Ozone trends in the mid-latitude stratopause region based on microwave measurements at Lindau (51.66° N, 10.13° E), the ozone reference model,and model calculations

We compared 8 years of ozone measurements taken at Lindau (51.66° N, 10.13° E) at altitudes between 40 and 60 km using the microwave technique with the CIRA ozone reference model that was established 20 years ago (Keating et al., 1990). We observed a remarkable decrease in ozone density in the stratopause region (i.e., an altitude of 50 km), but the decrease in ozone density in the middle mesosphere (i.e., up to 60 km in altitude) is slight. Likewise, we observed only a moderate decrease in the atmospheric region below the stratopause. Other studies have found the strongest ozone decrease at 40 km and a more moderate decrease at 50 km, which is somewhat in contradiction to our results. This decrease in ozone density also strongly depends on the season. Similar results showed model calculations using the GCM COMMA-IAP when considering the increase in methane. In the lower mesosphere/stratopause region, the strongest impact on the concentration of odd oxygen (i.e., O₃ and O) was observed due to a catalytic cycle that destroys odd oxygen, including atomic oxygen and hydrogen radicals. The hydrogen radicals mainly result from an increase in water vapor with the growing anthropogenic release of methane. The finding suggesting that the stratopause region is apparently attacked more strongly by the water vapor increase has been interpreted in terms of the action of this catalytic cycle, which is most effective near the stratopause and amplified by a positive feedback between the ozone column density and the ozone dissociation rate, thereby chemically influencing the ozone density. However, the rising carbon dioxide concentration cools the middle atmosphere, thereby damping the ozone decline by hydrogen radicals.     

Quasi-biennial oscillation (QBO) of tropical total ozone under alternative QBO scenarios of equatorial stratospheric wind

Equatorial total column ozone variations with quasi-biennial periodicity are described by paying attention to their coupling with the quasi-biennial oscillation (QBO) of zonal wind in equatorial stratosphere. Analysis is made for the 35-year time interval from 1978 to 2013 using the zonal mean total ozone (TOZ) data in latitude band from 5° S to 5° N derived from satellite measurements by means of Total Ozone Mapping Spectrometer (TOMS) and Ozone Monitoring Instrument (OMI). The study was performed using strong seasonal regularities of the wind QBO and the discrete variation of the QBO-period revealed earlier. The forecast of the wind QBO evolution made in Gabis (2012) is fully justified. The comparison between predicted and actually observed changes of the height wind structure shows the prominent accordance, which confirms the forecast validity. It is shown that variations of deseasonalized TOZ are in strong coupling with changes of equatorial wind QBO that coincides with the numerous previous researches. However our results contradict the assumption about quite complicated ozone response in the equatorial region due to continuously varying with time relationship between annual and quasi-biennial cycles and irregularly variable wind QBO-period. The total ozone changes actually observed clearly corresponds to the mean ozone variations calculated for different QBO scenarios and aligned according to the sequence of QBO scenarios already occurred in fact. This close association indicates the possibility of forecasting the equatorial total ozone QBO based on the predicted wind QBO.     

飞机座舱空气净化技术综述

本文指出了飞机座舱空气质量控制的两大途径。根据飞机座舱空气净化技术的发展过程和国内外研究的现状,对不同的座舱空气净化技术和装置进行了总结和比较,包括臭氧转换装置、颗粒污染物净化装置、气态污染物净化装置、新型一次回风净化系统,以及新型的引气系统等,并指出了不同净化技术系统的优势和不足。     

Vertical wavenumber spectra of atmospheric ozone measured from ozonesonde observations

Vertical profiles of ozone have been measured at balloon altitudes. Our purpose is to examine the character of vertical wavenumber spectra of ozone fluctuations, to assess the possible roles of gravity wave field in ozone fluctuations, and to determine dominant vertical wavelengths of ozone spectra. Vertical wavenumber spectra of 12 ozone fluctuations obtained during June–August 2003 are presented. Results indicate that mean spectral slopes in the wavenumber range from 4.69 × 10⁻⁴ to 2.50 × 10⁻³ cyc/m are about −2.91 in the troposphere and −2.87 in the lower stratosphere, which is close to the slope of −3 predicted by current gravity wave saturation models. The consistency of the observed spectral slopes with the value of −3 predicted by current gravity wave saturation models suggests that the observed ozone fluctuations are due primarily to atmospheric gravity waves. At m = 1/(1000 m) the mean spectral amplitude is over 30 times larger in the lower stratosphere than in the troposphere. Mean vertical wavenumber spectra in area-preserving form reveal dominant vertical wavelengths of ∼2.6 km in the troposphere and ∼2.7 km in the lower stratosphere, which is consistent with the values varying between 1.5 and 3.0 km estimated from the velocity field and temperature field at these heights.     

