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Corrosion Resistance of Ni-P Composite Coating on Mg Alloy: Critical Role of the Intermediate Phosphate Conversion Coating Layer for Suppressing Galvanic Couple Formation 下载免费PDF全文
Electroless nickel (EN) plating can give rise to the severe galvanic corrosion of the magnesium (Mg) alloy matrix, owing to its nobler electrochemical potential than Mg alloy. To hinder the formation of galvanic couple, an intermediate phosphate conversion coating (PCC) layer is introduced between the EN layer and the Mg alloy matrix. Since the ceramic-like PCC layer cannot be catalyzed, a low-cost Ag-activation technique is used to process the PCC layer before electroless plating. The cross-section morphology and element distribution of the PCC-EN composite coating indicate that the PCC intermediate layer can effectively separate the Mg alloy from the EN layer. Moreover, the results of electrochemical tests suggest that the PCC-EN composite coating has a better corrosion resistance in comparison with the EN coating and AZ91D Mg alloy. 相似文献
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LIAO Jinge LI Chengxing ZOU Wenbing KANG Jing SONG Jiangfeng JIANG Bin ZHAO Hu YANG Zhiyuan PAN Fusheng 《上海航天》2022,39(1):92-101
Mg-Gd-Y-Zr alloy castings are widely used in the aerospace field owing to their high strength and excellent creep resistance. The castability of these alloys is also an important consideration for engineering application. Thus, the hot tearing susceptibilities (HTSs) of Mg-10Gd-1Y-1Zn-0.5Zr (VW91) alloy and Mg-10Gd-2Y-1Zn-0.5Zr (VW92) alloy are investigated with a constrained rod casting (CRC) mold. The microstructures and fracture surface are characterized by optical microscope and scanning electron microscope. The results unveil that the HTS of VW92 alloy is lower than that of VW91 alloy. The microstructures indicate that obvious tears can be observed in VW91 alloy, while the tears in VW92 alloy are tiny. The tear feeding and healing by eutectic are also observed in VW91 and VW92 alloys. Therefore, the lower hot tearing susceptibility of VW92 alloy is mainly attributed to the high amount of eutectic which feeds and heals tears. Besides, the effects of the coefficient of thermal expansion (CTE) and the fluidity of VW91 and VW92 alloys on their HTSs are discussed. 相似文献