负载型钌催化剂的制备及其催化性能

制备了负载型钌催化剂，研究了该催化剂对环十二碳三稀选择性催化加氢的催化活性和催化寿命，得到了环稀烃选择性催化加氢的最佳反应条件，结果表明，该催化剂的催化寿命能满足工业生产的要求。     

Characterization of GPS-TEC over African equatorial ionization anomaly (EIA) region during 2009–2016

This study characterizes total electron content (TEC) measured by Global Positioning System (GPS) over African equatorial ionization anomaly (EIA) region for 2009–2016 period during both quiet geomagnetic conditions (Kp?≤?1) and normal conditions (1?>?Kp?≤?4). GPS-TEC data from four equatorial/low-latitude stations, namely, Addis Ababa (ADIS: 9.04°N, 38.77°E, mag. lat: 0.2°N) [Ethiopia]; Yamoussoukro (YKRO: 6.87°N, 5.24°W, mag. lat: 2.6°S) [Ivory Coast]; Malindi (MAL2; 3.00°S, 40.19°E, mag. lat: 12.4°S) [Kenya] and Libreville (NKLG; 0.35°N, 9.67°W, mag. lat: 13.5°S) [Gabon] were used for this study. Interesting features like noontime TEC bite-out, winter anomaly during the ascending and maximum phases of solar cycle 24, diurnal and seasonal variations with solar activity have been observed and investigated in this study. The day-to-day variations exhibited ionospheric TEC asymmetry on an annual scale. TEC observed at equatorial stations (EIA-trough) and EIA-crest reach maximum values between ～1300–1600 LT and ～1300–1600 LT, respectively. About 76% of the high TEC values were recorded in equinoctial months while the June solstice predominantly exhibited low TEC values. Yearly, the estimated TEC values increases or decreases with solar activity, with 2014 having the highest TEC value. Solar activity dependence of TEC within the EIA zone reveals that both F10.7?cm index and EUV flux (24–36?nm) gives a stronger correlation with TEC than Sunspot Number (SSN). A slightly higher degree of dependence is on EUV flux with the mean highest correlation coefficient (R) value of 0.70, 0.83, 0.82 and 0.88 for quiet geomagnetic conditions (Kp?≤?1) at stations ADIS, MAL2, NKLG, and YKRO, respectively. The correlation results for the entire period consequently reveals that SSN and solar flux F10.7?cm index might not be an ideal index as a proxy for EUV flux as well as to measure the variability of TEC strength within the EIA zone. The estimated TEC along the EIA crest (MAL2 and NKLG) exhibited double-hump maximum, as well as post-sunset peaks (night time enhancement of TEC) between ～2100 and 2300 LT. EIA formation was prominent during evening/post-noon hours.     

Spiral eddies in the Baltic,Black and Caspian seas as seen by satellite radar data

Despite spiral eddies were first seen on the sea surface more than 40 years ago, there is still a lot of uncertainty concerning these eddies. The present paper is aimed to provide the comprehensive results on the occurrence and statistics of small-scale eddies in the three inner seas (the Baltic, Black and Caspian) using satellite synthetic aperture radar (SAR) images. The dataset used includes over 2000 medium resolution Envisat ASAR and ERS-2 SAR images obtained in 2009–2010 in the different parts of the seas mentioned. As a result of the analysis performed ∼14,000 vortical structures were detected. 71% of them were visualized due to surfactant films (“black” eddies), while 29% due to wave/current interactions (“white” eddies). Practically all the eddies detected were cyclonically rotating. Their diameter was within 1–20 km. Characteristic size of the “black” eddies in all the basins was discovered to be less than that of the “white” eddies. Characteristic eddy size for the Baltic, Black and Caspian seas proved to be strictly proportional to the values of the baroclinic Rossby radius of deformation typical for these basins. The “black” eddies did not demonstrate a significant connection with the basin- and meso-scale surface circulation of the seas. Most of the “white” eddies detected were attributed to the zones with the most intense drift currents, i.e. those along the western boundaries and (in the Baltic Sea only) in the elongated parts of the basin.     

三元甘氨酰-L-缬氨酸-铜(Ⅱ)-多吡啶配合物SOD活性及电化学性质

应用改进的氯化硝基四氮唑蓝(NBT)光照还原法研究了甘氨酰-L-缬氨酸-铜(Ⅱ)-多吡啶型配合物:[Cu(Gly-L-Val)(Phen)]·3H_2O (1)、[Cu(Gly-L-Val)(Tatp)]·2H_2O (2)、[Cu(Gly-L-Val)(Dppz)]·2H_2O (3) [其中:Gly-L-Val =甘氨酰-L-缬氨酸;Phen=1,10-邻菲咯啉;Tatp=1,4,8,9-四氮三联苯;Dppz=二吡啶并(3,2-a:2',3'-c)吩嗪]在水溶液中催化超氧阴离子自由基(O_2~-·)歧化分解活性,并用循环伏安法研究了配合物的电化学性质.结果表明:3种配合物均具有良好的SOD活性,表观催化速率常数分别为1.03×10~7、0.96×10~7 和 0.79×10~7 L·mol~(-1)·s~(-1).     

