Mg-Zn-Zr-RE系镁合金的显微组织

 应用于航空工业中的MB15镁合金（Mg,5.0～6.0％Zn,0.5～0.9％Zr）为高强度变形镁合金。为进一步提高此合金的强度而添加稀土元素。本文报导含有Y及混合稀土的Mg-Zn-Zr-RE系合金的相组成及其微观形态的研究结果。 试验用合金的化学成分列于表1。表中MM为混合稀土,其中主要元素La10.76％,Nd17.54％,Gd14.60％,Dy14.09％,Y26.88％,此外还有少量Ce、Pr、Ho、Er等。试样用材为铸锭及挤压型材,后者是铸锭经350℃加热2h后挤压而成。     

TMO对铝镁贫氧推进剂低压燃烧性能影响

研究了过渡金属氧化物（TMO）及其复配物对非壅塞固体火箭冲压发动机铝镁贫氧推进剂燃烧特性的影响。研究发现，氧化铁对提高铝镁贫氧推进剂燃速的作用显著。过渡金属氧化物组合（氧化钴／氧化铬和氧化铜／氧化铬）对提高铝镁贫氧推进剂的燃速催化作用显著，且含组合催化剂（氧化钴／氧化铬、氧化铜／氧化铬和氧化铁／氧化铜）的盆氧推进剂具有高的燃速压强指数。     

先进镁合金材料及其在航空航天领域中的应用

文章介绍了上海交通大学轻合金精密成型国家工程研究中心在先进镁合金材料与成型工艺的研究进展,重点介绍了JDM1和JDM2两种镁合金新材料的显微组织与强化机制,详细介绍了涂层转移精密铸造技术、大型铸件低压铸造技术、大型锻件成型技术和表面超声波阳极氧化技术等4种镁合金成型新工艺,最后介绍了JDM1和JDM2合金及成型新工艺在我国航空航天领域中的应用。     

Corrosion Resistance of Ni-P Composite Coating on Mg Alloy： Critical Role of the Intermediate Phosphate Conversion Coating Layer for Suppressing Galvanic Couple Formation

Electroless nickel (EN) plating can give rise to the severe galvanic corrosion of the magnesium (Mg) alloy matrix, owing to its nobler electrochemical potential than Mg alloy. To hinder the formation of galvanic couple, an intermediate phosphate conversion coating (PCC) layer is introduced between the EN layer and the Mg alloy matrix. Since the ceramic-like PCC layer cannot be catalyzed, a low-cost Ag-activation technique is used to process the PCC layer before electroless plating. The cross-section morphology and element distribution of the PCC-EN composite coating indicate that the PCC intermediate layer can effectively separate the Mg alloy from the EN layer. Moreover, the results of electrochemical tests suggest that the PCC-EN composite coating has a better corrosion resistance in comparison with the EN coating and AZ91D Mg alloy.     

连铸连轧镁合金AZ41微观结构与摩擦磨损性能

为研究铸轧镁合金AZ41板材的摩擦磨损性能,通过连铸连轧制备出镁合金AZ41板材,并观察其铸轧态和热处理态的微观组织结构特点。研究了滑动干摩擦条件下滑动速度和载荷对AZ41镁合金板材摩擦磨损性能的影响,采用扫描电镜观察磨损表面形貌,探讨了其磨损机制,并利用有限元方法模拟了其磨损时的应力分布。结果表明：制备的镁合金AZ41在（1012）上出现了大量压缩孪晶,经热处理后晶粒变为等轴晶;摩擦系数随着转速的增加而升高,在一定范围内随载荷的增加而降低;磨损量随着载荷和转速的增加而增加,低载时磨损机制为磨粒磨损,伴有氧化磨损的发生,高载时其磨损以粘着磨损为主。     

