Preparation and Microstructure of Cu/Ti_3SiC_2 Nanocomposite

Mixed micron-sized Cu/Ti3SiC2 (vol5%) powder was mechanically milled using agate balls and zirconia balls separately. Then followed an examination of it with the FEI-SEM. The experimental results show that, distributed homogenously in Cu matrix, the Ti3SiC2 particles have a size of about 30-50 nm after milled with agate balls for 8 h, while it remains approximately unchanged after milled with zirconia balls. The microstructure of the mixture at different ball-milling stages was also studied. Bulks of Cu/Ti3SiC2 nano-composite were fabricated by hot pressing nano-sized Cu/Ti3SiC2 powder at the temperature of 1 073 K under 100 MPa. Then came an investigation of the effects of the particle size and agglomerate state of Ti3SiC2 as well as the microstructure of Cu/Ti3SiC2 nano-composite. It was found that the nano-sized Ti3SiC2 particles distribute evenly in copper.     

Electrolytic Passivation of Nitinol Shape Memory Alloy in Different Electrolytes

The corrosion behavior of the nitinol alloy was studied in various corrosion media of different Cl^- ion concentrations. The results demonstrate that the Cl^- ion concentration has significant influences on the corrosion behavior of the nitinol alloy. In order to enhance the corrosion resistance, protective films were generated on the surface of the nitinol alloy by means of the electrochemical passivation method, for which five different electrolytic solutions were investigated. The surface analysis indicates full growth of all samples passivated in the different electrolytic solutions with layers, however, showing different morphological features. Without any defects like micro-cracks and pores, the surface of the samples passivated in the molybdate solution turns out smoother and denser than those passivated in other solutions. It is shown that the electro-chemical passivation will reduce Ni content but increase Ti content in the surface, reaching the Mole ratio of Ti：Ni = 9.01：1 on the outermost surface. Potentiodynamic polarization test demonstrates that the samples electrochemically passivated in the molybdate solution present a significant increase in breakdown potential due to titanium enrichment on the outermost surface.     

双(口恶)唑啉化合物改性热固性树脂的研究

采用自制2,2′-(1,3-苯)双(4,5-二氢)(口恶)唑分别与热塑性酚醛树脂或二氨基二苯甲烷(DADPM)进行聚合反应制得了聚醚酰胺树脂(PEAR)和聚氨基酰胺树脂(PAAR).实验表明PEAR的冲击强度达到6 kJ/m2以上,弯曲强度达到100MPa以上,且电绝缘性能优良,可作为H级绝缘材料使用;PAAR的冲击强度最高达到22kJ/m2,弯曲强度达到202 MPa,电绝缘性能较PEAR稍差,但仍然可作为H级绝缘材料使用,另外还可望作为无卤阻燃材料使用.以这两种高性能热固性树脂为基体可制备出性能优良的玻璃布复合材料.     

30CrMnSiNi2A和GC4（40CrMnSiMoVA）钢裂纹扩展性能比较分析研究

在分析30CrMnSiNi2A和GC4力学性能的基础上,在相同裂纹长度条件下,对两种材料的裂纹扩展寿命和裂纹扩展速率的统计特性进行了统计研究。经比较分析后认为,由于30CrMnSiNi2A钢的裂纹扩展速率较慢,故裂纹扩展寿命较长,但由于其分散性较大,在裂纹长度较大时,99.9%的安全寿命尽管仍比GC4钢大,但两者已很接近。     

纳米铁酸铜的制备及对RDX热分解的催化作用

以CuCl2·2H2O和Fe(NO3)3·9H2O为原料,采用室温固相化学反应法制备出三种不同铜、铁摩尔质量比的纳米CuFe2O4粉体,产物的粒径约为5nm。采用差示扫描量热法(DSC)测试了纳米CuFe2O4对RDX热分解的催化作用。结果表明:纳米CuFe2O4对RDX热分解有明显的催化效果。在三种纳米CuFe2O4中,铜、铁摩尔质量比为1∶1的纳米CuFe2O4的催化效果最好,它使RDX的分解峰温前移了17 8℃,放热量增加了250J/g,活化能降低了21 9kJ/mol。纳米CuFe2O4的用量增加对RDX热分解的催化效果显著增大。     

水泥生产的在线故障诊断系统的设计

是否能实现在线状态监测与故障实时诊断,是集散控制系统中能否成功的关键问题之一。本文介绍了一种基于专家系统的水泥生产在线故障诊系统,着重讨论了系统结构、原理、软件的功能及设计方法。     

大气吸气模式激光推进的实验研究

激光推进是一种新概念推进技术,在未来航天事业中将有重要的应用前景。利用高重复频率高功率TEA-CO₂脉冲激光器进行了抛物形飞行器的水平和垂直激光推进实验,实现了大气模式的激光垂直推进,飞行高度超过了1m。实验测定了多种工作状况下光脉冲能量转变为飞行器动量的推进效能,测得的光能－冲量耦合系数C_m达到27.7dyne·s/J,与国外文献报道相当。     

Ti2AlNb基合金的研究进展

着重介绍了Ti2AlNb基合金的成分、显微组织及性能，综述了合金元素及热处理工艺对Ti2Al-Nb基合金组织性能的影响，介绍了Ti2AlNb基合金熔炼凝固特性，并展望Ti2AlNb基合金的未来。     

La2O3对Li2O-Al2O3-SiO2系统微晶玻璃性能的影响

以丙烯酰胺、N，N’-亚甲基双丙烯酰胺、碳酸锂、硝酸铝和正硅酸乙酯为原料，采用丙烯酰胺凝胶法成功地制备出多组分氧化物Li2O-Al2O3-SiO2（LAS）微晶玻璃超微粉末，并掺杂了稀土氧化物La2O3。将粉体压制烧结得到微晶玻璃块体。用IR，XRD，SEM等测试手段研究了掺杂对微晶玻璃组织与性能的影响，测定了微晶玻璃的热膨胀系数。实验表明：La2O3的加入使微晶玻璃的相变温度降低到900℃；掺杂后微晶玻璃的粒径减小；丙烯酰胺凝胶法制备的Li2O-Al2O3-SiO2（LAS）微晶玻璃热膨胀系数达到10^2数量级，掺La2O3，使Li2O-Al2O3-SiO2（LAS）微晶玻璃的热膨胀系数增大。     

The primordial Helium-4 abundance determination: systematic effects

By extrapolating to O/H = N/H = 0 the empirical correlations Y–O/H and Y–N/H defined by a relatively large sample of 45 Blue Compact Dwarfs (BCDs), we have obtained a primordial ⁴Helium mass fraction Y _p=0.2443±0.0015 with dY/dZ=2.4±1.0. This result is in excellent agreement with the average Y _p=0.2452±0.0015 determined in the two most metal-deficient BCDs known, I Zw 18 (Z /50) and SBS 0335–052 (Z /41), where the correction for He production is smallest. The quoted error (1) of 1% is statistical and does not include systematic effects. We examine various systematic effects including collisional excitation of hydrogen lines, ionization structure and temperature fluctuation effects, and underlying stellar Hei absorption, and conclude that combining all systematic effects, our Y _p may be underestimated by 2–4%. Taken at face value, our Y _p implies a baryon-to-photon number ratio =(4.7^+1.0 _–0.8)×10^–10 and a baryon mass fraction _b h ² ₁₀₀=0.017±0.005 (2), consistent with the values obtained from deuterium and Cosmic Microwave Background measurements. Correcting Y _p upward by 2–4% would make the agreement even better.