Variation of ionospheric electron and ion temperatures during periods of minimum to maximum solar activity by the SROSS-C2 satellite over Indian low and equatorial latitudes

To study the variation of ionospheric electron and ion temperatures with solar activity the data of electron and ion temperatures were recorded with the help of Retarding Potential Analyzer payload aboard Indian SROSS-C2 satellite at an average altitude of ∼500 km. The main focuses of the paper is to see the diurnal, seasonal and latitudinal variations of electron and ion temperatures during periods of minimum to maximum solar activity. The ionospheric temperatures in the topside show strong variations with altitude, latitude, season and solar activity. In present study, the temperature variations with latitude, season and solar activity have been studied at an average altitude ∼500 km. The peak at sunrise has been observed during all seasons, in both electron and ion temperatures. Further, the ionospheric temperatures vary with latitude in day time. The latitudinal variation is more pronounced for low solar activity than for high solar activity.     

Ionospheric variation at Thailand equatorial latitude station: Comparison between observations and IRI-2001 model predictions

In this paper, the F2-layer critical frequency (foF2) and peak height (hmF2) measured by the FM/CW ionosonde at Thailand equatorial latitude station, namely Chumphon (10.72°N, 99.37°E, dip 3.22) are presented. The measurement data during low solar activity from January 2004 to December 2006 are analyzed based on the diurnal, seasonal variation. The results are then compared with IRI-2001 model predictions. Our study shows that: (1) In general, both the URSI and CCIR options of the IRI model give foF2 close to the measured ones, but the CCIR option produces a smaller range of deviation than the URSI option. The agreement during daytime is generally better than during nighttime. Overestimation mostly occurs in 2004 and 2006, while underestimation is during pre-sunrise hours in June solstice in 2005. The peak foF2 around sunset is higher during March equinox and September equinox than the other seasons, with longer duration of maximum levels in March equinox than September equinox. Large coefficients of variability foF2 occur during pre-sunrise hours. Meanwhile, the best agreement between the observed foF2 and the IRI model is obtained in June solstice. (2) In general, The IRI (CCIR) model predicts the observed hmF2 well during daytime in June solstice from 2004–2006, but it overestimates during March equinox, September equinox and December solstice. For nighttime, the model overestimates hmF2 values for all seasons especially during March equinox and September equinox. However, the model underestimates hmF2 values during September equinox and for some cases during June solstice and December solstice at pre-sunrise. The agreement between the IRI model and the hmF2(M3000_OBS) is worst around noontime, post-sunset and pre-sunrise hours. All comparative studies give feedback for new improvements of CCIR and URSI IRI models.     

2005年8月24日强磁暴事件对高层大气密度的扰动

对2005年8月24日发生的突发型强磁暴(Kp峰值达到9)事件,利用星载大气密度探测器在轨实时的连续探测数据进行了处理和分析.结果表明,此次强磁暴事件期间,引起560 km高度附近大气密度剧烈扰动,并存在着两种响应过程.一种是跟随地磁扰动程度变化的全球性大气密度涨落变化,响应时间滞后6h左右, 最大涨落变化比为2.5;另一种为磁暴峰期出现在高纬地区的大气密度突发性跃增,增变比高达5.5.后者存在着区域上的不对称性及时间上的突发性和增幅的差异.此次强磁暴峰期还同时出现了南北半球高纬地区的大气密度跃增双峰.同时还表明这种增变峰可能存在着由高纬向低纬地区迅速推移的现象,在中纬地区推移速度可达15°/h(纬度)左右.      

Probing the method of correcting Faraday rotation in vector magnetograms

By analyzing the vector magnetograms of Huairou Solar Observing Station (HSOS) taken at the line center (0.0 Å) and the line wing (−0.12 Å) of FeI λ5324.19 Å, we make an estimate of the measured errors in transversal azimuths (δ?) caused by Faraday rotation. Since many factors, such as the magnetic saturation and scattered light, can affect the measurement accuracy of the longitudinal magnetic field in the umbrae of sunspots, we limit our study in the region ∣B_z∣ < 800 G. The main mean azimuth rotations are about 4°, 6°, 7° and 9°, while ∣B_z∣ are in the ranges of 400–500 G, 500–600 G, 600–700 G and 700–800 G, respectively. Moreover, we find there is also an azimuth rotation of about 8° at the wavelength offset −0.12 Å of the line compared against a previous numerical simulation.     

多孔板水升华器试验研究

探索了多孔板的制造方法,设计了水结器试验单元件和试验装置;对不同的多孔板升华器进行了试验研究,试验重点研究了热流体入口温度和流量、多孔板物理参数、给水室压力及升华器放置情况对升华器性能的影响。试验结果证明文章提出的升华器基本的设计概念是可行的,并给出了关于水升华器进一步设计的一些有益的结论。     

Some Properties of Microwave Emission From Flaring Regions

A study is made of the differences in the polarization distribution and other characteristics of microwave emission for several active regionswith high flare productivity. Conclusions are drawn about the magnetic field structure of these regions at coronal heights.