氧化物陶瓷的微波烧结

利用自行研制的微波烧结装置，进行了氧化锆（Ｙ－ＴＺＰ）、氧化锆增韧氧化铝（ＺＴＡ）和氧化铝陶瓷的微波烧结实验研究。重点讨论了烧结温度、保温时间对烧结密度的影响。另外，还从烧结工艺、烧结结果等方面与常规烧结方法进行了比较。     

Investigation on plume interference effect of solid propellant micro-thruster

The three-dimensional numerical simulation of two-phase plume flow of solid propellant micro-thrusters was developed. Then it was used to investigate the plume interference effect by combining the direct simulation Monte Carlo (DSMC) method for multi-component gas flow with the two-way coupling model for two-phase rarefied flow. At different space between the two micro-thrusters and different wall temperature,the plume interference effect was analyzed specifically. The results show that under the plume interference effect the gas is compressed and the flow direction is changed,which resulted in the increasing of gas pressure and temperature; solid phase made no significant effect on the flow parameters of gas phase; with the rising of the space between the two micro-thrusters,the maximum pressure decreased and the maximum temperature increased in the domain under the plume interference effect; the wall temperature could influence the temperature of the gas which is extremely close to the wall,but not the gas pressure.      

Effects of Shot Peening Process on Thermal Cycling Lifetime of TBCs Prepared by EB-PVD

Conventional two-layered thermal barrier coatings (TBCs) are prepared by electron beam physical vapor deposition (EB-PVD) with ZrO2-8 wt% Y2O3 (8YSZ) as top coat and CoCrAlY as bond coat on disk-shaped Ni based super-alloy. In this paper, three kinds of shot peening process with different lengths of operating time were adopted for bond coating. As a result, changes took place in its sur- face roughness and the surface micro-hardness. A thermal cycling test at 1 273 K×55 min and another at room temperature for 5 min were performed to study the effects of shot peening process on the thermal cycling lifetime of TBCs. It is found that a moderate shot peening process will be able to prolong the life time. The oxidation dynamic of the as-processed TBCs basically accords with the para- bolic rule, and the oxidation test also attests to the spallation between YSZ and thermal growth oxide (TGO) responsible mainly for the failure of TBCs.     

Scalable Preparation of SrTiO3 Submicro-wires from Layered Titanate Nanowires

SrTiO3 submicro-wires were prepared by the reaction of layered titanate nanowires with Sr(OH)2 powder in an autoclave. The wires were investigated using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), Ultra-violet visible (UV-vis), photoluminescence (PL) and Raman spectroscopy. The XRD measurement shows that the prepared SrTiO3 submicro-wires hardly have impurity phases. The SEM and TEM images demonstrate that the scalable wires, which need to be proc- essed at the reaction temperature of 180 ℃ for about 48 hours, are not composed of single crystals. The PL shows that the wire-like SrTiO3 has emission peaks at the wavelengths of 568 and 585 nm. Further, the Raman spectroscopy reveals structural changes in the products through different reaction time.     

Electrochemical Behavior of Oxide Films of Stainless Steel in 40 kHz Sonicated Sulphate Electrolytes

This paper describes effects of 40 kHz ultrasound on the oxide films of stainless steel in sulphate electrolytes so as to determine the transmitted power and to characterize mass transfer and peak current density on the electrode surface. Emphasis was mainly laid on electrochemical oxidations and peeling mechanism of oxide films in sonicated sulphate solutions (0.5 and 1.0 mol/L). Polarization voltammetry, current response traces and SEM analysis were carried out in order to provide full information as to oxide films surface. Results shows that the rate of electrochemical oxidation, the shape of polarization curves and the surface micrographs in sonicated sul- phate electrolytes are different from those obtained without introduction of ultrasound. It is concluded that ultrasound can change the electro-chemical behavior of oxide films by its cavitaion effects, which would produce transient mechanical impulsive force and enhance electrochemical reactions.     

甲烷/氧气双组元微型推力室的实验研究

为研究微小推力室的工作特点,建立了双组元微小推力室的地面实验装置和数据采集系统。在内径为4mm,喉部直径为0.4mm的微小推力室内,采用氧气和甲烷气体作为推进剂进行了点火热试车,实时测量燃烧室压力和壁面的温度分布。实验结果表明,在富燃工况下,随着混合比的升高,燃烧温度和燃烧室压力逐渐升高;当混合比一定时,随着总流量的增加,燃烧室压力增加,微小推力室的推力和比冲也在升高。微小推力室的真空推力达到120mN,真空比冲达到了240s。     

基于微型固体推力器阵列的轨道控制点火算法

为了解决基于微型固体推力器阵列轨道控制的推力器组合点火问题,优化了阵列布局,使其适用于轨道控制,得出了推力器坐标位置分布律。在此基础上研究了推力器阵列组合点火算法,建立了相应数学模型,进行了算法验证。仿真结果表明,设计的推力器阵列优化方案能够满足皮纳卫星轨道控制要求,所建数学模型能有效解决点火问题,设计的算法能够实现较快寻址。     

纳米结构铜铬氧化物的制备及在推进剂中的催化作用

为探索纳米催化剂的分散技术，设计并制备了由惰性组分和纳米颗粒铜铬氧化物（CC）组成的一种纳米结构催化剂（ns-CC）。研究了铜铬氧化物前驱体铬酸铜铵（CAC）的热解条件对纳米结构催化剂中CC晶粒尺寸的影响。XRD分析结合TEM观察表明升温速率增大，粒径变小，但保温时间在一定范围内对晶粒的影响不明显。ns-CC对AP催化热分解结果显示加入少量的ns—CC使AP的高温分解峰温提前95℃，且大幅增加AP的表观放热量。在RDX／AP／Al／HTPB推进剂中，添加0．5％的ns—CC和普通CC时，6MPa下燃速由基础配方的6．31mm/s分别提高到8．82和8．69mm／s，4～10MPa范围内压力指数由基础配方的0．35分别升高到0．38和0．49。初步研究表明，ns-CC是一种具有较大潜力的值得深入研究的推进剂燃烧催化剂。     

可燃性气体对氧化锆氧分析仪测量误差影响的分析

当气体中有可燃性气体存在时,会对氧化锆氧分析仪产生测量误差.本文阐述了氧化锆氧分析仪的使用条件,同时提出了测量误差的解决办法和措施.     

锂离子电池用正极材料LiNi_(1-x)Co_xO_2的研究

采用高温固相法分别在空气和氧气气氛下合成锂离子电池正极材料LiNi1-xCoxO2 (x =1 ,0 .8,0 .5,0 .2 ,0 ) ,用X射线衍射 (XRD)测定晶格结构和晶胞参数 ,并用CR2 0 2 5扣式电池及 1 8650型电池对材料充放电性能进行测试。试验结果表明 ,随着LiNi1-xCoxO2 中钴含量增加 ,晶胞参数a和c值依次减小 ,晶胞体积收缩。同时烧结气氛对材料结构和电化学性能影响极大 ,氧气气氛有助于LiNi1-xCoxO2 (x >0 )的生成