飞机电热防冰用BaTiO3热敏陶瓷力学性能的改进

飞机电热防冰系统用ＢａＴｉＯ３基ＰＴＣ热敏陶瓷材料要求有低电阻及优良的ＰＴＣ效应,同时有良好的力学性能。本文叙述了在ＢａＴｉＯ３为基的ＰＴＣ材料中,通过配方组成设计及先进的工艺制备手段,获得了居里温度５０℃,室温体电阻率８０Ω·ｃｍ,ＰＴＣ效应１０６数量级,耐电压２４０Ｖ／ｍｍ,断裂韧性ＫＩＣ１９．１４ＭＮ／ｍ３／２,冲击韧性２．６Ｊ／ｃｍ２,抗弯强度１０８ＭＰａ,综合性能优良的ＰＴＣ材料。初步实验表明,该发热体陶瓷具有较强的防冰和化冰能力。     

Damping of Ni-Mn-Ga epoxy resin composites

By combining the advantages of effcient damping and high mechanical properties,Ni-Mn-Ga particle composites have a very good prospect for applications in damping structure design.In this paper,a ferromagnetic shape memory alloy Ni-Mn-Ga composite is prepared.Ni-Mn-Ga particle/bisphenol-A epoxy composite cantilever beam vibration tests under a magnetic feld and without the magnetic feld are conducted to analyze the structural damping ratios n.Meanwhile,the damping characteristics of the Ni-Mn-Ga composite are studied through the axial loading-unloading method and the acoustic emission signals method.The damping coeffcient of the composite for different Ni-Mn-Ga volume fractions is obtained.The interface properties of the composite are discussed by micro examination and axial loading.The relationships between the damping of the composite and that of the component materials are discussed.The specifc damping capacity（SDC）and acoustic emission counts diagram of different specimens with different Ni-Mn-Ga volume fractions are analyzed.     

碳纳米管在金属材料保护中的应用

碳纳米管（简称CNTs）是一类新型碳材料，具有中空无缝管状纳米结构。自Iijima1991年发现CNTs以来，其制备、表征和应用引起人们的极大兴趣。随着CNTs制备工艺获得突破，其潜在的应用前景日益受到关注，CNTs应用研究已经取得长足进展，其范围涉及到纳米电子器件、场发射材料、模板材料、复合材料、储氢材料和传感器组件等领域。CNTs具有优良的力学性能和独特的电学性能等，是复合材料的理想增强相，在CNTs复合材料领域的研究已经取得了一定的成果。     

Preparation and Mechanical Properties of Glass Coats with High Temperature Radar Absorber

BaO-La2O3-B2O3 （BLB） glass, suitable to be used as a sealing between metals, was chosen to be the binder in preparing glass coats on the Ti-alloy substrate. The SiCN nano-powder was introduced as the filler for the absorbing coat because it is considered to be a good high temperature absorber. The effect of the coating temperature and coating time on the tensile strength of the glass coat was investigated and the proper coating parameters to get good mechanical properties were determined. In addition, the effects of the SiCN content on the tensile strength of the absorbing coat were also discussed. Results show that it is possible to prepare the glass coat using the BLB glass as a binder. That the coat formed at 730℃ for 30 min has the best tensile strength witnesses 730 ℃, 30 min to be the proper parameter to prepare the glass coat. The BLB glass coat without SiCN powder possesses good tensile strength and the introduction of the SiCN absorber into the glass coat will lower the tensile strength. As the SiCN content increases, the tensile strength of the absorbing coat decreases, which could be attributed to the aggregation of SiCN in the coats.     

Preparation and Microstructure of Highly - Oriented LaNiO3 Thin Films by RF Sputtering Method

In an attempt of being used as buffer layers and electrodes for the textured BaTiO3 （BTO） ferroelectric thin films, highly （100）-oriented LaNiO3 （LNO） thin films of different thicknesses were deposited directly on Si （100） substrate with radio-frequency （RF） magnetron sputtering method. It is observed that the substrate temperatures and the film thicknesses bring main influences on the microstructures and orientation of the thin film. The effects of the thicknesses and substrate temperatures on the orientation of the films were studied on the LNO films of different thicknesses. The highly （100）-oriented LNO thin films were obtained at the substrate temperature of 600℃. The existence of epitaxially grown BTO films indicates that the oriented LNO thin films obtained in this work could be used as a buffer layer for epitaxial growth.     

高分子纳米复合材料研究进展(I)高分子纳米复合材料的制备、表征和应用前景

综述了高分子纳米复合材料的发展研究现状,将高分子纳米复合材料的制备方法分为四大类:纳米单元与高分子直接共混(内含纳米单元的制备及其表面改性方法);在高分子基体中原位生成纳米单元;在纳米单元存在下单体分子原位聚合生成高分子及纳米单元和高分子同时生成.介绍了高分子纳米复合材料的表征技术及其应用前景.     

钴铁氧体微粉的化学法制备工艺及其吸波性能

采用化学沉淀法合成钴铁氧体原始粉料,通过变化反应原料配方、掺混聚碳硅烷并进行高温处理、球磨等手段达到调节钴铁氧体吸收雷达波性能的目的,研究了产物微粉的制备工艺、物相组成与吸收雷达波性能的对应关系。     

单向Hi-Nicalon/SiC复合材料的工艺与性能

对比了采用先驱体转化法及热压法制备的单向Hi-Nicalon纤维增强SiC基复合材料的性能差异,结果表明制备工艺对复合材料的微观结构和性能有极大的影响.采用先驱体转化制备的Hi-Nicalon/SiC复合材料具有较好的性能,弯曲强度为703.6MPa,断裂韧性为23.1MPa@m1/2;两种工艺制备的碳化硅基复合材料性能产生差别的主要原因是高温下Hi-Nicalon纤维的性能下降.     

航空发动机及燃气轮机涡轮叶片热障涂层技术研究及应用

介绍了航空发动机及燃气轮机涡轮叶片热障涂层技术的研究和应用情况,对热障涂层黏结层和陶瓷层的材料、制备、应 用及主要失效原因等4个方面的现状和发展趋势进行了综述。详细介绍了应用广泛的黏结层材料MCrAlY以及近几年新兴的 PtAl;包括多元稀土氧化物掺杂ZrO2、萤石结构化合物、稀土锆酸盐等的陶瓷层材料;目前广泛用于生产的等离子喷涂、电子束物 理气相沉积等制备技术;着重介绍了热障涂层在中国的应用情况。主要从TGO和CMAS 2方面对热障涂层的失效原因分别进行 了分析。简要论述了涡轮叶片热障涂层研究未来将向着1300 ℃以上超高温陶瓷层、1200 ℃以上抗氧化并与先进单晶高温合金界 面匹配良好的金属黏结层、长寿命且抗CMAS性能良好的方向发展。     

可膨胀石墨的制备研究

通过传统氧化制备法制得的可膨胀石墨含硫量较高,具有腐蚀性,因此低硫或无硫可膨胀石墨的工艺制备方法具有非常重要的科研意义与经济价值。本文通过分析混酸系(硝酸/磷酸)在氧化剂重铬酸钾的作用下与天然鳞片石墨的反应,探究出一套相对科学的可膨胀石墨制备工艺。