N-(5-硝基-6-氯-3-吡啶甲基)邻苯二甲酰亚胺的合成

研究了N-(5-硝基-6-氯-3-吡啶甲基)邻苯二甲酰亚胺的合成方法。该法先在室温条件下以邻苯二甲酰亚胺与氢氧化钾反应合成了邻苯二甲酰亚胺钾。然后在70°C条件下,以邻苯二甲酰亚胺钾作为亲核试剂,与2-氯-5-氯甲基吡啶发生缩合反应,制备了N-(6-氯-3-吡啶甲基)邻苯二甲酰亚胺。缩合产物再经过硝化,合成N-(5-硝基-6-氯-3-吡啶甲基)邻苯二甲酰亚胺,其熔点为143.1~143.8°C,收率为90.5%。用红外光谱(IR)、核磁共振氢谱(1HNM R)、气谱-质谱(GC-M S)解析以确定中间体和产物的结构;用高效液相色谱测定合成产物的含量。实验结果表明合成了具有较高含量和较高收率的产品。     

DD6单晶合金循环蠕变性能研究

采用含与不含气膜孔平板试样,研究了[001]、[011]和[111]晶体取向在980℃不同保载时间和应力条件下的镍基单晶合金DD6的循环蠕变性能。研究发现,DD6单晶合金的高温蠕变疲劳性能存在明显的方向性,试样形状及表面状态是影响单晶合金寿命的重要因素,特别是气膜孔的存在显著地降低了材料的循环蠕变寿命;不含气膜孔平板试样蠕变损伤起主要作用,含气膜孔平板试样疲劳损伤起主要作用。同时,在高温条件下,不同保载时间的蠕变和疲劳损伤对试件的破坏起重要作用,蠕变与疲劳的交互作用会大大缩短材料的使用寿命。     

应用六西格玛方法提高TCAS系统可靠性

在大型民用飞机中,TCAS系统是保证飞机安全运行重要的航电系统之一。本文结合航空公司波音737NG机队运行中TCAS系统的故障情况,介绍了运用六西格玛方法的分析过程,有效地改进了TCAS系统的使用可靠性。     

Investigation on surface integrity of electron beam melted Ti-6Al-4 V by precision grinding and electropolishing

Electron beam melting (EBM), as an excellent Additive Manufacturing (AM) technology, enables the printing of Ti-6Al-4 V alloy for a wide range of applications such as aerospace and biomechanical industries. It improves functionality and integrity of components and negates complexities in assembly processes. However, due to the poor surface and sub-surface integrity represented by the rough surface finish and low dimensional accuracy, achieving a favorable surface condition is quite challenging. Therefore, post processing becomes essential for these electron beam melted (EBM-ed) Ti-6Al-4 V alloys. Being the most common technique to improve such parts, milling of Ti-6Al-4 V alloy is very challenging and resulting tool wear issues, due to its unique material properties. Thus, this paper presents a comprehensive study on the surface integrity of EBM-ed Ti-6Al-4 V parts processed by precision grinding and electropolishing, aiming to qualitatively and quantitatively clarify the interrelation between process parameters and processed surface quality. The surface and subsurface characteristics such as profile accuracy, surface roughness, microstructure, defective layer and residual stress before and after post processing were compared and evaluated. The results show that by precision grinding, the profile accuracy was improved from over 300 µm PV to 7 µm PV, while surface roughness (R_a) was reduced from 30 µm to about 2 µm. The layer with partially melt particles was removed, but introduced a deformed subsurface layer with more residual stress. Then by applying electropolishing, the residual stress was released and the deformed layer was removed. In addition, R_a was further reduced to 0.65 µm. The research can serve as a reference for the integration of post machining processes with AM.     

基于eN-数据库方法复杂构型飞机转捩预测

为探索边界层转捩对大型运输机在起降条件和有较大层流区的巡航条件下的气动力精确计算问题，通过在三维RANS求解器中引入eN-数据库方法来预测飞行器表面的转捩位置，并探索转捩对气动力的影响规律。方法与目前流行的基于间歇因子控制方程的转捩预测方法相比，具有计算效率高、易于工程应用、且考虑TS不稳定性转捩因素的特点。在此基础上，通过计算NASA梯形翼来分析起降构型条件下气动力受转捩影响的规律，并通过计算DLR－F6翼身组合体来探索三维构型在巡航条件下的气动力精度。使用eN-数据库转捩判断方法的计算结果与实验值吻合较好，验证了所构建的基于RANS求解器的eN-数据库转捩预测方法的有效性，并为大型运输机气动力精确计算提供了分析工具。     

Tribological evaluation of surface modified H13 tool steel in warm forming of Ti–6Al–4V titanium alloy sheet

The H13 hot-working tool steel is widely used as die material in the warm forming of Ti–6Al–4V titanium alloy sheet. However, under the heating condition, severe friction and lubricating conditions between the H13 tools and Ti–6Al–4V titanium alloy sheet would cause difficulty in guaranteeing forming quality. Surface modification may be used to control the level of friction force, reduce the friction wear and extend the service life of dies. In this paper, four surface modification methods(chromium plating, TiAlN coating, surface polishing and nitriding treatment)were applied to the H13 surfaces. Taking the coefficient of friction(CoF) and the wear degree as evaluation indicators, the high-temperature tribological behavior of the surface modified H13 steel was experimentally investigated under different tribological conditions. The results of this study indicate that the tribological properties of the TiAlN coating under dry friction condition are better than the others for a wide range of temperature(from room temperature to 500 C), while there is little difference of tribological properties between different surface modifications under graphite lubricated condition, and the variation law of CoF with temperature under graphite lubricated is opposite to that under the dry friction.     

基于变步长CFD/RBD方法的旋转弹轨迹仿真

采用变步长方法实现非定常Navier-Stokes方程和刚体六自由度运动方程的耦合求解,并对美国ARL旋转弹试验模型的飞行轨迹进行了仿真。旋转弹自由飞行过程中受到空气阻力作用,转速下降,气动力变化趋缓。因此轨迹仿真时先选取较小的时间步长,随着转速的下降逐渐增大步长,这样可以减少计算时间。刚体六自由度运动方程的数值求解采用变步长Adams预估校正法。将定步长和变步长两种方法应用于旋转弹实验模型轨迹仿真,并将计算得到的旋转弹空间位置、姿态角与试验结果进行了对比,结果显示:方法能较精确地仿真旋转弹飞行轨迹。在相同初始步长条件下,变步长方法较定步长方法计算时间减半;在相同计算时间条件下,变步长方法较定步长方法精度更高。     

应用6Sigma改进方法提高TCAS系统可靠性

在大型民用飞机中TCAS系统是重要的飞行安全运行的航电系统之一,其故障会对飞机正常营运造成很大的影响。应用6Sigma原理进行维修管理可以有效地改进TCAS系统的可靠性。结合航空公司波音737NG机队的运行中TCAS系统故障情况,介绍运用6Sienna方法的分析过程达到的实际改进效果。     

The AWIATOR airborne LIDAR turbulence sensor

The development and first flight tests are described of a short pulse direct measuring UV LIDAR for the measurement of gusts, turbulence and potentially wake vortices. The results of these stage 1 tests confirm that relative wind velocities can be measured with a standard deviation of below 10 m/s even at high altitudes with no appreciable aerosol concentrations. Operating the system under various flight conditions including rain, dense clouds, and clear air up to 24,000 ft was highly successful. Means to push the standard deviation below 1.6 m/s, foremost by increasing the laser output power and the efficiency of the light collecting system, are identified and quantified. Questions of instrument stability are addressed.