非合金结构钢低铬表面达克罗工艺与性能研究

本文主要研究复合添加硼酸和磷酸取代传统达克罗涂液中的铬酐以制取低铬达克罗的配方和工艺,降低了该涂层在工艺和应用中对环境的危害。通过实验配方和工艺参数的变化,对低铬达克罗的组织结构及相关性能进行分析研究,以得到各方面性能较好的低铬达克罗涂液配方及涂层。     

Enhanced electromagnetic-interference shielding effectiveness and mechanical strength of Co-Ni coated aramid-carbon blended fabric

An efficient method was proposed to prepare high-performance conductive Aramid-Carbon Blend Fabrics (ACBF) with cobalt–nickel (Co-Ni) alloy coatings, which is conducive to industrial production. The grid-like substrate composed of aramid and carbon fibers was innovatively used in flexible Electromagnetic Interference (EMI) shielding materials. The natural network structure is advantageous to the uniform deposition of metal particles to the establishment of conductive pathways subsequently in order to improve conductivity. The induction of a synergistic effect from Electromagnetic (EM) wave-reflection and EM wave-absorption through the whole carbon-Co-Ni-ternary system notably enhanced the EMI Shielding Effectiveness (SE) value to an average of 42.57 dB in the range of 30–6000 MHz. On the other hand, together with the inherent toughness of the alloy coatings, the tensile strength of the aramid fibers used for bulletproof made a significant contribution to the desired mechanical properties. The light weight of the resultant composite made it applicable to aerospace vehicles simultaneously. X-ray Photoelectron Spectroscopy (XPS) was conducted to investigate the variations of elements and groups on the sample surface in pre-treating process. The elemental components and surface morphologies of fabric samples during different stages of the process were investigated by Scanning Electron Microscope (SEM) and Energy Dispersive spectrometer (EDX) measurements. X-Ray Diffraction (XRD) results indicated that the obtained Co-Ni alloy coating had a combined Hexagonal Closed-Packed (HCP) and Faced-Centered Cubic (FCC) crystalline phase. The relatively high corrosion resistance demonstrated in different acid and alkaline conditions was instrumental in more complex environments as well.     

Corrosion Resistance of Ni-P Composite Coating on Mg Alloy： Critical Role of the Intermediate Phosphate Conversion Coating Layer for Suppressing Galvanic Couple Formation

Electroless nickel (EN) plating can give rise to the severe galvanic corrosion of the magnesium (Mg) alloy matrix, owing to its nobler electrochemical potential than Mg alloy. To hinder the formation of galvanic couple, an intermediate phosphate conversion coating (PCC) layer is introduced between the EN layer and the Mg alloy matrix. Since the ceramic-like PCC layer cannot be catalyzed, a low-cost Ag-activation technique is used to process the PCC layer before electroless plating. The cross-section morphology and element distribution of the PCC-EN composite coating indicate that the PCC intermediate layer can effectively separate the Mg alloy from the EN layer. Moreover, the results of electrochemical tests suggest that the PCC-EN composite coating has a better corrosion resistance in comparison with the EN coating and AZ91D Mg alloy.