3Y-ZrO2／Al2O3细晶复相陶瓷涡轮盘的超塑挤压

以高纯氧化铝(Al2O3)和氧化锆(3Y-ZrO2)粉末为原料,在1450℃下通过真空热压烧结制备3Y-ZrO2/Al2O3细晶复相陶瓷致密块料,随后在1500~1650℃温度范围内进行涡轮盘模拟件的超塑挤压。结果显示,3Y-ZrO2/Al2O3陶瓷在1600℃具有最佳挤压性能,最大单位挤压力小于25MPa,最大压头速率达到0.14mm.min-1,成形件质量良好,无明显缺陷。与变形前相比,尽管材料晶粒明显粗化,但是致密度有很大提高,断口SEM显示主要以穿晶断裂方式为主,所以成形件的弯曲强度、断裂韧度和维氏硬度并没有出现大的变化,甚至盘片部位还有所提高,分别由变形前的573MPa,7.1MPa.m1/2和17.7GPa提高到617MPa,8.1 MPa.m1/2和18.8GPa。     

巨磁电阻材料La1—xZnxMnO3化合物的制备工艺及其结构研究

对巨磁电阻材料La1-xZnxMnO3(x=0.1,0.3,0.5,0.7,0.9,1.0)样品的制备工艺、晶体结构、微观结构进行研究。结果表明,样品ZnO与MnO2固相反应的烧结温度和时间分别大于1300℃和6h时,反应生成具有四面体结构的ZnMnO3化合物;压制成型的压力对结构具有一定影响;不同浓度的Zn2 (x=0.1,0.3,0.5,0.7,0.9)掺杂样品在1350℃烧结12h后,均具有钙钛矿结构,但掺杂浓度在大于x=0.5时有新的衍射峰,产生新的物相,从而影响巨磁电阻效应性能。     

二次流喷射位置对流体推力矢量喷管气动性能影响的数值模拟

数值模拟了二次流喷射位置对基于激波控制的二维收-扩(2DCD)喷管的流体推力矢量气动性能,结果表明喷射位置对矢量角有较大影响,在喷管落压比NPR=4.5时,二次流喷射位置相对位于喷管发散段中部时,矢量角最大;在NPR≥7.2时,二次流喷射位置越靠近出口,矢量角越大.喷射位置对推力系数及流量系数的影响不大.      

镍掺杂对α-Al2O3烧结过程、微观结构及力学性能的影响

 首先采用非均相沉淀包裹法制备金属镍包裹α-Al₂O₃复合微球粉体,然后采用热压烧结制备了Al₂O₃/Ni金属陶瓷。通过X射线衍射仪（XRD）、扫描电子显微镜（SEM）、能谱仪（EDS）对复合粉体及热压烧结产物的成分和结构进行了表征,利用阿基米德法测量了复合陶瓷的密度,分别通过三点弯曲法和单边切口横梁法对陶瓷试条的抗弯强度和断裂韧性进行评估。研究发现：金属镍的引入活化了α-Al₂O₃的烧结,镍粒子均匀地分布在氧化铝的晶界上,增加了弱界面,提高了氧化铝的断裂韧性,最高可达7.62 MPa·m^1/2。     

SiC含量对Ti_3SiC_2/SiC复合材料性能的影响

采用反应热压烧结法制备了Ti3SiC2/SiC复合材料,针对SiC含量对该复合材料致密化程度、力学性能以及应力.应变行为的影响进行了研究.结果表明:(1)随着SiC含最的增加,试样难于致密,试样需要在更高的温度才能达到较高的致密度;(2)随SiC含量的增加,Ti3SiC2/SiC复合材料弯曲强度和断裂韧性提高,但SiC含量达到50%时,由于复合材料含有较多的孔洞,使强度和断裂韧性降低;(3)Ti3SiC2/SiC复合材料在常温下表现为非脆性断裂.     

热障涂层用La2Zr2O7粉末研究进展

介绍了La2Zr2O7的结构及作为热障涂层材料的热力学性能;综述了国内外制备La2Zr2O7粉末的方法及其工艺对产物性能的影响;论述了La2Zr2O7用作热障涂层的优缺点和有待解决的问题.     

TiC／Ti3AlC2复合材料的原位合成

以Ti粉、铝粉和活性碳粉为反应原料,利用高能球磨及热压工艺合成了TiC/Ti3AlC2复合材料.研究了在Ti-Al-C体系中,温度对TiC/Ti3AlC2复合材料的影响,并重点分析了反应过程热力学机理及材料微结构的影响.结果表明:通过高能球磨及热压烧结,在1 300℃时得到了物相比较均匀、致密的TiC/Ti3AlC2复合材料.通过高能球磨使得晶粒不断得到细化,使Ti3AlC2的烧结温度降低,同时分析TiC/Ti3AlC2复合材料微观结构的增韧机理,发现TiC是以颗粒增韧方式镶嵌在Ti3AlC2基体中.     

火箭助推器对雷达观测的影响研究

针对运载火箭二级助推器及分离时产生的大的碎片对雷达观测可能造成的影响,阐述了雷达成像重叠轨道(ROIO)的概念,并就雷达处于火箭载荷轨道平面内的情况分析了ROIO的存在条件、确定方法和观测中火箭载荷轨道及其ROIO上所对应的位置相对于雷达的角度差.仿真结果表明,目标轨道的观测范围及雷达相对于该观测范围的距离决定了ROIO的确定.     

Preparation of SiC_p/Al_2O_3-Al Composites by Directed Metal Oxidation

SiCp/Al2O3-Al composites were synthesized by means of direct metal oxidation method. The composition and microstructures of the composites were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) and metallurgical microscope. The effects of technical parameters on the properties of the product were analyzed. The results indicate that the composite possesses a dense microstructure, composed of three interpenetrated phases. Of them, SiO2 layer prohibits the powdering of the composites; Mg promotes the wetting and infiltration of the system and Si restricts the interfacial reaction while improving the wetting ability between reinforcement and matrix.     

Preparation and Mechanical Properties of Glass Coats with High Temperature Radar Absorber

BaO-La2O3-B2O3 （BLB） glass, suitable to be used as a sealing between metals, was chosen to be the binder in preparing glass coats on the Ti-alloy substrate. The SiCN nano-powder was introduced as the filler for the absorbing coat because it is considered to be a good high temperature absorber. The effect of the coating temperature and coating time on the tensile strength of the glass coat was investigated and the proper coating parameters to get good mechanical properties were determined. In addition, the effects of the SiCN content on the tensile strength of the absorbing coat were also discussed. Results show that it is possible to prepare the glass coat using the BLB glass as a binder. That the coat formed at 730℃ for 30 min has the best tensile strength witnesses 730 ℃, 30 min to be the proper parameter to prepare the glass coat. The BLB glass coat without SiCN powder possesses good tensile strength and the introduction of the SiCN absorber into the glass coat will lower the tensile strength. As the SiCN content increases, the tensile strength of the absorbing coat decreases, which could be attributed to the aggregation of SiCN in the coats.