镁合金消失模铸造充型过程中模样-金属界面行为的研究

通过直接观察充型过程和金属充型速度的标准方差分析技术研究了抽真空条件下镁合金消失模铸造充型过程中模样-金属界面行为。结果表明：在镁合金的浇注温度下,泡沫模样主要熔解为液态产物。在不抽真空时充型过程主要受模样-金属问热解产物的排除控制,金属前沿充型平稳并呈微凸形,充型速度很小并持续降低。然而,在抽真空条件下金属充型更多地受模样-金属界面处模样分解控制,金属前沿极不平稳并呈不规则的凹形,在充型过程中金属的充型速度变化很大并且无明显的规律可循。金属的充型速度随真空度提高而迅速增大,真空度与浇注温度对充型速度的影响具有很强的交互作用;进一步提高真空度,浇注温度成为影响充型过程最重要的因素,而真空度以及真空度与浇注温度的交换作用对充型速度的影响大为减弱。基于以上研究,提出了负压条件下镁合金消失模铸造充型过程中模样-金属界面处模样的热解和热解产物的排除行为模型。     

航空航天用高强度Mg-RE系合金的研究进展

近年来，镁稀土合金由于其高强度、低密度和高温性能良好等特点，在追求轻量化的航空航天产业当中受到越来越多的关注。总结当前主流的2系高强度Mg-RE合金(Mg-Gd和Mg-Y系合金)的性能特点、强化机制和研究进展，简要介绍其他Mg-RE合金的研究情况，最后回顾镁稀土合金在航空航天领域的应用。     

Research on Residual Stress Measurement of Magnesium Alloy Cabin Castings

Owing to the nonuniform wall thickness and complex internal structure， the measurement of the residual stress on magnesium alloy cabin castings is complex and difficult extremely， and thus seldom research has focused on the residual stress of magnesium alloy castings. In this paper， the blind-hole method， the X-ray diffraction (XRD) method， and the contour method are used to conduct comprehensive and systematic residual stress tests for a magnesium alloy cabin casting. The results show that the residual stress on the surface of the casting obtained by the blind-hole method is between -20.03 MPa and -71.03 MPa， the residual stress obtained by the XRD method is between -26.01 MPa and -87.11 MPa， while the residual stress obtained by the contour method is between -45.89 MPa and 76.87 MPa. The study can lay a basis for the subsequent research of magnesium alloy cabin castings， and provide a reference for the residual stress test of magnesium alloy castings.     

Study on the Deformation Behavior of Mg-Gd-Y-Zn-Mn Wrought Magnesium Alloys by Visco-plastic Self-consistent Modeling

The plastic deformation behavior of new Mg-Gd-Y-Zn-Mn magnesium alloys gains great necessity to clarify and understand the mechanism deeply. In the present work， the tensile mechanical property test and visco-plastic self-consistent (VPSC) model are used to investigate the activities of deformation modes of VW84M and VW94M magnesium alloys during the tensile deformation. The results show that the mechanical properties of the above extruded alloys are similar but VW94M has higher strength than VW84M after the same aging process. Compared with the extruded alloys， the as-aged alloys have significantly higher activation of pyramidal slip at the later stage of plastic deformation. In addition， the as-aged VW94M alloy with higher strength has the largest activity of pyramidal slip. In summary， the addition of Gd increases the critical resolved shear stress (CRSS) in each slip system of VW94M， while the increase in the strength and the decrease in the elongation of as-aged alloys are associated with the significant activation of pyramidal slip.     

Microstructure and Hot Deformation Behavior of Mg-9Al-3Si-0.375Sr-0.78Y Alloy

Using Gleeble-3500 thermal simulator， the high temperature plastic deformation behavior and microstructure evolution of Mg-9Al-3Si-0.375Sr-0.78Y alloy are investigated at the temperature of 523 K?673 K and the strain rate of 10-3 s-1?10 s-1. True strain-true stress curves show the characteristics of the typical dynamically recrystallization process. The Arrhenius constitutive equation of the hyperbolic model is established. The average activation energy and the strain rate sensitivity index are， respectively， 221.578 kJ.mol-1 and 0.137. The result shows that the α-Mg phase exhibits dynamic recrystallization (DRX) characteristics obviously. But no DRX occurs in theβ-Mg17Al12 phase. Hot deformation does not affect the primary Mg2Si phase. Under the conditions of low temperature (523 K?673 K) and high strain rate (1 s-1?10 s-1)， the flow instability and macro-defects such as crack appear in the specimens. However， there are finer recrystallization grains. Under the conditions of high temperature (≥673 K) or low strain rate， the microstructure of the alloy shows good homogeneity. The size of the primary Mg2Si phase is uniform， the size of the β-Mg17Al12 phase is small， and the distribution of the β-Mg17Al12 phase is uniform.