制备氧化物涂层的新方法

本文介绍了一种新型的制备氧化物涂层的新方法,溶胶－凝胶法,较详细地介绍了用该方法制备二氧化铈,二氧化钛,二氧化硅,二氧化锆,镧系稀土氧化物等涂层的原理,方法及用途。     

铜中间层1420铝锂合金扩散连接工艺

采用铜作为中间层,对1420铝锂合金的固相扩散连接技术进行了试验研究,分析了不同工艺参数对扩散连接界面组织及接头强度的影响规律.     

The Influence of Co Addition on Phase Transformation Behavior and Mechanical Properties of TiNi Alloys

The influences of Co-addition on phase transformation behavior and mechanical properties of TiNi alloys were investigated. Re- sults indicate that, as a substitute for Ni, Co added to TiNi alloys can dramatically decrease the martensite transformation temperature, and R phase transformation and martensite transformation are accordingly separated. When Co-content reach 10 at.%, the martensite transformation temperature is lower than that of liquid nitrogen. During deformation at room temperature, Ti50Ni48Co2 alloy exhibits good ductility with a lower stress plateau caused by stress-induced martensite and martensite reorientation.     

Scalable Preparation of SrTiO3 Submicro-wires from Layered Titanate Nanowires

SrTiO3 submicro-wires were prepared by the reaction of layered titanate nanowires with Sr(OH)2 powder in an autoclave. The wires were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Ultra-violet visible (UV-vis), photoluminescence (PL) and Raman spectroscopy. The XRD measurement shows that the prepared SrTiO3 submicro-wires hardly have impurity phases. The SEM and TEM images demonstrate that the scalable wires, which need to be proc- essed at the reaction temperature of 180 ℃ for about 48 hours, are not composed of single crystals. The PL shows that the wire-like SrTiO3 has emission peaks at the wavelengths of 568 and 585 nm. Further, the Raman spectroscopy reveals structural changes in the products through different reaction time.     

Effects of RRA Treatments on Microstructures and Properties of a New High-strength Aluminum-Lithium Alloy-2A97

A new high strength 2A97 Al-Cu-Li-X alloy was subjected to triple-aging of retrogression and re-aging treatments (RRA). Transmission electron microscopy (TEM), differential scanning calorimetry (DSC), and tensile tests were used to investigate the effects of RRA treatment on the microstructures and properties. DSC test reveals the reversion temperature range of the strengthening δ' (Al3Li)phase. The results show that the microstructure consists of δ' (Al3Li) phase, T1 (Al2CuLi) phase and θ"/θ'(Al2Cu) phase for 2A97 alloy treated by a triple-aging ora retrogression and re-aging treatment in the following order: (1) at 165 ℃×30 min, (2) at 220 ℃ or 240 ℃×15 min, (3) at 165 ℃×24 h. The plastic deformation, incorporated into the treatment after secondary high temperature aging, promotes the T1 precipitation during final re-aging. The tensile properties of the alloy treated by the retrogression and re-aging treatment reach the peak level of alloy single-aged at 165 ℃ in T6 temper.     

LaSr3Fe3O10-δ混合导体结构及氧非化学计量的研究

采用柠檬酸盐法制备了纯的LaSr3Fe3O10-δ粉体。利用间接碘量法测定了LaSr3Fe3O10-δ系列样品中铁离子的平均价态和氧的非化学计量值。实验发现,随着温度的逐渐升高,LaSr3Fe3O10-δ逐渐失氧,三价铁浓度增加使得铁的平均价态降低。     

铝锂合金与钛合金压印接头的力学性能

采用试验方法研究了铝锂合金(1420)和钛合金(TA1)同种压印接头及这两种材料组合的异种压印接头的力学性能,以接头的承载以及缓冲抗震能力作为评价接头质量的两个主要标准,经实验得到每组接头的载荷-位移曲线和能量吸收直方图间接得出压印接头的承载以及缓冲抗震能力。由实验结果可知,表征接头的承载以及缓冲抗震能力的载荷-位移曲线和能量吸收直方图均表明TA1-1420接头的力学性能相较于其他接头好,且与TA1-TA1接头相比,作为下板的1420密度较小,TA1-1420组的压印接头质量更轻。TA1-1420接头更适用于对于承载和缓冲抗震要求较高的部件。     

国外铝锂合金工艺性研究

本文介绍了俄国、美国和欧洲轻合金中铝锂合金成型、热处理和焊接的发展现状，在成型和热处理工艺中分析了工艺参数对半成品件的影响，指出了合理的选择工艺参数的重要性；在焊接工艺中介绍俄、美两国三个阶段研究的重点内容，比较了两国的焊接研究特点，最后提出几点看法。     

化学电池电解液中锂含量的测定方法

研究与应用氧化亚氮—乙炔火焰原子吸收光谱法测定化学电池电解液中含锂量。介绍了锂的最佳测定条件及呈良好线性范围的浓度。该方法选择性和重现性好、干扰小 ,并具有操作简便、易掌握、分析周期短等特点。相对标准偏差 RSD<1.0 % (n=10 ) ,标准加入回收率均在 97%～ 10 2 % (n=4)范围内。方法的精确度和准确度均能满足化学电池研制工作的要求。