提高聚丙烯腈基碳纤维原丝质量的研究进展

概述了世界主要聚丙烯腈（PAN）基碳纤维生产厂家在各自生产工艺下的碳纤维原丝或碳纤维的质量状况。综述了提高PAN基碳纤维原丝质量的研究进展。重点讨论了我国以丙烯腈（AN）、丙烯酸甲酯（MA）、衣康酸（ITA）为单体，以硫氰酸钠（NaSCN）为溶剂，采用一步法均相溶液聚合制得聚丙烯腈原液，经纺丝制得碳纤维原丝过程中存在的问题。指出我国原丝质量不能真正过关的根本原因，提出了我国现阶段碳纤维的发展方向。     

Physiologic and metabolic responses of wheat seedlings to elevated and super-elevated carbon dioxide

The metabolic consequence of suboptimal (400 μmol mol⁻¹ or ppm), near-optimal (1500 ppm) and supra-optimal (10,000 ppm) atmospheric carbon dioxide concentrations [CO₂] was investigated in an attempt to reveal plausible underlying mechanisms for the differential physiological and developmental responses to increasing [CO₂]. Both non-targeted and targeted metabolite profiling by GC–MS and LC–MS were employed to examine primary and secondary metabolites in wheat (Triticum aestivum, cv Yocoro rojo) continuously exposed to these [CO₂] levels for 14, 21 and 28 days. Metabolite profile was altered by both [CO₂] and physiological age. In general, plants grown under high [CO₂] exhibited a metabolite profile characteristic of older plants under ambient CO₂. Elevated [CO₂] resulted in higher levels of phosphorylated sugar intermediates, though no clear trend in the content of reducing sugars was observed. Transient starch content was enhanced by increasing [CO₂] to a much greater extent at 10,000 ppm CO₂ than at 1500 ppm CO₂. The percentage increase of starch content resulting from CO₂ enrichment declined as plants develope. In contrast, elevated [CO₂] promoted the accumulation of secondary metabolites (flavonoids) progressively to a greater extent as plants became mature. Elevated [CO₂] to 1500 ppm induced a higher initial growth rate, while super-elevated [CO₂] appeared to negate such initial growth promotion. However, after 4 weeks, there was no difference in vegetative growth between 1500 and 10,000 ppm CO₂-grown plants, both elevated CO₂ levels resulted in an overall 25% increase in biomass over the control plants. More interestingly, elevated atmospheric [CO₂] reduced evapotranspiration rate (ET), but further increase to the supra-optimal level resulted in increased ET (a reversed trend), i.e. ET at 1500 ppm < ET at 10,000 ppm < ET at 400 ppm. The differential effect of elevated and super-elevated CO₂ on plants was further reflected in the nitrogen dynamics. These results provide the potential metabolic basis for the differential productivity and stomatal function of plants grown under elevated and super-elevated CO₂ levels.     

Three dimensional investigation of the shock train structure in a convergent–divergent nozzle

Three-dimensional computational fluid dynamics analyses have been employed to study the compressible and turbulent flow of the shock train in a convergent–divergent nozzle. The primary goal is to determine the behavior, location, and number of shocks. In this context, full multi-grid initialization, Reynolds stress turbulence model (RSM), and the grid adaption techniques in the Fluent software are utilized under the 3D investigation. The results showed that RSM solution matches with the experimental data suitably. The effects of applying heat generation sources and changing inlet flow total temperature have been investigated. Our simulations showed that changes in the heat generation rate and total temperature of the intake flow influence on the starting point of shock, shock strength, minimum pressure, as well as the maximum flow Mach number.     

Friction and Wear Properties of Amorphous Carbon Nitride Coatings in Water Lubrication

The friction and wear properties of amorphous carbon nitride(a-CN x)coatings in water lubrication were reviewed.The influences of mating materials and tribological variables such as normal load(W)and sliding speed(V)on the friction and wear properties of the a-CN x coatings were analyzed.It was indicated that the specific wear rate of the a-CN x coatings was related to the hydration reaction of mating materials with water.If the mating materials were easily hydrated,the specific wear rate of a-CN x coatings was low.The water-lubricated properties of the a-CN x coatings were better in comparison to the a-C coatings.The a-CN x/Si-based non-oxide ceramics tribo-pairs exhibited the lowest friction coefficient and wear rate.To describe their friction and wear properties at the normal loads of 3—15Nand the sliding speeds of 0.05—0.5m/s,the wear-mechanism maps for the a-CN x/SiC(Si3N4)tribo-pairs in water were developed.     

