航天器异种金属钎焊接头静态裂纹行为分析

采用高频感应钎焊方法连接了航天推进系统的异种金属(钛合金与不锈钢)薄壁小直径导管结构,结构的质量和性能远远优于螺栓连接的导管结构.钎焊接头静态拉伸试验发现,银基钎料钎焊的接头承载能力要优于铜基钎料.对静态拉伸断裂接头的微观组织进行了分析,结果发现,银基钎料钎焊的接头区域出现的裂纹仅在钎缝区域萌生和扩展,当裂纹扩展到钎缝与母材的界面位置时停止扩展.铜基钎料钎焊的接头区域的裂纹从3个位置萌生:钎缝2种组织的交界处,钎缝与钛合金、不锈钢的界面.裂纹驱动力主要是由静态拉伸载荷和异种金属钎焊接头失配行为构成的,而裂纹扩展抗力主要与钎焊接头的微观组织有关.     

ATP/BPS交联体合成及性能研究

以丁二酸和丙炔醇为原料,合成出了丁二酸双丙炔醇酯( BPS),借助于叠氮基与炔基叁键之间的1,3-偶极环加成反应,完成了对叠氮粘合剂ATP 的交联固化。由于异氰脲酸酯基团的引入, ATP 基聚三唑交联体力学性能明显优于GAP基聚三唑。在研究的范围内,常温抗拉强度为0.792~2.05 MPa,延伸率为90%~70%。其中,90.27%ATP/9.73%BPS配方具有较好的综合性能。     

PET/N100粘合剂体系固化过程FTIR研究(Ⅰ)--TIR曲线

采用了加热原位池／FTIR联用技术实时跟踪N100和环氧乙彬四氢呋喃共聚醚（PET）固化反应过程的方法,获得了固化度与温度的关系（TIR）曲线,研究了添加物及升温速率对固化体系的影响,发现催化刺对固化反应有明显的力口速作用,增塑荆的加入,使得固化反应的起始温度增加,终止温度降低,这些结果为固化TIR动力学的进一步研究提供了基本数据。     

Stress-controlled LCF experiments and ratcheting behaviour simulation of a nickel-based single crystal superalloy with [001] orientation

Uniaxial ratcheting behaviour and low cycle fatigue (LCF) failure mechanism of nickel-based single crystal superalloy DD6 with [001] orientation are investigated through the stress-controlled LCF tests with stress ratio of −1. Then the deformation behaviour during the whole-lifetime from the beginning of the experiment to the fracture of the specimen, as well as the fractographic/metallographic morphology, are compared with the strain-controlled LCF experimental results. Through the scanning electron microscope (SEM) observations, it is shown that the failure characteristics under stress-controlled LCF loading are similar with those under strain-controlled loading. Nevertheless, unlike strain-controlled LCF loading, even under fully reversed cycle loading for stress-controlled LCF, DD6 shows significant ratcheting behaviour due to the tension-compression asymmetry. In addition, the LCF lifetimes under stress control are significantly shorter than the LCF lifetimes under strain control, and the culprit might be the detrimental effect of ratcheting strain on LCF lifetime. Based on these phenomena, an improved crystal plasticity constitutive model on the basis of slip-based Walker constitutive model is developed through modifying the kinematic hardening rule in order to overcome the inaccurate prediction of decelerating stage and stable stage of ratcheting behaviour. Furthermore, combining the continuum damage mechanics, a damage-coupled crystal plasticity constitutive model is proposed to reflect the damage behaviour of DD6 and the accelerating stage of ratcheting behaviour. The simulation results for the stress-controlled LCF deformation behaviour including the whole-lifetime ratcheting behaviour show good agreement with the experimental data.     

