TiBw/TA15复合材料板材超塑变形行为研究

研究了TiB_w/TA15复合材料板材在900～960℃、5×10^–4～10^–2s^–1条件下的超塑变形行为。结果表明,TiB_w/TA15复合材料流变应力随拉伸温度的升高和应变速率的减小而降低,在940℃、5×10^–3s^–1变形条件下获得的最大超塑性伸长率为439%。利用Zener–Hollomn参数和Arrhenius方程所建立的峰值应力本构方程为ε~·=3.55×10⁸[sinh(2.0×10^–2σ)]^1.99×exp(–6.381×10⁵/RT),其变形激活能Q=638.1kJ/mol。复合材料超塑性变形组织与拉伸温度和应变速率密切相关。高温低应变速率有利于基体α相的动态再结晶以及晶须与基体处孔洞的愈合,低温高应变速率下,孔洞更易萌生于增强相与基体结合界面的端部。动态再结晶对复合材料超塑性的发挥起着关键作用。     

V,Al对Nb-Si系超高温结构材料抗氧化性能的影响

采用真空非自耗电弧炉制备了Nb-22Ti-12Si三元以及三种不同V,Al含量的Nb.Ti-Si-V-Al五元Nb-Si合金,研究了四种合金铸态显微组织和1250℃的抗氧化性能.结果表明:V,Al的加入促进了反应Nb3Si→Nb Nb Nb5Si3,使合金相组成由Nb Nb3Si转变成为Nb Nb5Si3,从而增加了合金中Nb相体积分数;合金的抗氧化性能随V,Al含量的增加而提高;V,Al的加入使合金氧化皮结构发生了转变,生成了较为致密的氧化皮,降低了合金的氧化速率,减少了合金氧化皮的剥落和金属氧化损失量.Nb-21.9 Ti-11.9Si-4.4V-4.1Al经过1250℃/50h氧化后金属损失厚度仅为0.1mm.     

Joining of SiO2 ceramic and TC4 alloy by nanoparticles modified brazing filler metal

Nano-Al₂O₃ particles modified AgCuNi filler was adopted to braze the SiO₂ ceramic and TC4. The effects of filler size as well as the brazing temperature on the interfacial microstructure and mechanical property of the joints were investigated. Nanoscale filler reduced the phases dimension and promoted the homogeneous distribution of microstructure, obtaining a higher joint strength when compared to microscale filler. The increase of brazing temperature made the accelerating dissolution and diffusion of Ti, which promoted the increase of thickness of Ti₄O₇ + TiSi₂ layer adjacent to SiO₂ ceramic and diffusion layer zone nearby TC4 alloy. The hypoeutectic structure was produced in the brazing seam due to the high Ti content. The maximum shear strength of ∼40 MPa was obtained at 950 °C for 10 min.     

Improvement and application of Y2O3 directional solidification crucible

In order to satisfy the drastic temperature change and high chemical activity in directional solidification of Nb–Si based alloys, Y_2O_3 crucible is demanded to possess high thermal shock resistance and erosion resistance. This paper improved the sintering degree and density of Y_2O_3 crucible by optimizing the sintering temperature and time, and its practical application performance was investigated. Y_2O_3 grains gathered with the increase of sintering temperature and time, and the contact area enlarged, resulting in the open pores being changed into closed pores.The higher density caused the improvement of erosion resistance of Y_2O_3 crucibles. However, excessive density weakened the thermal shock resistance. Considering high-temperature strength, erosion resistance, thermal shock resistance and costs, optimum sintering temperature and time of Y_2O_3 directional solidification crucible were 1800 °C and 120 min, respectively, and the porosity was20%. Improved Y_2O_3 crucible has been successfully applied to directional solidification of Nb–Si based alloys, and significantly reduced the oxygen contamination. Slight interaction occurred between Hf and Y_2O_3, but no obvious dissolution, penetration or erosion was found, showing good erosion resistance and thermal shock resistance.     

