掺氮TiO2光学薄膜的吸光特性研究

TiO2在光催化方面具有较好的应用前景,可望用于有害污染物的降解处理;但由于其禁带宽度对应的激发波长在紫外区,限制了其大规模应用。文章利用操作简便、易于控制的真空阴极电弧离子镀膜技术,制备了非掺氮和掺氮的TiO2薄膜。并分别在300℃和500℃退火后,获得了非晶态向锐钛矿结晶的转变。结果还表明,掺氮TiO2薄膜的相变温度比非掺氮的TiO2薄膜要高,其光吸收区也从紫外区扩展到了可见光区。     

Silver Film Growth on Glass Ceramic by Radio Frequency Magnetron Sputtering

Thin silver films are deposited by radio frequency magnetron sputtering on glass ceramic at room temperature.Variations of sputtering power,bios voltage and power density are carried out for each deposition,then parts of as-deposited samples are subjected to annealing at 600 ℃ within a vacuum chamber.Structural properties are studied by X-ray diffraction(XRD),scanning electron microscope(SEM)and laser scanning confocal microscope(LSCM).It is shown that structural properties have a strong dependency on sputtering power and annealing temperature.Electrical contact resistance measured by a four point probe instrument is directly affected by the thickness of films.It is also found that the film conductivity,especially in thinner films,is improved by the increasing grain size.Finally,the film adhesion is observed by scratch tests.And the adhesive ability deposited by radio frequency magnetron sputtering shows a better performance than that produced by traditional methods.     

双酚A型2,2-对氨基苯甲酸苯基氧化膦本质阻燃PA66

以自合成的双酚A型2,2-对氨基苯甲酸苯基氧化膦(BNNPO)、 己二胺及PA66盐为原料,通过高温高压(280 ℃,1.7 MPa)聚合制备了本质阻燃PA66树脂。红外分析表明BNNPO盐含有N-P膨胀结构;热分析表明阻燃PA66树脂较纯PA66有更优异的热稳定性;极限氧指数及垂直燃烧法结果显示阻燃PA66具有良好的阻燃性能,当BNNPO含量达4.5 wt%时,极限氧指数(Limiting oxygen index,LOI)及垂直燃烧水平（UL94）分别达28%和V-0;锥形量热法及扫描电镜分析发现BNNPO以气相及凝聚相协效阻燃作用于PA66基体材料;力学性能结果显示BNNPO的引入对PA66的力学性能影响较小。     

多项式系统几何性质的注记

证明：在研究多项式系统的几何性质时，多项式系统应当定义成射影空间中奇点集之余维数至少为2的线场。在这个定义中，多项式系统的次数与通常的次数，在概念上不同相同，通常的n 1次退化系统属于这里的n次系统。值得注意的是，本给出的定义与坐标系的选取无关，在这种定义下，多项式系统的某些几何性质变得非常明显。     

R134a的热物理性质计算

氯氟碳化合物（ＣＦＣ）作为制冷与空调设备的工质，长期以来被广泛应用于生产和生活的各个部门。近年来，人们逐步认识到某些ＣＦＣ对臭氧层具有破坏作用和挥发后产生温室效应，因此不得不寻求新的替代工质。替代Ｒ１２的制冷剂方案中，有单一工质，也有混合工质。在单一工质中，从长远意义上最有希望替代Ｒ１２的新工质是民１３４ａ。为了对制冷系统应用Ｒ１３４ａ进行性能评价，而要一套完整的热物理性质公式。目前，有关Ｒ１３４ａ的热力学性质数据较多，但有关它的热物理性质数据却很少。本文列出并推导了Ｒ１３４ａ热物理性质的计算方程式，给出了部分计算数据，为用Ｒ１３４ａ作为制冷剂循环的制冷装置及换热器计算机辅助设计打下基础。     

Thermo-mechanical properties of RTM-made carbon fibre/polyimide composite attaching collar under transient heating

This study focuses on the thermo-mechanical properties of Carbon Fibre/Polyimide Composite (CFPC) attaching collars under transient heating. The CFPC attaching collars were fabricated by a high-temperature resin transfer moulding process, and their thermo-mechanical properties under the conditions of simultaneous transient heating and bending load were investigated. The results show that the attaching collar tends to fail at 118% of the limit load. The failure mode includes the fracture of the connecting screws, local extrusion damage of the hole edges, and slight ablation damage at the outer plies. And there is no observable residual deformation in the composite attaching collar. Furthermore, considering that the material properties vary with temperature, a progressive damage model based on the sequential thermo-mechanical coupling method was established to study the failure mechanism of the attaching collar. Finally, the damage factor of the CFPC was calculated to assess the safety status of the attaching collar. The results show that the primary damage modes of the composite attaching collar are intralaminar failure, which mainly occurs at the heat insulation layer and the hole edges, and these slightly affect the structural bearing capacity. A good correlation between the experiment and FEA is obtained. The test methods and analysis models proposed contribute to the safety assessment of composite structures under transient heating.     

含高能氧化剂(FBN)的推进剂能量特性计算研究

简介了1,4-二氟-1,1,4,4-四硝基丁二醇二硝酸酯[2,3](FBN)的理化性能,并根据最小自由能原理,编写了计算机程序,对含FBN复合固体推进剂进行能量特性计算,着重研究了HTPB、FBN、高氯酸铵、铝粉和奥克托今等组分含量变化对推进剂能量特性的影响,得出了一些规律,并从结果可以看出,FBN部分取代高氯酸铵后推进剂比冲可提高98N·s/kg以上,最高比冲可达2850N·s/kg。由此可见,FBN是一种较好的高能有机氧化剂,应引起有关研究单位的重视。     

温度对小型柔性接头力矩特性的影响

为了研究柔性接头在固定压强下力矩特性随温度的变化,设计了弹性材料为硅橡胶的小型柔性接头,测试了一系列0.1MPa容压条件下柔性接头在正弦激励下的动态特性,获得了不同温度时接头的摆角力矩曲线。根据接头在摆角为0°时的力矩获得摩擦力矩,根据摆角力矩曲线的近线性部分获得弹性比力矩,在此基础上研究了温度对各个力矩的影响。结果表明:作动力矩随温度的升高而减小,但温度对作动力矩的大小影响很小,库伦摩擦力矩随温度的升高而增加,弹性比力矩和总比力矩因发生热弹逆变现象随温度的升高先减小后增加,动态弹性模量和损耗系数随温度的升高而降低,能量损耗受动态弹性模量和损耗系数变化影响随温度的升高而降低.      

一种新型水溶性芯模的制备和性能

概述了金属模具不易脱模的形状复杂的复合材料结构件成型中遇到的工艺技术难题,着重对水溶性芯模的制备工艺特点和性能进行了研究,并将所制得的水溶性芯模成功的用于树脂基复合材料结构件的制造中。结果表明,水溶性芯模的各项性能满足复杂异型复合材料结构件制造的要求。     

壁面厚度随机度对闭孔 Voronoi泡沫材料弹性性能的影响

基于闭孔Voronoi随机模型,通过引入壁面厚度随机度,研究了壁面厚度不均匀性对各向同性和各向异性闭孔泡沫弹性性能的影响,并讨论了壁面厚度随机度与模型随机度共同作用下的影响效果.结果表明,壁面厚度随机度对各向同性和各向异性弹性模量均起减小的作用,且其在各向同性时的影响效果要低于模型随机度的影响,而在各向异性情况下则要高于模型随机度的影响.但是,壁面厚度随机度对闭孔泡沫的泊松比影响却很小.