Preparation and Characterization of Fe3O4/T-ZnOw Composites

Fe3O4/T-ZnOw composites are fabricated by depositing a layer of Fe3O4 film on the surface of tetrapod-shaped ZnO whisker (T-ZnOw) by ferrite plating method. The morphology, structure and magnetic properties of the composites are characterized by scanning electron microscopy (SEM), X-ray diffractometer (XRD) and vibrating-sample magnetometer (VSM), respectively. The effects of temperature and pH value of ferrite plating on the Fe3O4/T-ZnOw composites and the magnetic properties of composites are studied. It is shown that the chemical environment with pH value at 7.5 is most favorable for the ferrite plating processes by analyzing the main peaks intensity of Fe3O4 in the XRD patterns and the average diameters of the Fe3O4 crystalline. The increase of the ferrite plating temperature with pH value around 7.5 benefits the whole encapsulation of T-ZnOw by the Fe3O4 magnetic films. The composites exhibit ferromagnetic properties and show much lower magnetization intensity than bulk samples at the same magnetic field intensity.     

基于选择性激光烧结的结构电路一体化技术研究

为了实现结构电路一体化部件的快速制造,本文提出将增材制造技术与结构电路一体化技术相结合。传统结构电路一体化工艺基于注塑成形技术,成本高、周期长,难以实现快速制造与迭代设计。本文提出基于选择性激光烧结(Selective laser sintering,SLS)技术,开展结构电路一体化的制造工艺研究,该技术具有成型速度快、精度高等特点。尝试以激光烧结方式实现成形,随后进行激光活化和化学镀。试验结果表明可以在成形件表面快速制造出具有优良导电性能的镀铜区域。     

Al—Li合金表面的化学镀镍

介绍了Ａｌ－Ｌｉ合金表面化学镀镍的工艺方法，镀层结合力测试以及孔隙率、氯化钠浸泡试验表明，化学镀镍层可能成为Ａｌ－Ｌｉ合金这一新型航空航天材料的良好防护层。     

稀土钇提高离子镀TiN膜层与基体结合力的研究

研究了稀土钇不同含量时对离子镀ＴｉＮ膜层与基体结合力的影响．用扫描电镜，俄歇谱仪，Ｘ射线衍射等手段，对加入稀土钇的ＴｉＮ膜层作了分析。结果表明，加适量稀土钇后，ＴｉＮ膜层与基体的结合力大大提高。其微观机制是，加稀土钇后，膜层相组成发生变化，在膜－基之间形成一过渡层，塑性相（Ｔｉ相）增加，脆性相（Ｔｉ２Ｎ）减少，从而减小了膜－基界面间的应力。此外，结果还表明，稀土钇能明显提高镀膜过程中钛料蒸发率，使成膜速率增加，在相同镀膜时间内ＴｉＮ膜层加厚。     

离子镀TiN膜层扩散壁障作用的试验研究

利用离子镀方法在基体与耐热涂层之间予先沉积一层ＴｉＮ膜层，作为扩散壁障（中间阻挡层），进行了高温阻扩散试验研究，并应用光镜、电镜、Ｘ射线衍射仪及电子探针等手段对试样氧化区域进行了分析。结果表明，有ＴｉＮ中间层试样、其高温抗氧化性明显提高，ＴｉＮ层在一定温度范围内有良好的稳定性和阻扩散作用；在本试验范围内，ＴｉＮ中间层厚度增加阻扩散效果增强。     

镀镍碳纳米管的制备及电磁性能

将碳纳米管经过纯化、敏化、活化处理后,采用化学镀方法制备镀镍碳纳米管,利用DSC分析出合适的热处理温度,然后在惰性气体保护下进行退火处理.利用TEM、EDS、XRD对退火前后镀镍碳纳米管的形貌、元素组成、结构进行表征.结果表明:碳纳米管表面被成功镀上了一层镍磷合金,热处理后镀层更光滑,并发生晶化反应得到晶态镍,使得电磁性能得到较大提升.电性能测试表明,镀镍碳纳米管的电导率为450 S/m,热处理后提高到1400 S/m.磁性能测试表明,镀镍碳纳米管热处理前后均表现为软磁性,热处理前饱和磁化强度为2.753 emu/g,热处理后提高到11.254 emu/g.     

