电化学浸渍液乙醇中铜铁镁含量的测试技术

运用空气-乙炔火焰原子吸收光谱法进行电化学浸渍液乙醇中铜、铁、镁含量的连续测试。介绍了铜、铁、镁最佳测定条件及呈良好线性范围的浓度。同时对样品消化处理条件及在测定中样品的干扰因素进行了综合考虑,该方法具有很好的灵敏度、很好的复现性。同时具有方法步骤简单、操作容易掌握等特点,对样品铜、铁、镁含量的连续测试,其相对标准偏差均小于1.0％(n=10);标准加入回收率均在97.0％-102.0％(n=6)范围内。     

事故车辆油漆物证分析-比对系统的建立

在已建立的事故车辆物理信息和光谱信息的油漆样本数据库的基础上,建立油漆物证比对系统。根据相关系数所表现的特征,实现对未知样本属性范围的确定,找出数据库中与其相关度较高的部分油漆样本,再根据数据库中同一车辆信息具有同一序号的特点,找出与油漆对应的车辆,即与案件现场最接近的嫌疑车辆,为肇事逃逸案件的破获提供数据依据。     

Ionospheric and geomagnetic Pc5 oscillations as observed by the ionosonde and magnetometer at Sodankylä

The study is based on the data of the rapid-run ionosonde at the Sodankylä Geophysical Observatory at auroral latitude (L?=?5.25) which routinely performs one-minute sounding since 2007. This dataset allows a unique opportunity for investigating possible effects of ultra-low frequency (ULF, 1–7?mHz) waves in the auroral ionosphere. Suitable observations were made during moderately disturbed geomagnetic conditions typically at recovery of the geomagnetic storms caused by solar wind high-speed streams, in the daytime between 9 and 16 MLT. The ionospheric oscillations corresponding to Pc5 geomagnetic pulsations were found in variations of the virtual height of the F layer and the power of ionosonde reflections from E and F layers. The later are most probably caused by modulation of electron precipitation, which is also manifested in weak (about 0.01–0.06?dB) variations of cosmic noise absorption. The most important and novel result is that the pulsations of power of reflection from E and F layers typically has a spectral maximum at nearly half the periodicity of the Pc5 geomagnetic pulsations, whereas such spectral peak is negligible in the geomagnetic pulsations.     

Exploration life support technology challenges for the Crew Exploration Vehicle and future human missions

As NASA implements the U.S. Space Exploration Policy, life support systems must be provided for an expanding sequence of exploration missions. NASA has implemented effective life support for Apollo, the Space Shuttle, and the International Space Station (ISS) and continues to develop advanced systems. This paper provides an overview of life support requirements, previously implemented systems, and new technologies being developed by the Exploration Life Support Project for the Orion Crew Exploration Vehicle (CEV) and Lunar Outpost and future Mars missions. The two contrasting practical approaches to providing space life support are (1) open loop direct supply of atmosphere, water, and food, and (2) physicochemical regeneration of air and water with direct supply of food. Open loop direct supply of air and water is cost effective for short missions, but recycling oxygen and water saves costly launch mass on longer missions. Because of the short CEV mission durations, the CEV life support system will be open loop as in Apollo and Space Shuttle. New life support technologies for CEV that address identified shortcomings of existing systems are discussed. Because both ISS and Lunar Outpost have a planned 10-year operational life, the Lunar Outpost life support system should be regenerative like that for ISS and it could utilize technologies similar to ISS. The Lunar Outpost life support system, however, should be extensively redesigned to reduce mass, power, and volume, to improve reliability and incorporate lessons learned, and to take advantage of technology advances over the last 20 years. The Lunar Outpost design could also take advantage of partial gravity and lunar resources.     

原子氧对红外干扰材料消光性能的影响研究

为探索大气中的红外干扰材料可否应用于外层空间, 利用原子氧效应地面模拟装置对铜粉和石墨粉两种红外干扰材料样品进行了原子氧暴露实验, 并对样品进行了质量分析、XRD分析和红外透过率测试. 结果表明, 原子氧累积通量达到5.0×1019cm-2时, 铜粉样品质量增加0.004mg•cm-2,石墨粉样品质量损失0.117mg•cm-2; 原子氧暴露后, 铜粉对3~5μm与8~12μm红外质量消光系数由3.64 m2•g-1与2.74 m2•g-1变为3.14 m2•g-1与2.65 m2•g-1, 消光能力降低; 石墨粉对3~5μm和8~12μm红外的质量消光系数由6.54 m2•g-1和5.78 m2•g-1减小为2.38 m2•g-1和2.27 m2•g-1, 消光能力明显减弱.      

