Zn-5Al-xMn(x=0，0.1，0.2，0.3)合金的铸态组织与耐蚀性能

采用SEM、EDS、电化学测试等方法研究了热浸镀用Zn-5Al-xMn(x=0,0.1,0.2,0.3)合金的铸态组织与耐蚀性能。结果表明:在Zn-5Al合金中加入少量的Mn显著抑制了粗大初生β-Zn相的生成,当Mn含量为0.2%时,初生β-Zn相最少,共晶组织占比最高。试验合金的自腐蚀电位随着Mn含量的提高而增大,自腐蚀电流密度先减小后增大。Zn-5Al-0.2Mn合金自腐蚀电流最小为1.403μA/cm~2,其高频阻抗和低频扩散阻抗均最大。Zn-5Al合金中初生β-Zn相优先腐蚀,Zn-5Al-0.2Mn合金因初生β-Zn相较少,发生均匀性腐蚀,其腐蚀产物在Zn-5Al-xMn合金中最致密。     

用阻抗均匀过渡法研制高分辨力换能器

分辨力是超声探伤用换能器的关键指标,本文从理论和实验两方面探讨了如何利用机械阻抗均匀过渡法提高换能器分辨力的有关问题。     

微带贴片双频天线研究与设计

微带贴片天线以其馈电方式和极化制式的多样化以及馈电网络、有源电路集成一体化等特点而成为印刷天线类的主角。本论文采用HFSS仿真软件对单馈单层矩形微带贴片天线进行了设计和仿真。此次设计的1．85GHZ和2．45GHZ的双频贴片天线,在两个频点处,反射系数都低于-25dB,输入电阻都约为50欧姆,且电抗很小,达到了良好的匹配效果,辐射场量在两频点处分别约为2dB和4dB,符合小尺寸指标要求。     

液体火箭金属膜盒式蓄压器的动力学模型

蓄压器是抑制液体火箭POGO振动的重要装置,通过推导建立了更具普适性的蓄压器精细化动力学模型,给出了膜盒刚度、动质量以及膜盒组件数量对蓄压实际柔度参数、惯性系数的修正方法,该模型提高了输送系统液路频率的计算精度.针对带有充气管路的蓄压器结构形式,引入了充气管路的分布参数动力学模型.研究发现较长的充气管路不仅会对蓄压器产...     

基体曲率对热障涂层结合强度影响的无损检测研究

 针对复杂型面航空发动机涡轮叶片表面热障涂层(TBCs)的失效问题,采用交流阻抗谱(IS)法和洛氏硬度(RH)压痕法对比研究了制备在平板基体和曲率基体上,热障涂层在热循环过程中微观结构和界面结合强度的演变规律。交流阻抗谱法的结果表明:两种涂层试样的热生长氧化(TGO)层厚度及陶瓷层内裂纹数量均随着热循环时间增加而增长,但曲率试样的微观结构恶化速度更快;洛氏硬度压痕法的结果验证了经热循环后,曲率基体上热障涂层界面结合强度低于平板样品。     

Fe2+对碳钢硫酸盐还原菌腐蚀行为的影响

对比分析了Q235钢在无Fe2+的接菌培养基和Fe2浓度为30mg/L的接菌培养基中的腐蚀行为.使用光学显微镜跟踪观察Q235钢在两种介质中的表面形貌随时间的变化,用电化学阻抗谱研究Q235钢在两种培养基中的电化学行为.用聚焦离子束显微镜制作Q235钢在两种培养基中的腐蚀产物剖面,并用能谱对腐蚀产物进行成分分析.对电化学阻抗谱所得结果进行拟合,结果表明,Fe2会使Q235钢表面形成的生物膜电阻降低,电容升高,Q235钢反应电阻保持较低,从而使反应持续进行,铁不断溶解.培养基中加入30mg/L的Fe2+后,Q235钢表面附着的细菌显著增多,形成的生物膜厚而疏松,膜中混合有腐蚀产物硫化物,膜下的金属出现众多微小的点蚀.电化学阻抗谱拟合结果与形貌观察及成分分析结果吻合,Fe2+对Q235钢的SRB腐蚀反应具有催化作用.     

Failure of EB-PVD Thermal Barrier Coatings Subjected to Thermo-Mechanical Loading

Thermal barrier coatings (TBCs) were developed to protect metallic blades and vanes working in turbo-engines. The two-layered structure TBCs, consisting of NiCoCrAlY bond coat and yttria stabilized zirconia (YSZ), were deposited on a cylinder of superalloy substrate by the electron beam-physical vapor deposition (EB-PVD). The failure mechanism of the TBCs was investigated with a thermo-mechanical fatigue testing system under the service condition similar to that for turbine blades. Non-destructive evaluation of the coated specimens was conducted through the impedance spectroscopy. It is found that the crack initiation mainly takes place on the top coat at the edge of the heated zones.     

Investigation on a Sol-gel Coating Containing Inhibitors on 2024-T3 Aluminum Alloy

For a long time, chromate incorporated conversion coatings have been drawn special attention in corrosion protection of air-craft-used aluminum alloys. However,ever-increasing environmental pressures requires that non-chromate conversion coatings be developed because of the detrimental carcinogenic effects of the chromate compounds. In recent years, the sol-gel coatings doped with inhibitors were developed to replace chromate conversion coatings, and showed real promise. A sol-gel coating was prepared and its anti-corrosion behavior was investigated using the potentiodynamic scanning (PDS) and the electrochemical impedance spectroscopy (EIS). It is found that the sol-gel coating obtained by the hydrolysis and condensation of 3-glycidoxypropyltrimethoxysilane (GPTMS) and tetramethoxysilane (TMOS) is prone to form defects if cured at the room temperature, whereas if cured at a higher temperature (100 ℃), these flaws can be avoided. Furthermore, it can be seen that addition of anti-foam agents and surfactants will reduce the faults if cured at the room temperature. Effects of the corrosion inhibitors, CeCl3 and mercaptobenzothiazole (MBT), in the sol-gel coatings on 2024-T3 aluminum alloy were also investigated. Results show that the corrosion resistance of the sol-gel coatings containing CeCl3 proves to be better than that of the pure and MBT added sol-gel coatings by the electrochemical methods.     

宽带变负载阻抗匹配网络的设计研究

某坦克电台采用螺旋天线以缩短天线的几何尺寸，提高安全性。由于该天线的输入阻抗随频率而变化，需要用一个宽带变负载阻抗匹配网络来实现天线与电台之间的匹配。首先从理论上分析论证了实现具有最平坦频率特性的变负载阻抗匹配网络的可能性。然后，根据实际要求进行了计算机辅助工程设计，并给出了相应的设计和仿真结果。     

螺旋天线几何尺寸的优化设计

本文首先导出了螺旋天线输入阻抗的计算公式。然后，在使天线输入阻抗满足技术要求的条件下，对螺旋天线的几何尺寸进行了优化设计。