环氧共混树脂的光固化及其表面化学反应

研究了双酚A型环氧树脂与有机硅环氧树脂紫外光辐照共混改性的工艺条件,并采用扫描电镜和X射线光电子能谱等分析手段对树脂改性效果和表面的物理和化学变化进行了研究.结果表明,采用二苯基碘鎓六氟磷酸盐为光引发剂,当质量分数为5％时,随着E-44含量的增加,共混树脂体系的光固化速度加快.当两者质量比为1∶ 2时,经15min的紫外光辐照后,共混树脂体系的凝胶率可达93％.X射线光电子能谱分析结果表明,在光固化的同时,试样的表面被紫外光辐照时产生的臭氧和原子氧部分氧化,转化为一层含C的氧化硅(SiO _{x )膜.}      

一次性医用注射针组装环氧胶粘剂的研制

文章利用改性二乙烯三胺作为环氧树脂固化剂,以二氧化钛为填充剂,制备了一次性医用注射针组装胶粘剂,研究了填充剂和固化剂对胶粘剂性能的影响。实验结果表明,该胶的拉拔强度远超医用针头组装胶粘剂的国家标准。     

缠绕用低温快速固化氰酸酯树脂的改性

针对湿法缠绕工艺,在不影响固化温度条件下用TDE-85对氰酸酯树脂进行改性,对改性前后树脂性能进行对比研究。结果表明:环氧与催化剂混合物在40℃时黏度低于1 Pa·s,且能维持超过214 min,能够满足湿法缠绕的工艺需求;环氧含量低于10 wt%时,起始固化温度不超过77℃,在80℃的凝胶时间为30min左右,仍满足低温快速固化要求;当TDE-85含量为10 wt%时,树脂浇铸体力学性能最优,其拉伸强度、弯曲强度、冲击强度分别为46.2、83.4 MPa、10.8 kJ/m^2;但环氧的加入对氰酸酯的吸湿性和耐热性能均有一定负面的影响。     

N,N,N'',N''-四炔丙基-4,4''-二氨基-二苯甲烷的热固化反应及其固化产物的热稳定性研究

初步研究了N，N，N’，N’-四炔丙基-4，4’-二氨基-二苯甲烷（TPDDM）的热固化反应。通过DSC分析其固化行为特征。FT-IR观察了它固化过程中特征官能团变化，对比了其在空气中和氮气中固化行为的差异，发现在空气中固化产物出现1733cm^-1的峰，推断是被氧化所致，并通过DSC和FT-IR确定了固化条件。利用TGA技术考察了该固化产物在空气中和氮气中的热稳定性。结果表明：在空气中固化产物起始失重率为5％的分解温度为414．4℃，高于在氮气中的392．8℃。TPDDM的固化产物在氮气中700℃残碳率为53．9％，在空气中全部分解。     

影响室温硫化硅橡胶脱模剂表面固化时间的因素分析

通过实验分析了影响室温硫化硅橡胶脱模剂表面固化时间的各种因素。结果表明，脱模剂表面固化时间与环境温度、湿度和交联剂、催化剂、稀释剂用量，以及加料顺序有关，经实验得出了最佳配制工艺。     

Analysis of dynamic behaviour of inflatable booms in zigzag and modified zigzag folding patterns

The deployment behaviour of inflatable booms with zigzag and modified zigzag folding patterns is experimentally and theoretically investigated in this paper with the aim to deploy the booms as the actuator for future deployable large-scale membrane structures. Regarding the experimental approach, the stable deployment of a modified zigzag folding pattern is demonstrated, and the relation between stable and unstable deployment behaviour is considered in relation to air pressure and flow rate. In terms of the theoretical approach, the folding process and deployment behaviour are simulated using commercially available software (PAM-CRACH and PAM-SAFE). To create folding lines from the zero stress condition in the case of analytical inflatable boom models, the stress distribution and the shapes of the folding lines are considered for the initial self-deployment behaviour and deployment behaviour using the uniform pressure method. From the folding experiments and the results of folding analyses and UPM, the deployment behaviour of inflatable boom models in zigzag and modified zigzag folding patterns is compared by using the finite point-set method. For the sequential deployment behaviour, which is difficult to replicate, the uniform pressure method is used for the calculations, and the relation between inlet air flow and stable deployment behaviour is discussed through comparison of the experimental and analytical results.