不同热处理工艺下激光增材制造TC4钛合金组织与性能研究进展

由于激光增材制造(Laser Additive Manufacturing,LAM)TC4钛合金加工成形过程的特殊性,导致该合金在力学性能上存在明显的各向异性,同时韧性、疲劳性能不能很好地满足使用要求。从材料组织与力学性能之间的关系出发,介绍了不同热处理工艺对激光增材制造TC4钛合金组织与力学性能的影响,指出了当前激光增材制造TC4钛合金热处理研究中存在的问题,并为后续激光增材制造TC4钛合金的热处理研究提供思路与方向。     

沉积温度对碳芯SiC 纤维微观结构的影响

以沥青基碳单丝为基体,一甲基三氯硅烷为碳化硅前驱体,使用通电加热的冷壁CVD工艺,温度在1 473～1 773 K,制备了碳芯SiC纤维.采用扫描电子显微镜和拉曼光谱对纤维的表面形貌及结构进行了表征,研究了沉积温度对其结构的影响.结果表明,SiC涂层为β-SiC晶型.沉积温度的升高引起了沉积速率的增加以及SiC涂层晶粒尺寸的长大.同时,导致碳芯中心区域发生结构重排,引起了该区域取向度的提高以及晶粒尺寸的减小.     

加热温度对TC4钛合金的空冷组织及热疲劳抗力的影响

对经不同温度加热随后空冷的ＴＣ４钛合金在－１９６～３５０℃范围内进行了外约束型热疲劳试验。结果表明：经单相区加热的合金，其热疲劳裂纹易于沿原β相晶界处萌生，以穿晶的方式扩展，对热疲劳裂纹萌生抗力较低。而经９５０℃加热的合金，其热疲劳裂纹易于沿初生α相与基体（条形的α＋β相）的界面处萌生，裂纹易于切过条形的α＋β相扩展，其热疲劳裂纹萌生抗力最高。经９００℃加热的合金，其热疲劳裂纹易于沿初生α相与基体的界面处萌生并沿其扩展，合金的热疲劳裂纹萌生抗力也较低     

稀土对GH4169激光微焊接接头组织性能的影响

通过添加稀土元素Ce对0.2mm厚的GH4169高温合金进行微激光对接焊接,利用光学显微镜、扫描电镜、电子精密拉伸仪测试等分析方法,对比研究稀土元素对焊缝表面成形、接头显微组织及力学性能的影响。结果表明：在添加稀土元素的条件下焊接时,对焊接工艺参数进行正交试验优化,得出焊接最优工艺参数为脉冲功率17%、脉冲频率4.0Hz、脉冲宽度3.1 ms,此时焊接接头断裂在母材。焊接过程中,液态金属流动使稀土在熔池中均匀混合,获得了组织均匀的焊缝。稀土元素能够改变焊缝温度梯度,形成“梯形”状焊缝;同时,稀土元素能够降低接头的显微硬度,增强接头的韧性和塑性。     

TiAl 与TC4 扩散焊接接头的组织与性能

主要对TiAl基金属间化合物与TC4的扩散连接技术进行了研究。通过对钛铝基合金进行热处理,获得了高温性能良好的全片层组织;通过对扩散连接后的接头进行组织结构、力学性能和断口的分析发现,在915℃/80 MPa/1 h的扩散连接条件下,TiAl基合金与TC4实现了冶金结合,在室温、400和500℃下,接头的抗拉强度分别达到了TiAl母材的91.77%、95.27%和99.21%。     

Synthesis and characterization of geopolymer from lunar regolith simulant based on natural volcanic scoria

In this study, a new GVS（Ground Volcanic Scoria） lunar regolith simulant was produced. The similarity between GVS and lunar soil was proved by comparison with Apollo lunar soil samples and other commercial lunar soil simulants. Then, GVS lunar regolith simulant was investigated as the source material for preparing geopolymer to produce building material for lunar colony construction. To study the possibility of preparing geopolymer from GVS lunar regolith simulant and the optimum activator formu...