细观统一本构模型研究

基于高精度通用单胞模型(HFGMC)建立了陶瓷基复合材料(CMCs)的宏细观统一本构模型.首先基于CMCs的细观结构和损伤特点建立代表体元(RVE)并定义细观损伤变量.然后采用HFGMC模型计算细观损伤变量的演化,由此获得宏观应力应变曲线,从而建立了CMCs的宏细观统一本构模型.采用该本构模型预测了CMCs的宏观应力应变曲线,与实验结果吻合良好.结果表明该本构模型能够模拟CMCs的拉伸与损伤行文,为CMCs强度分析提供了有效手段.      

纤维增强塑料拉挤型材弯曲强度研究

研究了纤维增强塑料 ( FRP)拉挤型材的弯曲强度。试验结果表明 ,FRP拉挤型材在大跨距 (跨高比 l/h>1 0 )下的弯曲破坏模式通常是梁的纵向开裂 ;FRP拉挤型材由于剪切变形较大 ,强度计算时不能按普通各向同性梁理论进行计算 ,应考虑剪切变形的影响。为此 ,本文应用复合材料薄壁梁理论给出了 FRP拉挤型材在大跨距下弯曲强度计算的半经验公式     

多胺－硫脲缩聚物改性环氧固化体系的研究

主要研究了多胺－硫脲缩聚物对环氧－聚酰胺固化体系的促进作用。通过示差扫描量热，对改性前后固化反应动力学多种参数进行了计算，说明了这种增强作用是由于多胺－硫脲缩聚物的加入使体系动力学反应的前置因子和反应速率常数大幅度提高。在此基础上研制的环氧树脂／聚酰胺／缩聚物胶粘剂具有高强度，高耐湿热性，室温下可快速固化的特点。     

Thermo-mechanical properties of RTM-made carbon fibre/polyimide composite attaching collar under transient heating

This study focuses on the thermo-mechanical properties of Carbon Fibre/Polyimide Composite (CFPC) attaching collars under transient heating. The CFPC attaching collars were fabricated by a high-temperature resin transfer moulding process, and their thermo-mechanical properties under the conditions of simultaneous transient heating and bending load were investigated. The results show that the attaching collar tends to fail at 118% of the limit load. The failure mode includes the fracture of the connecting screws, local extrusion damage of the hole edges, and slight ablation damage at the outer plies. And there is no observable residual deformation in the composite attaching collar. Furthermore, considering that the material properties vary with temperature, a progressive damage model based on the sequential thermo-mechanical coupling method was established to study the failure mechanism of the attaching collar. Finally, the damage factor of the CFPC was calculated to assess the safety status of the attaching collar. The results show that the primary damage modes of the composite attaching collar are intralaminar failure, which mainly occurs at the heat insulation layer and the hole edges, and these slightly affect the structural bearing capacity. A good correlation between the experiment and FEA is obtained. The test methods and analysis models proposed contribute to the safety assessment of composite structures under transient heating.     

Interconnected Ni（OH）2 and polyether amine on carbon fiber surface for simultaneously improving interfacial adhesion of epoxy composites and electrochemical properties

Interconnected Ni（OH）₂ nanoflakes and polyether amine（PEA） were deposited on carbon fiber tows via a facial and effective process of chemical bath deposition and dip coating. Based on this, a win–win benefit of simultaneously improvements in interfacial shear strength（IFSS） of carbon fiber/epoxy composites and the electrochemical activity has been achieved. Compared with CF and CF-Ni（OH）₂ composites, the IFSS of CF-Ni（OH）₂-PEA/epoxy composite respectively increas...     

(TiB+TiC)/TC4复合材料电解钻孔试验研究

钛基复合材料是一种典型的难加工材料,采用传统机械加工方法存在加工效率低和加工质量差等问题。利用电解加工技术,采用直径为10mm的管状阴极,对(TiB+TiC)/TC4复合材料进行电解钻孔加工试验研究。进行了(TiB+TiC)/TC4复合材料的电化学特性研究,测量了(TiB+TiC)/TC4复合材料在10%NaNO₃溶液中的极化曲线和电流效率。探究了加工电压、电解液压力对加工精度的影响。结果表明,当加工电压为30V,电解液压力为0.6MPa时,电解钻孔可以在1mm/min的进给速度下稳定加工。当加工的盲孔深径比为3.06时,孔的圆度误差为41.1μm,锥度为0.4°,具有较高的加工精度。