血药浓度在位检测仪的光路设计

介绍了血药浓度在位检测仪的光路设计，重点阐述发如何降低光能的损耗。该仪器利用Ｙ型光纤束把紫外光照射到血液中的药物上，再把药物发出的荧光收集并送到检测器，其信号供计算机实时采集。     

正电子素的络合作用

本文介绍了正电子素及其络合作用。讨论了正电子素络合反应速度常数的测量方法。比较了几种线性自由能的表达式。     

An icy mineralogy package (IMP) for in-situ studies of Titan’s surface

We describe the scientific case for and preliminary design of an instrument whose primary goal is to determine the chemistry (element abundance) and mineralogy (compound identity and abundance) of Titan’s surface using a combination of energy dispersive X-ray fluorescence spectroscopy (EDXRF) and X-ray diffraction (XRD). XRD is capable of identifying any crystalline substance present on Titan’s surface at relative abundances greater than ∼1 wt%, allowing unambiguous identification of, for example, structure I and II clathrates (even in the presence of ice), and various organic solids, which may include C₂H₂, C₂H₄, C₄H₂, HCN, CH₃CN, HC₃N, and C₄N₂). The XRF component of the instrument will obtain elemental abundances for 16 < Z < 60 with minimum detection limits better than 10 ppm (including detection of atmospheric noble gas isotopes), and may achieve detection limits of 0.01–1% for lighter elements down to Z = 6 (carbon). The instrument is well suited to integration with other analytical tools as part of a light-weight surface chemistry and mineralogy package. Although considerably less sensitive to elemental abundance than GC–MS (10⁻² vs. 10⁻⁸) it is likely to be significantly lighter (<0.5 kg vs. 10 kg).     

CMP加工过程中加工载荷对液膜厚度的影响分析

本文采用激光诱导荧光技术(LIF)来研究抛光参数对化学机械抛光加工区液膜厚度的影响.研究表明,抛光液膜厚度随着抛光载荷的增加而减少,减小的趋势随抛光载荷的提高而减缓.同时液膜厚度随着抛光速度的增加而变大.通过抛光参数的变化对抛光液液膜厚度影响的分析,为改善CMP加工工艺提供理论性的依据.     

Effects of UV-B radiation on photosynthesis activity of Wolffia arrhiza as probed by chlorophyll fluorescence transients

The higher plant Wolffia arrhiza is regarded to be well suited concerning the provision of photosynthetic products in the cycle of matter of a Controlled Ecological Life Support System (CELSS) to be established in the context of extraterrestrial, human-based colonization and long-term space flight. Since UV radiation is one major extraterrestrial environmental stress for growth of any plant, effects of UV-B radiation on W. arrhiza were assessed in the present study. We found that UV-B radiation significantly inhibited photosynthetic CO₂ assimilation activity, and the contents of chlorophyll a, chlorophyll b (Chl a, Chl b) and carotenoids considerably decreased when plants were exposed to UV-B radiation for 12 h. High UV-B radiation also declined the quantum yield of primary photochemistry (φ_po), the quantum yield for electron transport (φ_Eo) and the efficiency per trapped excitation (Ψ_o) in W. arrhiza simultaneously, while the amount of active PSII reaction centers per excited cross section (RC/CS) and the total number of active reaction centers per absorption (RC/ABS) had comparative changes. These results indicate that the effects of UV-B radiation on photosynthesis of W. arrhiza is due to an inhibition of the electron transport and via inactivation of reaction centers, but the inhibition may take place at more than one site in the photosynthetic apparatus.     

基于PLIF技术的气氧/气甲烷同轴剪切喷嘴试验

以数值仿真的结果作为参考,开展了基于PLIF(平面激光诱导荧光)技术、高速摄影技术等非接触光学燃烧诊断技术的气氧/气甲烷同轴剪切喷嘴试验研究。通过联合光学诊断对不同设计工况的燃烧流场进行诊断测量,获得燃烧室内OH分布,燃烧流场发展演化过程、火焰的结构等信息,对燃烧流场进行详细的分析。研究结果表明:气氧/气甲烷剪切燃烧火焰存在明显的剪切燃烧层,且随着轴向距离的增加,火焰逐渐失稳;随燃氧速度比的增加,流场涡旋作用明显加强,火焰根部稳定段变短,瞬时火焰结构卷曲和褶皱增多;仿真计算的OH分布与试验测得的OH分布相似,仿真模型能够合理预测气氧/气甲烷同轴剪切喷嘴的燃烧流场。      

LiXAlF6:xCe3+(X=Ca,Sr,Ba)的发光研究

光激励发光材料一直是人们竞争研究的对象。为在较短的时间内在发光中心存储更多的电子，要寻找一种荧光材料作为光激励发光材料的增感材料，使光激励发光材料敏化，从而提高光激励发光强度，这是提高激发光源利用率的最佳途径。通过对用紫外光源作激发源的光激励发光材料发光机理的研究，确定在紫外波段靠近短波方向的光可能使这种光激励发光材料敏化。Ce^3＋在氟化物体系中的发射通常位于紫外波段，对Ce^3＋掺杂浓度为x的LiXAlF6：xCe^3＋（X=Ca，Sr，Ba，x=0．002～0．012mol）一系列荧光材料作了研究，研究其发光是否在紫外波段，哪种基质更适合需要。采用高温固相法制备，研究该3种化合物的发射光谱及发射光谱随Ce^3＋掺杂浓度的变化。结果找到了最有可能作为用紫外光源作激发源的光激励发光材料的最佳Ce^3＋掺杂浓度的基质LiBaAlF6：xCe^3＋（x=0．010mol）。     

推进剂组分对聚醚聚氨酯粘合剂热氧降解的影响(Ⅰ)硝酸酯增塑剂的影响

采用傅立叶红外光谱和核磁共振技术,研究了硝化甘油（ＮＧ）和１,２,４－丁三醇三硝酸酯（ＢＴＴＮ）两种硝酸酯增塑后的聚醚聚氨酯在空气中９０°Ｃ下的热氧降解。结果表明：ＮＧ,ＢＴＴＮ在聚氨酯粘合剂中的分解产物主要为醇类。这些小分子醇参与了聚氨酯硬段的重聚合反应,形成氨基甲酸酯结构;硝酸酯对聚氨酯粘合剂的热氧降解表现出某种稳定作用,并改变了软段产物结构,使甲酸酯和叔碳结构相对增加;硝酸酯分解产生的ＮＯ２自由基可能与软段降解产生的过氧化氢反应形成硝酸,从而加速了硝酸酯的水解。     

分压力质谱计校准装置的不确定度分析

介绍了分压力质谱计校准装置的结构，工作原理及分压力测量方法，对分压力测量和灵敏度校准的不确定度进行了分析。     

不完备轨道信息下的LEO轨道面内机动检测方法

针对某些因轨道信息不完整而无法直接外推的LEO轨道飞行器的机动检测问题,提出了一种基于轨道摄动影响的面内机动检测方法。该方法将半长轴和偏心率作为检测量,通过分析大气阻力摄动和J 2 项摄动对 LEO 飞行器轨道的影响,从而确定目标飞行器的轨道参数允许边界值,再通过和实际轨道参数进行比较来判定被检测数据点参数是否超出正常范围。最后,采用这种方法对X\|37B飞行器轨道数据进行了仿真验证,共检测出10个机动点,结果表明该方法可以较为准确地利用有限轨道信息检测目标的轨道机动情况。