“双顺差”下中国经济隐含的危机

中国的国际收支正处于“双顺差”阶段,一些学者认为“双顺差”是中国经济迅速腾飞的必经阶段,而另一些学者提出“双顺差”正给中国带来巨大的福利损失。文章对“双顺差”的成因进行分析,指出“双顺差”使中国经济孕育的风险增加,环境污染加剧,资源和能源耗竭速度加快,企业遭遇贸易争端的风险增加,政府储备机构承受的风险越来越高。要控制和缓解“双顺差”带来的危机,可采取以下对策：优化利用外资结构,提高外商投资的门槛;优化和提升出口产品结构,禁止战略性资源出口;扩大内需,降低中国经济的对外贸易依存度;适当放松资本管制,但要抑制非法资本的流入;制定鼓励进口的政策,扩大进口贸易。     

Ozone variability related to several SEP events occurring during solar cycle no. 23

Data from geostationary operational environmental satellite (GOES) series were used to identify intense solar energetic particle (SEP) events occurred during the solar activity cycle no. 23. We retrieved O₃, NO, NO₂, HNO₃, OH, HCl and OHCl profiles coming from different satellite sensors (solar occultation and limb emission) and we looked for the mesospheric/stratospheric response to SEPs at high terrestrial latitudes. The chemistry of the minor atmospheric components is analysed to evaluate the associated odd nitrogen (NO_x) and odd hydrogen (HO_x) production, able to cause short (h) and medium (days) term ozone variations. We investigated the effects of SEPs on the polar atmosphere in three different seasons, i.e., January 2005, April 2002 and July 2000. The inter-hemispheric variability of the ozone, induced by the SEP series of January 2005, has been compared with the effects connected both to larger and quite similar events. We found that during SEP events: (i) solar illumination is the key factor driving SEP-induced effects on the chemistry of the polar atmosphere; (ii) even events with limited particle flux in the range 15–40 MeV are able to change the abundance of the minor constituents in the mesosphere and upper stratosphere.     

平流层臭氧和辐射场的季节分布特征

利用美国NCAR化学气候耦合模式WACCM3对平流层温度场、风场、臭氧及辐射场进行了模拟.结果表明,在适宜飞艇长期驻留的准零风层高度20～22km(对应大气压强范围为50～30hPa,以下均采用气压值表征对应大气高度),7-8月风速小于5m·s-1的风带可长期稳定在40°N以北.臭氧空间分布显示,在30hPa气压高度处中国地区臭氧浓度出现了带状分布,30hPa高度以下低纬度地区臭氧浓度低于中纬度地区.平流层太阳加热率的时空变化表明,在平流层上层,太阳加热率可达100×10-6K·s-1,而在平流层下层,只有10×10-6K·s-1.6-8月中国区域的太阳加热率大于9月;在100～30hPa高度内,中纬度地区太阳加热率高于低纬度地区,在30hPa高度以上,低纬度地区太阳加热率高于中纬度地区;8-9月30～40hPa高度处,太阳加热率的空间变化较小.在30hPa高度上,太阳加热率在40°N昼夜变化最大;50hPa高度处,太阳加热率的昼夜变化小于30hPa高度处,而且白天太阳加热率出现极大值的纬度明显靠北.平流层低纬度地区的长波加热率小于中纬度地区.青藏高原由于地形特殊,其6-7月的臭氧浓度、太阳加热率和长波加热率均小于同纬度其他地区.      

短波长紫外辐射变化与臭氧含量涨落之间的关系

位于低纬地区的印度同时测量了短波紫外辐射与臭氧含量,表明臭氧含量下降3%,短波紫外辐射通量(290nm)上升35%.但这个数值大于以往理论预期的数值.本文给出一个简单公式,这个公式描述了臭氧含量的变化与相应的紫外辐射变化之间的关系,用此公式计算得出的结果与印度测得的结果相符,很好地解释了低纬地区的印度测量的臭氧涨落与其相应的短波长紫外辐射变化之间的关系.      

Observations of the ozone and nitrogen dioxide profiles in the TROICA-4 experiment

To investigate the vast area of Russia, a mobile scientific facility based in a railway carriage was developed. It is capable to perform continues measurements being coupled in a passenger train traveling along railroads. It was first equipped with a spectrometer for remote sensing of ozone and nitrogen dioxide in the atmosphere for the transcontinental observations into the chemistry of the atmosphere-4 expedition performed from February 18 to March 5, 1998. A twilight DOAS method, which was applied for retrieval of the nitrogen dioxide profiles basing on spectral measurements at the visible wavelengths (434–451 nm), is described in the paper. Main features of a new algorithm for retrieval of the ozone profile and total content using the differential structure of the UV spectrum (310–335 nm) are presented. The ozone and nitrogen dioxide contents are obtained and shortly validated against available alternative data.     

Study of the seasonal ozone variations at European high latitudes

The geographic area at high latitudes beyond the polar circle is characterized with long darkness during the winter (polar night) and with a long summertime insolation (polar day). Consequentially, the polar vortex is formed and the surrounding strong polar jet is characterized by a strong potential vorticity gradient representing a horizontal transport barrier. The ozone dynamics of the lower and middle stratosphere is controlled both by chemical destruction processes and transport processes.