环氧树脂辐射固化反应速率及速率常数的研究

研究了环氧树脂溶液的电子束辐射固化反应速率常数以及树脂特性对反应速率的影响.研究结果显示,辐射反应增长速率常数k_p和终止速率常数k_t在反应进行的不同阶段表现出不同的控制机制.环氧树脂的分子量及其分布,分子化学结构对辐射反应速率都有很大影响,反应速率大的树脂体系最终达到的反应程度也高.     

快速凝固制备的Cu—Sn—Ag—In钎料薄带的韧脆性探讨

用快速凝固法将代银钎料Ｃｕ－Ｓｎ－Ａｇ－Ｉｎ合金制备成薄带，透射电镜分析结果表明薄带组织为晶态。扫描电镜分析结果显示薄带显微组织由银或富银的面心立方固溶体ａ相和脆性相组成。     

Investigation on the Orientation Transition of Oriented Magnetostrictive TbDyFe Crystals

<110> and <112> TbDyFe magnetostrictive oriented crystals were prepared by the zone-melting unidirectional solidification method at 240 mm/h and 720 mm/h respectively. <112> oriented crystals were also obtained with <110> oriented seeds with the same technique as for growing the <112> oriented crystals. It is confirmed that this technique is stable for growing the oriented crystals in the TbDyFe alloys. Meanwhile, the variation of orientation, the solidification morphology and the magnetostriction were studied during the transition from <110> oriented seeds to the <112> oriented crystal growth. As the growth speeds up, the preferred orientation changed from <110> to <112>, and its morphology develops from of initial cellular to dendritic gradually. When an axial compressive pre-stress of 10 MPa is applied, the magnetostriction at the bottom, the middle and the top are 972×10-6, 918×10-6 and 900×10-6 at 100 mT respec-tively. The middle sections with mixed orientations have the same high magnetostriction performance as those with a single preferred orientation, which may be due to its celluar-dendritic morphology.     

Si对In718合金凝固过程及元素偏析的影响

本文研究了Ｓｉ对Ｉｎ７１８合金凝固过程及元素偏析的影响。结果表明，当Ｓｉ含量升高后，不仅在枝晶或Ｌａｖｅｓ相中偏析程度加剧，而且在枝晶内的浓度也逐渐升高而达到显著水平。Ｓｉ降低Ｎｂ在Ｌａｖｅｓ相中的溶解度，因而促进Ｌａｖｅｓ相的析出，提高Ｌａｖｅｓ相吸收剩余液体的能力，缩小偏析区的面积。分析认为，过分降低Ｓｉ含量对改善合金凝固组织及提高终凝温度的作用不大。     

Primary Solidification Phase and Lamellar Orientation in Directionally Solidified Ti-45Al-7Nb Alloy

Primary solidification phase and lamellar orientation are investigated in Ti-45Al-7Nb alloy at very high ratio of temperature gradient to growth rate (G/v) by a liquid-metal-cooled directionally solidified method. It shows that Ti-45Al-7Nb alloy solidifies with primary α phase. Longitudinal (parallel to growth direction) microstructure shows that α dendrites in solid-liquid mushy zone are discontinuous and transverse microstructure of α dendrites is worm-like feature. Growth direction of α phase is about 80° away from〈0001〉α direction, and close to〈1120〉α direction. The corresponding lamellar orientation is aligned at the angle of about 10° to growth direction, which is consistent with α-dendrite growth direction according to Blackburn orientation relationship. Therefore, due to the altered growth direction of α phase, the lamellar orientation in Ti-45Al-7Nb alloy is controlled at the G/v ratio of 5×109 K·sm-2.     

三维铸件定向凝固过程模拟Ⅰ——稳态定向凝固过程的边界元解

在定向铸件的生产中,由于不能测取许多凝固参数而无法对实际凝固过程实施动态控制,影响了铸件质量的提高。对凝固过程的数值模拟将有助干揭示凝固过程并为过程控制提供重要信息。根据热量传递的特征,实际定向过程可以划分为抽拉前的稳态过程和抽拉开始后的非稳态过程。本文讨论了边界元法对于稳态定向凝固过程的数值模拟;考察了热物性参数和边界条件非线性的影响及其简化的可能性。     

预置裂纹定向凝固高温合金叶片的断裂特征分析

通过对涡轮叶片用、定向凝固合金材料DZ4紧凑拉伸试样的断裂韧性计算,在有限元程序MSC.MARC下建立了复杂构件应力强度因子的计算模型;结合试验研究,计算了预置裂纹叶片的应力强度因子,分析了发生断裂时的状态,发现叶片的断裂韧性具有较大的分散性,其中一部分明显低于材料的试验值;对工作条件下的故障叶片进行了模拟计算,反映出该叶片在发生断裂时瞬断区偏大而疲劳区偏小的断裂特征。     

定向凝固镍基高温合金上激光熔覆Inconel 738的裂纹敏感性研究

针对定向凝固镍基高温合金叶片的强化与修复需求,研究了在定向凝固镍基高温合金基体上激光熔覆Inconel 738的裂纹敏感性问题.在定向凝固镍基高温合金基体上激光熔覆Inconel 738合金对裂纹非常敏感,所产生的裂纹为热裂纹,由定向凝固基体晶界处引发并穿过界面向熔覆层发展;多层熔覆过程中熔覆层间也会产生热裂纹,热裂纹沿晶界纵向扩展.定向凝固高温合金基体晶界处的低熔共晶成为主要的裂纹源.严格控制激光熔覆过程中的热输入量可以显著降低裂纹敏感性.选择适当的熔覆工艺方法和参数可以在定向凝固镍基合金基体上形成良好冶金结合且无裂纹的基本保持定向凝固特性的熔覆层组织.     

定向凝固涡轮叶片高温低周疲劳的破坏特点

针对几何形状完全相同但材料不同的两种涡轮叶片,采用相同的试验方法进行高温低周疲劳试验,普通铸造K403合金叶片和定向凝固DZ22B合金叶片却在不同的部位破坏,K403合金叶片在试验考核的榫齿部位断裂,而DZ22B合金叶片的榫齿在叶身根部断裂前均未出现裂纹.为了解释上述试验结果,展开了两类叶片试验条件应力场的有限元分析和...     

强磁场对Al-40％Cu合金中Al2Cu析出相的影响

在10T强磁场下进行了Al-40％ Cu(质量分数)合金重熔凝固实验,并用金相分析方法研究了磁场对凝固组织的影响.实验结果表明,Al-40％Cu合金在10T强磁场中凝固时,析出相Al2Cu形成与磁场方向成一角度的规则排列的平面层状组织.理论分析认为:由于Al2Cu晶体在不同方向的磁化率不同,在磁场中受到磁力矩的作用而转...