基于Ti/TiN薄膜传感器的飞机金属结构裂纹监测

针对飞机金属结构在服役过程中的裂纹实时监测需求,提出一种Ti/TiN导电薄膜与电位监测原理相结合的结构裂纹监测研究方案。首先,通过真空离子镀膜技术在结构易于出现裂纹的部位制备了Ti/TiN薄膜传感器。然后,进行了传感器膜层与2A12-T4铝合金基体的损伤一致性验证。结果表明,传感器与基体具有良好的损伤一致性。最后,进行了两组基于Ti/TiN薄膜传感器的裂纹监测试验,主要研究结构裂纹与传感器电位之间的相互关系,并对两组电位监测结果进行对比。结果表明,通过分析Ti/TiN薄膜传感器电位的变化可以实现对2A12-T4铝合金结构裂纹萌生和扩展进行实时监测,两组试验的电位监测结果具有良好的重复性。     

基于柠檬酸金钾的电镀金工艺研究

针对现有的有氰镀金体系镀液含有有毒的氰化物,废液污染环境、处理困难等问题,提出低危害电镀金工艺实验研究。为了极大减少溶液在实验过程中电离出游离态氰离子,选择柠檬酸金钾作为电镀金溶液配方主盐。在既定的溶液配方基础上,改变电场、流场、冲液方式、阴阳极间距等参数,优化实验工艺,在紫铜基体上进行基础实验,得到结晶晶粒细致,与基底结合力高,表面光亮度好的电镀层。采用原子力量微镜(Atomic force microscope,AFM)测试了基体和镀层的微观形貌,镀金层有效复制,基体表面的粗糙度降低。应用扫描电子量微镜(Scanning election mircroscope,SEM)分析了镀层的组成成份,并用WS-97涂层附着力划痕试验仪检测了镀层的结合力,其性能满足行业标准的要求。     

Crack monitoring method based on Cu coating sensor and electrical potential technique for metal structure

Advanced crack monitoring technique is the cornerstone of aircraft structural health monitoring.To achieve real-time crack monitoring of aircraft metal structures in the course of service,a new crack monitoring method is proposed based on Cu coating sensor and electrical potential difference principle.Firstly,insulation treatment process was used to prepare a dielectric layer on structural substrate,such as an anodizing layer on 2A12-T4 aluminum alloy substrate,and then a Cu coating crack monitoring sensor was deposited on the structure fatigue critical parts by pulsed bias arc ion plating technology.Secondly,the damage consistency of the Cu coating sensor and2A12-T4 aluminum alloy substrate was investigated by static tensile experiment and fatigue test.The results show that strain values of the coating sensor and the 2A12-T4 aluminum alloy substrate measured by strain gauges are highly coincident in static tensile experiment and the sensor has excellent fatigue damage consistency with the substrate.Thirdly,the fatigue performance discrepancy between samples with the coating sensor and original samples was investigated.The result shows that there is no obvious negative influence on the fatigue performance of the 2A12-T4 aluminum alloy after preparing the Cu coating sensor on its surface.Finally,crack monitoring experiment was carried out with the Cu coating sensor.The experimental results indicate that the sensor is sensitive to crack,and crack origination and propagation can be monitored effectively through analyzing the change of electrical potential values of the coating sensor.     

基于表面技术的气动模型精密加工应用研究

表面技术应用于超高速气动实验模型的加工中,结果表明大大提高了模型的寿命,传统机械加工与表面工程相融合是气动模型加工新的复合工艺。