NiCrAlYSi涂层/DD6单晶高温合金界面再结晶和互扩散行为

采用电子束物理气相沉积(EB-PVD)在单晶高温合金DD6基体上沉积NiCrAlYSi涂层.利用X射线衍射(XRD)、扫描电镜(SEM)、能谱仪(EDS)以及透射电镜(TEM)等研究了高温扩散过程中NiCrAlYSi/DD6的界面再结晶和互扩散行为.研究结果表明合金表面喷砂处理后的涂层试样经1 323 K真空热处理4 ...     

芬顿反应与TiO2光催化氧化甲基橙的研究

分别采用Fe^2＋及TiO2作为光催化剂，考察了它们对甲基橙的降解率。结果表明：在芬顿反应体系中加人NaOH时，可有效地阻止反应的进行；pH=4时，光催化氧化率最高；甲基橙溶液浓度越低，光催化氧化效果越好；改进后的光催化剂对甲基橙的分解率明显提高，不会生成草酸的铁盐沉淀；H2O2＋FeC2O4、H2O2＋FeSO4、TiO2三种体系的光催化性能大小依次为H2O2＋FeC2O4〉TiPO2〉H2O02＋FeSO4。     

基于变惯量反作用飞轮的小卫星大角度姿态机动控制研究

研究以变惯量反作用飞轮作为执行机构的小卫星的大角度姿态机动控制问题。变惯量反作用飞轮是一种新型的动量交换装置,不仅可以通过改变飞轮转速输出力矩,还可以通过改变其转动惯量实现大范围的力矩输出。文中建立了带有变惯量反作用飞轮的星体姿态动力学方程,设计了姿态控制律和飞轮的操纵律。仿真结果表明,与一般反作用飞轮相比,当小卫星大角度机动时变惯量飞轮的转速更不容易饱和,且力矩的输出范围变宽,可以同时满足小卫星高精度稳定和快速大角度姿态机动的双重要求。     

自由射流超燃冲压发动机燃烧室流场对比计算研究

提出一种针对喷射的简化模型，拓展了二维／轴对称NS方程模型的适用范围。通过算例验证，显示出源项加质方法具有良好的质量守恒性。针对文献中的实验进行了对比计算，结果表明，数值模拟与实验点符合得较好，验证了方法的可靠性。采用上述简化模型，针对化学反应过程与流动过程采用了耦合与解耦这两种方法，对放置在自由射流实验台上两种构型的缩比发动机燃烧室段进行了考虑化学反应流场模拟，得到了主要气动参数的分布图。研究了总压耙等测量装置对于流动的影响。计算结果表明，数值模拟所得到的壁面静压值与实验壁面压力符合得较好，并且为合理布置测量仪器提供了一定的参考。     

运载火箭贮箱壁板化铣旋转设备的设计

根据运载火箭贮箱壁板精密化学铣切减重的技术要求,分析了设计技术难点,通过确定制动电机,计算传动比、线速度,释放扭矩和消除两侧齿轮间隙等,研制了一套专用定位倍式化学铣切旋转设备。采用倍式转动化学铣切,减少了传动间隙,提高了转动扭矩和使用寿命加工精度,确保运载火箭贮箱壁板的精密化学铣切的要求。     

Effect of nickel introduced by electroplating on pyrocarbon deposition of carbon-fiber preforms

In order to improve the deposition rate and microstructure of pyrocarbon, nickel was introduced by electroplating on carbon fibers and used as a catalyst during the deposition of pyrocarbon at 1000 C using methane as a precursor gas. The distribution of nickel catalyst and the microstructure of pyrocarbon were characterized by scanning electron microscopy（SEM）, energy dispersive spectroscopy（EDS）, X-ray diffraction（XRD）, and Raman micro-spectrometry. Results show that nano-sized nickel particles could be well distributed on carbon fibers and the pyrocarbon deposited catalytically had a smaller d002 value and a higher graphitization degree compared with that without catalyst. In addition, the deposition rate of pyrocarbon in each hour was measured.The deposition rate of pyrocarbon in the first hour was more than 10 times when carbon cloth substrates were doped with nickel catalysts as compared to the pure carbon cloths. The pyrocarbon gained by rapid deposition may include two parts, which are generation directly on the nickel catalyst and formation with the carbon nanofibers as crystal nucleus.     

除冰液对道面混凝土的影响及保护剂防护效果

通过冻融和化学侵蚀试验，研究了NW-056A机场道面除冰液对道面水混混凝土耐久性的影响以及在道面除冰液环境下两种新型混凝土保护剂的防护效果。结果表明：①混凝土在道面除冰液中冻融后表面无明显剥落现象，相对动弹模损失率比在水中小很多，道面除冰液延缓了混凝土的冻融破坏：②混凝土在道面除冰液常温浸泡下表面无剥蚀现象，但强度比在水中降低很多，因此存在化学腐蚀．且主要表现为对混凝土内部结构的缓慢损伤；（④两种新型混凝土保护剂均对预防混凝土的冻融破坏以及除冰液环境下的腐蚀破坏起到一定作用，涂刷混凝土保护剂是提高混凝土道面耐久性的有效方法。     

氨合成-水热改性法制备氢氧化镁阻燃剂

为了解决氢氧化镁和聚合物之间的不相容问题, 对氨合成法-水热改性处理2步法制备高分散氢氧化镁阻燃剂进行了研究,分析了常温合成温度、水热改性温度和水热改性时间对制备大晶型、低比表面积氢氧化镁阻燃剂的影响.结果表明,经过水热改性处理改变了氢氧化镁晶体的生长习性,生成了形貌规则、粒径分布均匀、分散性良好的氢氧化镁六方片状颗粒.另外通过提高氯化镁浓度和氨水过量1倍,探讨了常温合成反应的转化率,认为应该在反应原料等当量下寻求提高转化率的可行方法.     

FINITE DIFFERENCE MODEL FOR SIMULATION OF DENSIFYING CARBON-CARBON COMPOSITES BY CHEMICAL VAPOR INFILTRATIONP ROCESSES

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On initial steps of chemical prebiotic evolution: Triggering autocatalytic reaction of oligomerization

Searching for extraterrestrial life attracts more and more attention. However this searching hardly can be effective without sufficiently universal concept of life origin, which incidentally tackles a problem of origin of life on the Earth. A concept of initial stages of life origin is stated in the paper. The concept eliminates key difficulties in the problem of life origin, and allows experimental verification of it. According to the concept the predecessor of living beings has to be sufficiently simple to provide non-zero probability of self-assembling during short (in geological or cosmic scale) time. In addition the predecessor has to be capable of autocatalysis, and further complication (evolution). A possible scenario of initial stage of life origin, which can be realized both on other planets, and inside experimental facility is considered. In the scope of the scenario a theoretical model of multivariate oligomeric autocatalyst is presented. Results of computer simulation of two versions of oligomeric autocatalytic reactions are presented. It is shown that the contribution of monomer activation reaction is essential, and in some cases autocatalysis in polymerizing reaction can be achieved without catalyzing proper monomer binding reaction.