高校分析化学人才培养模式研究

高校是分析化学人才培养的摇篮,然而,目前高校分析化学人才培养中存在诸多问题,使得高校难以顺应时代对分析化学人才的需求。为此,分析了21世纪分析化学人才应该具备的素质,并以此为基点,探讨了目前高校分析化学人才培养的误区,提出分析化学人才培养模式的调整思路。     

Particle simulation of grid system for krypton ion thrusters

The transport processes of plasmas in grid systems of krypton (Kr) ion thrusters at different acceleration voltages were simulated with a 3D-PIC model, and the result was compared with xenon (Xe) ion thrusters. The variation of the screen grid transparency, the accelerator grid current ratio and the divergence loss were explored. It is found that the screen grid transparency increases with the acceleration voltage and decreases with the beam current, while the accelerator grid current ratio and divergence loss decrease first and then increase with the beam current. This result is the same with Xe ion thrusters. Simulation results also show that Kr ion thrusters have more advantages than Xe ion thrusters, such as higher screen grid transparency, smaller accelerator grid current ratio, larger cut-off current threshold, and better divergence loss characteristic. These advantages mean that Kr ion thrusters have the ability of operating in a wide range of current. Through comprehensive analyses, it can be concluded that using Kr as propellant is very suitable for a multi-mode ion thruster design.     

三氢化铝的合成及性能研究

采用LiAlH4还原AlCl3的方法制备了AlH3,产品的产率大于90%。采用不同的稳定剂对合成的样品进行了稳定化处理,将经处理的样品通过在70℃进行放气量测试比较了热稳定性,发现经稀酸处理的AlH3样品稳定性最好。研究了AlH的安全性能,并通过DSC法研究了AlH与常用推进剂组分的相容性。     

相对论性离子束（环束）流引起的电磁不稳定性

在相对论性框架下，研究了冷离子流产生的右旋共振模，非共振模电磁不稳定性的特征结果表明，非共振模不稳定性增长率受离子流初始参数影响较大，而右旋共振模的增长率则受离子流初始参数影响较小。此结果可应用于太阳高能离子流通过低日冕区和地球磁层辐射带俘获的高能质子情形。     

Coupled Clouds and Chemistry of the Giant Planets— A Case for Multiprobes

In seeking to understand the formation of the giant planets and the origin of their atmospheres, the heavy element abundance in well-mixed atmosphere is key. However, clouds come in the way. Thus, composition and condensation are intimately intertwined with the mystery of planetary formation and atmospheric origin. Clouds also provide important clues to dynamical processes in the atmosphere. In this chapter we discuss the thermochemical processes that determine the composition, structure, and characteristics of the Jovian clouds. We also discuss the significance of clouds in the big picture of the formation of giant planets and their atmospheres. We recommend multiprobes at all four giant planets in order to break new ground.     

凝胶点官能度是重均官能度,还是数均官能度

Flory和Stockmayer等的凝胶化理论用重均官能度表示凝胶点或凝胶生成的临界条件,虽已有50多年的历史,并为各国学者所公认,但从分析凝胶点定义的物理意义出发,只要用简单的数学分析,即可证明用重均官能度而不用数均官能度表示凝胶点,与反应程度定义的物理意义和Flory的两个基本假设不符。凝胶化理论新概念用数均官能度表示凝胶点,则不存在不符的问题。     

海尔-波普彗星离子尾的间断和波动

给出海尔-波普彗星近日点附近大尺度观测的结果.指出:1997年2月16、17和18日海尔-波普彗星等离子尾部分有断尾事件发生.观测时刻的离子尾内物质运动速度约为50km／s;离子尾射线向主尾主轴的并拢速度约为0.080'／s.1997年3月3日海尔-波普彗星离子尾有波动现象发生.波动发生在距离彗星密度中心约130×104km,偏离主轴30°处,振幅约20×104km、其离子束宽度约8×104km、波动的相速度约为200km／s.      

高纬极区电离层中离子声波谱线增强的解释

大量的实验研究表明, 在顶部极光区电离层, 利用EISCAT非相干散射雷达和Millstone Hill雷达可以观测到不对称、增强的离子声波谱线. 考虑到低能H+离子束沉降到背景电离层, 以及电离层顶部O+离子的外流事件, 采用含有场向热流项的双麦克斯韦分布描述H+离子束的分布函数, 进而基于离子－离子双流不稳定性理论来解释增强的离子声波谱线. 场向热流的引入可以减小离子声波谱线的不对称现象, 这样得到的结果更符合实际.      

Improved interpretation of solar wind ion measurements via high-resolution magnetic field data

The Wind   spacecraft’s Faraday cups (FC) continue to produce high-quality, in situ observations of thermal protons (i.e., ionized hydrogen) and α$\alpha$-particles (i.e., fully ionized helium) in the solar wind. By fitting a Wind/FC ion spectrum with a model velocity distribution function (VDF) for each particle species, values for density, bulk velocity, and temperature can be inferred. Incorporating measurements of the background magnetic field from the Wind Magnetic Field Investigation (MFI) allows perpendicular and parallel temperature components to be separated. Prior implementations of this analysis averaged the higher-cadence Wind/MFI measurements to match that of the Wind/FC ion spectra. However, this article summarizes recent and extensive revisions to the analysis software that, among other things, eliminate such averaging and thereby account for variations in the direction of the magnetic field over the time taken to measure the ions. A statistical comparison reveals that the old version consistently underestimates the temperature anisotropy of ion VDF’s: averaging over fluctuations in the magnetic field essentially blurs the perpendicular and parallel temperature components, which makes the plasma seem artificially more isotropic. The new version not only provides a more accurate dataset of ion parameters (which is well suited to the study of microkinetic phenomena), it also demonstrates a novel technique for jointly processing particle and field data. Such methods are crucial to heliophysics as wave-particle interactions are increasingly seen as playing an important role in the dynamics of the solar wind and similar space plasmas.     

The origin of sulfur-bearing species on the surfaces of icy satellites

We present experimental results in order to understand the physico-chemical effects induced by fast ions irradiating sulfur bearing molecules. The experiments are relevant both to Solar System objects (icy satellites, comets, TNOs) and icy mantles on grains in the interstellar medium. Here we concentrate on the application to the Galilean moons that are exposed to high energetic particle fluxes in the jovian magnetosphere.