TC4合金等温成形过程模拟与组织预测

在试验研究的基础上，建立了能够反映锻造热力参数对材料成形性能影响的新型本构方程，并采用变形与传热耦合分析的刚塑性有限元数值模拟方法，全面系统地研究了TC4合金的等温成形过程，基于建立的该合金动态再结晶组织的演化模型，定量地预测了等温成形过程中TC4合金微观组织的演变情况，并分析讨论了工艺参数合金微观组织演变过程的影响，从而为TC4合金热成形工艺参数的优化设计和控制提供了基础。     

Microstructural evolution and hardness of as-cast Be-Al-Sc-Zr alloy processed by laser surface remelting

As-cast beryllium-aluminum (Be-Al) alloy exhibits a coarse microstructure with pore defects due to a large solidification interval, greatly limiting its mechanical properties. In this research, the relationship between laser surface remelting process and microstructure and hardness of as-cast Be-Al-Sc-Zr alloy was established. The experimental results demonstrated that a pore-free refined microstructure of remelted layer was obtained by controlling the parameter of effective laser energy input. The microstructure of as-cast Be-Al-Sc-Zr alloy consisted of equiaxed grains with Al phase forming a continuous frame wrapping Be phase, which was significantly refined in the remelted zone (from 25 μm to 2 μm). The Vickers hardness in the remelted zone (approximately 210 HV) was approximately 3 times that of as-cast Be-Al-Sc-Zr alloy. Analysis of the Vickers hardness and the Be phase size showed a good agreement with a Hall-Petch equation. In addition, transmission electron microscopy (TEM), auger electron spectroscopy (AES) and X-ray diffraction (XRD) analysis evidenced that Sc and Zr elements formed a single blocky phase Be₁₃(Sc_x,Zr_1-x), which was also greatly refined from 8 μm to 1.5 μm in the remelted zone. The results obtained in this study indicate that the laser surface remelting allowed refining the microstructure and further strengthening the Vickers hardness of Be-Al-Sc-Zr alloy.     

PAN基高模量碳纤维微观结构研究

采用X射线衍射(X-ray diffraction,XRD)和拉曼光谱(Raman光谱)研究了3种自制PAN基高模量碳纤维(1#,2#,3#)的微观结构,并与M40J,M46J,M55J碳纤维进行了对比。结果表明:3种自制PAN基高模量碳纤维微晶尺寸的大小顺序为3#2#1#;1#到3#碳纤维表面和截面Raman光谱所获得的R值(D峰和G峰的积分强度比)均减小,石墨化程度升高,结晶性变好;1#碳纤维的结晶性介于M40J碳纤维和M46J碳纤维之间,2#和3#介于M46J碳纤维和M55J碳纤维之间;三者的石墨化程度略高于M46J碳纤维。     

Microstructure evolution of a hypereutectic Nb–Ti–Si–Cr–Al–Hf alloy processed by directional solidification

In this work, the Nb–14Si–24Ti–10Cr–2Al–2Hf–0.1Y alloy(at.%) was processed by the liquid–metal-cooled directional solidification(DS) at 1750 C with withdrawal rates of 1.2, 6,18 mm/min and post heat treatment(HT) at 1450 C for 10 h. The microstructures of the directionally solidified and heat treated samples were investigated. The results show that the microstructure of directionally solidified alloy mainly consists of petaloid Nbss+ Nb5Si3eutectics and Ti-rich Nbss+ Nb5Si3+ Cr2Nb eutectics. With the increase of withdrawal rate, the primary Nb5Si3is eliminated, Nbss+ Nb5Si3eutectic cells turn round and connected with the microstructure refinement and Nbss+ Nb5Si3+ Cr2Nb eutectics turn to a river-like morphology. After heat treatment,Nbss+ Nb5Si3+ Cr2Nb eutectics disappeared and petaloid Nbss+ Nb5Si3eutectics turn to a specific fiber-mesh structure gradually, which is promoted by higher withdrawal rates. Furthermore,both the volume fraction of Cr2Nb and the content of Cr in Nbssof Nbss+ Nb5Si3eutectics change regularly with the increase of withdrawal rate and heat treatment at 1450 C for 10 h.     