W 型钡铁氧体的研究进展

W型钡铁氧体具有吸波性能好、价格低廉的特点,因此,越来越引起广泛的重视和深入的研究。本文介绍了W型钡铁氧体BaMe2Fe16O27的主要制备方法,总结了Me为不同元素以及稀土离子掺杂时W型钡铁氧体的研究现状,展望了W型钡铁氧体未来的研究方向。     

系列嵌套圆环系统的能量吸收特性

能量吸收结构的性能对航空、航天等领域的人员和结构防护非常重要。针对一种系列嵌套圆环系统的能量吸收特性进行了理论、数值和实验研究。首先建立了考虑应变强化效应的系列嵌套圆环系统受刚性平板横向准静态压缩时的刚塑性理论模型;然后对双环和三环嵌套圆环系统进行了准静态压缩实验及有限元数值模拟,理论预测、数值模拟和实验测得的系列嵌套圆环系统的载荷-挠度曲线吻合很好;最后对将系列嵌套圆环系统应用到航空领域进行了探讨,以应用至航空座椅为例,建立了人体、座椅、能量吸收结构的数学模型,参照美国航空联邦局航空座椅动态实验标准,基于该模型计算得到了人体所受的腰椎负荷,并与不装备能量吸收结构时的腰椎负荷进行了比较,结果表明应用系列嵌套圆环系统可以有效地对人体进行防护。     

Anomalies in radiation-collisional kinetics of Rydberg atoms induced by the effects of dynamical chaos and the double Stark resonance

Radiative and collisional constants of excited atoms contain the matrix elements of the dipole transitions and when they are blocked one can expect occurring a number of interesting phenomena in radiation-collisional kinetics. In recent astrophysical studies of IR emission spectra it was revealed a gap in the radiation emitted by Rydberg atoms (RA  ) with values of the principal quantum number of n≈10$n\approx 10$. Under the presence of external electric fields a rearrangement of RA emission spectra is possible to associate with manifestations of the Stark effect. The threshold for electric field ionization of RA   is E≈3·10⁴$E\approx 3·{10}^4$ V/cm for states with n>10$n>10$. This means that the emission of RA   with n≥10$n\ge 10$ is effectively blocked for such fields. In the region of lower electric field intensities the double Stark resonance (or Förster resonance) becomes a key player. On this basis it is established the fact that the static magnetic or electric fields may strongly affect the radiative constants of optical transitions in the vicinity of the Föster resonance resulting, for instance, in an order of magnitude reduction of the intensity in some lines. Then, it is shown in this work that in the atmospheres of celestial objects lifetimes of comparatively long-lived RA states and intensities of corresponding radiative transitions can be associated with the effects of dynamic chaos via collisional ionization. The Föster resonance allows us to manipulate the random walk of the Rydberg electron (RE) in the manifold of quantum levels and hence change the excitation energies of RA, which lead to anomalies in the IR spectra.     

核电站工作场所中子能谱和周围剂量当量率测量

中子周围剂量当量是核电站辐射防护监测的主要对象之一,而中子周围剂量当量的评估强烈依赖中子的能量分布。利用自制的多球谱仪对秦山第三核电有限公司（TQNPC）重水反应堆安全壳内5个位置的中子能谱和周围剂量当量率进行了测量。该谱仪由1个³He正比计数器以及9个2.5～12英寸不同直径的聚乙烯球组成,响应函数通过MCNP程序计算,并利用标准²⁵²Cf中子源进行了校准和验证。通过测量的中子能谱,获得了不同工作区域的中子周围剂量当量率及其能量分布,并与中子周围剂量当量率仪和CR-39径迹蚀刻探测器的测量结果进行了比较,为核电站中子剂量的监测提供了相关参考数据。     

紫外成像光谱仪主动热控系统的设计与实现

为了确保紫外临边成像光谱仪的温度水平和温度梯度满足指标要求,分析了其所处空间环境并结合其光机电的特点,设计了整机的主动热控方案和被动热控方案。首先,总结了成像光谱仪热设计的基本原则,介绍了主动热控方案和被动热控方案。接着,利用最坏情况分析法分析了主动热控系统测温电路的测温精度。然后,根据主动热控方案的要求,对主动热控系统的硬件和热控策略进行了设计和实现。最后,规划了主动热控系统的验证试验,并对主动热控系统进行了试验验证。分析和实验结果表明：主动热控系统的测温精度满足≤±0.5℃的指标要求,主动热控系统能够保证紫外临边光谱仪13℃～18℃以及紫外环形成像仪8℃～18℃的温度水平要求,主动热控方案合理、可行,满足高可靠性的要求。