金属材料与玄武岩微纤维隔热材料接触腐蚀与防护研究

研究飞机使用的玄武岩微纤维隔热材料在潮湿环境下对机体内部铝合金、结构钢、不锈钢、钛合金等金属材料的接触腐蚀性能影响,考察化学氧化和氯化铵镀镉等金属表面处理工艺控制接触腐蚀的有效性.通过对铝合金、结构钢等金属接触腐蚀表面的EDS成分分析和SEM微观形貌分析,探讨金属材料与玄武岩微纤维隔热材料接触腐蚀的原因.     

组织类型对钛合金损伤容限性能的影响及电镜原位观察

采用扫描电镜(SEM)原位拉伸、原位疲劳方法研究TA15钛合金三种类型组织的裂纹尖端形状和疲劳裂纹扩展速率及扩展过程,并与宏观力学性能对比.结果表明,片状组织由于裂尖钝化、裂纹扩展路径曲折及分枝,损伤容限性能比等轴、双态组织好,即断裂韧性最高,疲劳裂纹扩展速率最低.     

用一种新型焊丝焊接TC18钛合金的接头性能与组织研究

对采用研制的焊丝和采用TC18同质焊材钨极氩弧焊焊接TC18钛合金的接头力学性能及微观组织进行了对比研究,结果表明:采用同质焊材焊接TC18钛合金只能保证接头的强度指标,而采用研制的新型焊丝焊接TC18钛合金,可以保证接头具有优良的综合力学性能.     

铝合金与橡胶软油箱抗老化涂层接触腐蚀机理研究

通过对7A04-T6包铝合金及去包铝合金与三种橡胶抗老化涂层材料在高温、高湿环境中的接触腐蚀产物SEM形貌分析及EDS成分分析,表明铝合金与橡胶抗老化涂层接触腐蚀形貌特征为点蚀,腐蚀严重时试样表面局部或全部被大量腐蚀产物所覆盖,腐蚀产物的主要元素为Al,C,O,Mg,Zn,Cl,Si,S.提出了铝合金与橡胶抗老化涂层"接触-扩散-吸附/沉积物层与电解质薄液膜层形成/腐蚀闭塞区形成/阴离子加速自催化腐蚀/点蚀-晶间腐蚀-剥落腐蚀"的接触腐蚀过程及机理.     

腐蚀条件下铝合金疲劳裂纹扩展试验及模型

进行2024-T3铝合金标准中心裂纹拉伸试件4种典型环境下的裂纹扩展试验,以试验数据为基础,通过对一般环境下的裂纹扩展模型进行修正,建立腐蚀环境下的裂纹扩展模型.对试验结果的分析处理表明,该模型能够很好描述各种典型腐蚀环境下裂纹稳定扩展阶段的裂纹扩展速率,能够较准确估算裂纹扩展寿命,腐蚀修正系数清楚地反映腐蚀影响的程度.通过对单一介质环境腐蚀修正系数的加权组合,模型可以推广应用于复杂环境下裂纹扩展分析.该模型便于充分利用现有材料裂纹扩展性能的数据.     

01420铝锂合金的搅拌摩擦焊接

对2 mm厚的01420铝锂合金薄板实现了搅拌摩擦焊接(FSW),分析焊接接头的微观组织形态,研究焊接工艺参数对搅拌摩擦焊接接头成型和接头性能的影响,并与氩弧焊接接头性能相比较.结果表明,当工艺参数选取得当时,焊缝成型较好,表面光洁,焊接接头的强度可达到母材强度的77%,接头的弯曲角可达到180°,均高于氩弧焊接接头.     

固体颗粒冲蚀对钛合金ZrN涂层抗冲蚀性能的影响

采用真空电弧镀在TC11钛合金上沉积ZrN涂层,固体颗粒冲蚀实验研究不同冲蚀颗粒、冲蚀速度、冲蚀角度对涂层抗冲蚀性能的影响,并用SEM观察表面及断面形貌.结果表明,在相同冲蚀条件下,ZrN涂层冲蚀率随冲蚀颗粒硬度、冲击角度及冲蚀颗粒速度的增加而增加,冲蚀角度为90°时,ZrN涂层冲蚀速率最大,ZrN涂层提高了TC11钛合金的抗冲蚀性能.     

Electrolytic Passivation of Nitinol Shape Memory Alloy in Different Electrolytes

The corrosion behavior of the nitinol alloy was studied in various corrosion media of different Cl–ion concentrations. The results demonstrate that the Cl–ion concentration has significant influences on the corrosion behavior of the nitinol alloy. In order to enhance the corrosion resistance, protective films were generated on the surface of the nitinol alloy by means of the electrochemical passivation method, for which five different electrolytic solutions were investigated. The surface analysis indicates full growth of all samples pas-sivated in the different electrolytic solutions with layers, however, showing different morphological features. Without any defects like micro-cracks and pores, the surface of the samples passivated in the molybdate solution turns out smoother and denser than those pas-sivated in other solutions. It is shown that the electro-chemical passivation will reduce Ni content but increase Ti content in the surface, reaching the Mole ratio of Ti:Ni=9.01:1 on the outermost surface. Potentiodynamic polarization test demonstrates that the samples electrochemically passivated in the molybdate solution present a significant increase in breakdown potential due to titanium enrichment on the outermost surface.     

Deformation Behavior of Mg-8 wt%Li Alloy under High-speed Impact

Deformation behavior of the Mg-8 wt%Li alloy at high strain rate was studied by means of the Split Hopkinson Pressure Bar (with strain rate of 103 s-1). It is found that shear localization proves to be the main damage mode for the alloy during dynamic loading. Strain and strain rate are the two necessary parameters affecting the occurrence of deformation and shear bands. Deformation bands begin to form when the strain and strain rate reach 0.20 and 1 900 s-1 respectively and will develop gradually with the strain rate increasing. Be-sides, deformation bands will transform into shear bands when the strain and strain rate reach above 0.25 and 3 500 s-1 separately.     

热变形对高铌TiAl合金微观组织的影响

通过对Ti-45Al-8.0Nb-0.2W-0.2B-0.1Y(原子百分数)合金的热压缩分析发现,其变形温度和变形速率对合金的真实应力-应变曲线以及变形后的组织有显著的影响。在低的变形温度和高的变形速率下,随应变量的增加合金呈现明显的软化现象,变形后存在大量的流线型组织,当变形温度达到1250℃、变形速率降到1×10^-3s^-1时,合金变形后的组织逐渐得到充分的再结晶,铸态组织得到明显的细化。