热解碳界面层与国产T300 增韧SiC 复合材料拉伸性能关联性初探

在国产T300碳纤维上沉积不同厚度的热解碳形成界面层,通过前驱体浸渍裂解工艺制备“迷你”Cf/SiC复合材料,考察了T300碳纤维在相同工艺过程中其界面层厚度的最优工艺参数,并研究了热解碳界面层与“迷你”复合材料拉伸性能的关联性.采用SEM与Raman手段对Cf/SiC复合材料进行结构表征.结果表明:该复合材料有明显的裂纹偏转,经高温热处理后界面层状结构更加明显,其复合材料的拉伸强度随热解碳厚度的增加其值有先增加后减小的趋势(PyC的厚度在0～150 nm),当界面层厚度约为60 nm时达到最大值(1 385.7 MPa).     

转速对20 mm厚2219铝合金搅拌摩擦焊接件的组织及性能的影响

对20 mm厚的2219 C10S铝合金板材进行搅拌摩擦焊对接试验,在进给速度为100 mm/min的条件下,对比研究转速为400～550 r/min时的对接接头的内部缺陷、宏观形貌及微观组织、显微硬度和拉伸力学性能的差异。结果表明,当转速为400～500 r/min时,焊接接头无缺陷,能获得内部质量较高的焊接接头。随着转速的增加,焊核区“洋葱环”的间距和轴肩影响区的范围增大,焊核区和热力影响区的硬度的降低越明显。接头的拉伸性能随转速的增大而降低,拉伸强度最高可达到334 MPa,接头断裂模式主要为韧性断裂,断裂位置发生在后退侧的热力影响区与热影响区的交界处,与显微硬度最小位置相吻合。当转速增大至525 r/min时,焊缝出现表面点状缺陷;当转速达到550 r/min时,焊缝出现连续的犁沟缺陷。     

TC4板材组织特征与超声检测信号对应关系研究

在大厚度板材在轧制过程中,由于工艺控制不当易引起材料组织分布不均匀、粗大晶粒等问题,本文针对TC4轧制板材研究超声检测信号对材料内部组织分布的表征情况。结果表明,声波垂直于板材流线方向入射时,声衰减分布均匀;而平行入射时,声衰减分布极不均匀,呈条带状分布。为此,对引起不同声波衰减的截面进行组织分析,金相观察发现超声波衰减与材料内部α相的分布及形态有关：声衰减小的区域,材料内部等轴α相较多,晶粒细小,分布均匀;声衰减大的区域,α相被明显拉长。     

Influence of welding parameters on microstructure and mechanical properties of electron beam welded Ti60 to GH3128 joint with a Cu interlayer

Effects of welding parameters on the microstructure and mechanical properties of Ti/Cu/Ni joint welded by electron beam were investigated. High welding heat input increased the melting quantity of Ti60 titanium alloy and promoted the formation of Ti–Cu intermetallic compounds (IMC) such as Ti₂Cu and Ti₃Cu₄, increasing the brittleness of the joints. Low welding heat input was not conducive to the complete melting of the copper interlayer, and the unmelted copper reduced the performance of the joints. Under the optimal welding parameters, Ti–Ni IMCs in the weld would be replaced by (Cu, Ni) solid solutions ((Cu, Ni)_ss). However, Ti–Cu IMC layers cannot be eliminated entirely by changing the welding parameters. The maximum tensile strength of the joints was 201 MPa. The fracture of the joints occurred at the Ti–Cu IMC layer, which was a typical brittle fracture.     

铝合金回填式搅拌摩擦点焊工艺及组织特征分析

对2219+5A06铝合金进行了回填式搅拌摩擦点焊试验，研究了搅拌头旋转速度，下压-回抽速度和压入量等工艺参数对点焊接头力学性能的影响。对不同参数焊接的点焊接头进行了剪切拉伸抗力试验。结果表明：搅拌头旋转速度和下压-回抽速度对点焊接头的力学性能影响较大，而压入量对力学性能的影响较小。对点焊接头的微观组织分析表明，焊点接头可分为焊核区、竖直面热机影响区和水平面热机影响区三个部分。焊核区及水平面热机影响区为细小的等轴晶粒，水平面热机影响区形成与板材平行的结合面，竖直面热机影响区及焊点根部的hook缺陷是焊点力学性能的薄弱区域。     

Interfacial characteristics in CNTs-AgCuTi systems

AgCuTi-based composite fillers reinforced with Carbon Nanotubes（CNTs） were prepared by mechanical ball milling and ultrasonic agitation. The morphological features, chemical components, and melting characteristics of the composite fillers with different content of CNTs addition were investigated using Field Emission Scanning Electron Microscopy（FESEM）, XRay Diffraction（XRD） and a Differential Scanning Calorimeter（DSC）. After being heated at 900 ℃, the microstructure of the composite fillers was ...