Studies of Electromagnetic Properties of MWCNTs after Electroless Plating with Co-Fe Alloy

A method of electroless plating is utilized to deposit Co-Fe alloy on the surface of multi-walled carbon nanotubes (MWCNTs), and electromagnetic parameters of MWCNTs with and without electroless plating are discussed. The MWCNTs covered by Co-Fe is a desirable light absorbent in wide wave band by utilizing electroless plating process in experiments. Field-emission scanning electron microscope (FESEM) and field-emission transmission electron microscope (FETEM) images as well as energy dispersive spectroscopy (EDS) results are presented to show the morphology, components and electromagnetic parameters of MWCNTs. Electromagnetic properties of MWCNTs are enhanced after electroless plating observed from contrast of results between MWCNTs with and without plating. In conclusion, the covering Co-Fe on the surface of MWCNTs in 2-18 GHz frequency range has better electromagnetic properties. When the material is in the 6.5 GHz electromagnetic waves, the reflection loss is up to ?10 dB, and the bandwidth more than ?4 dB is 5 GHz. The excellent electromagnetic properties make it probable for MWCNTs to be utilized as absorbent in electromagnetic shielding materials.     

Resol型酚醛树脂热解特征的TG-MS 研究

合成了一种低醛 /酚摩尔比 (1.3∶1)的Resol型酚醛预聚物。利用TG -MS详细研究了热交联固化后树脂的热分解特征。低于 35 0℃时 ,主要表现为分子内醚键断裂和脱端羟甲基 ,并逸出H2 O、CO2 和CH3 OH等产物及它们的碎片。在 35 0℃～ 75 0℃范围内 ,大分子主链在不同位置发生主链断裂而形成一甲基苯酚、二甲基苯酚和三甲基苯酚等产物及它们的碎片。说明了大分子主链热稳定性的提高是减少和防止Resol型酚醛树脂前驱体C/C复合材料缺陷的重要组成部分     

硫及硫化物对镍基合金碳蚀的抑制作用与机理

通过小单管燃烧试验,证实了燃油中适量的硫及硫化物对镍基高温合金碳蚀的抑制作用,并根据碳蚀机理和催化剂中毒原理,探讨了硫及硫化物对镍基高温合金碳蚀的抑制机理。为了防止镍基合金的碳腐蚀 ,提出了控制燃油中总硫含量和改进结构设计及合理选材的建议。     

旋流与炭黑对聚乙烯固体燃料冲压发动机工作性能的影响

为探究旋流与添加炭黑对聚乙烯推进剂固体燃料冲压发动机工作性能的影响,采用实验和数值仿真相结合的方法进行研究。结果表明:在聚乙烯中加入质量分数为5%的炭黑可以提高补燃室压强和温度,增大燃烧室内高温区面积,且对推进剂燃烧效率、发动机工作性能以及发动机燃烧稳定性具有积极作用。与聚乙烯推进剂相比,含炭黑推进剂在无旋工况下可使发动机平均燃面退移速率提高15%,特征速度提高4%,推力提高11%。在旋流工况下,添加炭黑可使推进剂平均燃面退移速率提高29%,特征速度提高8.5%,发动机推力提高22.3%。结果表明:在添加炭黑和旋流的共同作用下,对发动机工作性能提升更加明显。相比于无旋工况而言,旋流的引入有助于燃气与来流空气的掺混,提高推进剂燃烧效率,对推进剂燃面退移速率提升具有积极作用。     

碳黑对固体燃料冲压发动机旋流燃烧特性影响

为研究含碳黑推进剂对固体燃料冲压发动机(SFRJ)旋流燃烧特性的影响,以高密度聚乙烯和含碳黑聚乙烯为推进剂,使用直连式实验系统对冲压发动机进行了旋流和无旋工况的实验研究。并根据实验所获的数据进一步计算得到不同工况下SFRJ工作性能参数。结果表明与聚乙烯(PE)固体燃料相比,含5%碳黑的聚乙烯推进剂可以有效提高固体燃料的燃速、特征速度和推力。在旋流工况下,固体燃料冲压发动机补燃室压强和温度也相应提高,燃烧稳定性增强。同时,在对燃烧室构型进行实验研究时发现,固体燃料冲压发动机的燃烧稳定性和燃烧效率会随药柱内径的增大而提高,而发动机平均燃速则会随着药柱内径的增加而降低。     

Numerical Modeling of the Compression Process of Elastic Open-cell Foams

The random models of open-cell foams that can reflect the actual cell geometrical properties are constructed with the Voronoi technique. The compression process of elastic open-cell foams is simulated with the nonlinear calculation module of finite element analysis program. In order to get the general results applicable to this kind of materials, the dimensionless compressive stress is used and the stress-strain curves of foam models with different geometrical properties are obtained. Then, the influences of open-cell geometrical properties, including the shape of strut cross section, relative density and cell shape irregularity, on the compressive nonlinear mechani- cal performance are analyzed. In addition, the numerical results are compared with the predicted results of cubic staggering model. Numerical results indicate that the simulated results reflect the compressive process of foams quite well and the geometrical properties of cell have significant influences on the nonlinear mechanical behavior of foams.     

光纤CO气体传感器的研究

基于近红外吸收光谱分析技术,采用1.57μm分布反馈式半导体激光器(DFB LD)作为光源,应用二次谐波检测技术,实现了CO气体的浓度检测,与中红外CO气体检测系统相比,系统的灵敏度和稳定性得到很大提高。     

碳当量在3.6～3.9范围内不同Si/C比对铸件组织和性能的影响

以陕西压延设备厂生产的HT2 5 0以上的铸铁件为依据 ,通过 1998年 10月份前后大量数据的类比分析方法 ,寻找不同的Si/C比与机械性能、金相组织之间的关系 ,并严格控制熔炼工艺 ,提出了一些解决的措施 ,并在实际生产中取得了明显的效果     

Synthesis of Iron-containing Carbon Microparticles from Deoiled Asphalt and Ferrocene

The deoiled asphalt as the carbon source and the ferrocene as the metal source and the catalyst precursor were chosen to synthe-size iron-containing carbon microparticles through co-carbonization at the temperature of about 450 ℃ for 3 h. The resulting products were treated at 2 000 ℃ for 2 h. All samples were examined by high resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD). The results show that the iron particles in the heat-treated material are completely coated by carbon. In addition to the fully filled carbon microparticles as well as hollow carbon ones, also form carbon fibers with hollow centers. The formation mechanism of the as-prepared products was discussed briefly.