舰尾流环境中载机纵向QFT/TECS控制系统设计

为了消除舰尾流对载机着舰过程产生的影响,同时完成低动压状态下飞行速度与高度的解耦工作,基于定量反馈理论/总能量控制理论(QFT/TECS)设计了纵向着舰控制系统。针对着舰过程中数学模型所具有的不确定因素及舰尾流对下滑航迹的影响,以载机高度变化率为控制对象,使用定量反馈理论结合推力补偿系统进行了内回路鲁棒控制律设计。外回路控制律设计是以总能量控制理论为基础,通过粒子群优化算法对待调控制参数进行寻优,进而实现了对高度、速度等参数的精确控制,完成了载机纵向着舰轨迹与速度的解耦工作。仿真结果表明,该控制律在拥有较强的鲁棒性的基础上具有良好的解耦控制能力,实现了载机着舰段的高度与速度的解耦控制,明显提高了载机对着舰轨迹的跟踪能力,可满足不确定条件下载机的着舰要求。     

Microstructure,thermophysical property and ablation behavior of high thermal conductivity carbon/carbon composites after heat-treatment

Uni-directional carbon/carbon composites with high thermal conductivity are suitable to supply continuous thermal protection for future reentry vehicles since they could reduce surface temperature and ablation rates simultaneously in harsh environments. In this work, the high thermal conductivity carbon/carbon composites were prepared by chemical vapor infiltration. After heat-treatment, both their open porosity and internal friction increase due to the fiber/matrix thermal expansion mismatch; while their thermal conductive performance become better due to more complete carbon structure. With raising heat-treatment temperature from 1800 °C to 2450 °C, the mass and linear ablation rates of C/C composites with fibers vertical to the oxyacetylene torch for 60 s decrease from 0.66 mg/s and 2.95 μm/s to 0.51 mg/s and 2.05 μm/s respectively. The improved ablation resistance is resulted from the increased thermal conductivity from 282 to 508 W/(m·K) and more carbon fibers exposed to the flame during ablation, which have better oxidation resistance than those of carbon matrix. While such ablation rates become larger for composites with fibers parallel to the flame, from 1.02 mg/s and 3.73 μm/s to 1.28 mg/s and 5.01 μm/s respectively since the ablation occurred more easily through gaps at the fiber/matrix interfaces, which become larger and are always exposed to the flame for this case.     

石英陶瓷与碳纤维增强复合材料间胶接增强的优化工艺

为提高硅橡胶胶黏剂胶接石英陶瓷和碳纤维增强复合材料的强度和耐温性能,研究了胶接面湿热状态、打磨程度、胶层厚度、操作等待时间等工艺参数对胶接强度的影响。在试片正常烘干、打磨的情况下,当胶层厚度为0.4 mm、操作等待时间小于0.5 h时,胶接效果最优,其压缩剪切强度达到了3.06 MPa。探索了底涂剂处理对胶接强度和耐温性能的影响。在温度不高于100℃时,底涂剂A的效果较好。经底涂剂A处理后,胶接试片常温下的强度提高了13.7%,达到3.48 MPa;100℃时的强度提升率达到37.7%。在更高温度下,底涂剂B的效果更为显著。经底涂剂B处理后,胶接试片常温下的强度提升了10.1%,达到3.37 MPa;300℃时的强度提升了44.0%,达到1.57 MPa;200℃时的强度提升率最高,为49.0%。测试结果为高温条件下石英陶瓷胶接结构的胶接工艺优化及其应用提供了参考。     

测点布局对航空发动机总压畸变指数的影响

为了阐明测点布局对航空发动机进气总压畸变测试结果的影响，利用旋转总压测量耙对5种畸变流场的稳态和动态总 压畸变成分进行了测试，计算了旋转总压测量耙位于不同位置时畸变流场的稳态周向总压畸变指数和动态总压畸变指数，分析了 不同测点布局下总压畸变指数计算结果的偏差。结果表明：测量耙/测点与畸变流场的相对周向位置对总压畸变指数计算结果的 准确性至关重要，对于所分析的5种畸变流场，增加测量耙/测点周向数目并不能使总压畸变指数计算结果的偏差单调减小，但可 降低其对测量耙/测点周向位置的敏感度。基于畸变区域周向分布设计稳态总压畸变测量耙的周向位置，组合使用不同相对半径 处测点对动态总压畸变进行监测，可提高总压畸变指数计算结果的准确性。     

基于功率裕度的某型发动机全寿命性能研究

随着使用时间不断增加,研究飞行队所有选装ARRIEL2S系列发动机全寿命性能变化趋势的必要性突显.针对SRRIEL2S系列发动机全寿命性能参数变化特点,提出使用基于可几误差舍弃理论处理发动机功率校验数据,分区间描绘该系发动机全寿命性能指标变化趋势,给出该系发动机全寿命性能特点,为机务工程人员监控该系发动机提供有利依据；提出延长功率校验间隔的假设,并在理论上做了充分论证,为节约该系发动机运行成本提供一个明确及可行的方向.     

FINITE DIFFERENCE MODEL FOR SIMULATION OF DENSIFYING CARBON-CARBON COMPOSITES BY CHEMICAL VAPOR INFILTRATIONP ROCESSES

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