C_f/SiC复合材料表面熔盐反应法锆金属化研究

利用熔盐热歧化反应在碳纤维增强碳化硅(Cf/siC)复合材料表面制备了锆金属化层.研究反应时间对金属化层形貌、物相、厚度的影响,分析SiC/Zr的界面反应机理.结果表明,锆金属化层优先在SiC区域生成,随着反应时间的延长,逐渐在C纤维区域生成,当反应时间达到3h时,金属化层覆盖完全;金属化层主要物相为Zr,Zr,O,ZrC和Zr2Si;金属化层的生成受固相中Zr,Si,C等元素扩散控制.     

过滤条件对活性涂层陶瓷颗粒过滤铝熔体的影响

将活性涂层陶瓷颗粒分别装在能够透气的管状耐火砖和致密陶瓷管内,然后加热到710℃用于过滤铝熔体。研究结果表明,在透气条件下,拉伸试样的延伸率下降,并且拉伸断口裂纹大,韧窝大而不均匀;金相试样中的夹杂物数量多而且尺寸也大。在不透气(致密陶瓷管)条件下,当陶瓷颗粒尺寸为1mm,过滤后的拉伸试样延伸率达到48.7%,提高16%,拉伸断口裂纹细且韧窝小而均匀,仅有少数8μm的夹杂物。     

适于电子束固化的环氧648树脂体系的初步研究

对适于电子束固化的环氧 64 8树脂体系进行了初步研究,探索了二苯基碘六氟磷酸盐含量对环氧64 8树脂体系的影响,并针对辐射剂量对体系的影响进行了分析,最后还比较了环氧丙烷丙烯醚、丙烯酸丁酯及丙酮作为稀释剂的使用效果。结果表明 :在所研究的树脂体系中,碘盐的用量存在最佳值,辐射体系 Tg随辐射剂量的增大而有所增加,活性稀释剂在一定的用量范围内对体系的降粘效果较好     

双四唑盐的合成及表征

介绍了双四唑钾盐(K2BHT)、双四唑(BHT)、双四唑胍和双四唑氨基胍的合成。采用滴加醋酸和加入硫酸铜改善中间产物双四唑锰盐过滤性,提高了产率。采用双四唑锰盐和碳酸钾高温置换反应生产双四唑钾盐。双四唑和碳酸胍、碳酸氨基直接反应生成双四唑胍和双四唑氨基胍。通过DSC-TGA、元素分析、IR、1H NMR1、3C NMR和MS等方法,对其结构进行了鉴定,并进行了常规感度测试。结果表明,双四唑感度较高,而其它双四唑盐感度较低。     

四唑类盐的制备及其在固体推进剂中的应用初探

合成了5-苯基四唑、5-亚甲基二四唑，并通过元素分析及质谱方法对其进行了分析鉴定，制备了其铜、铅、锶盐；对3种金属盐在改性双基推进剂配方中的应用进行了探索性研究。初步研究表明，四唑类的金属盐类可以作为复合改性双基推进剂(CMDB)的含能燃烧催化剂。     

铝合金双光束激光填丝焊接熔丝特征分析

以5A06铝合金作为试验材料,采用单/双光束激光焊接方法进行了自熔焊接与填丝焊接试验。通过对焊接过程中熔池流动、匙孔形态及焊丝熔化与过渡过程的观察,研究了不同光束模式下焊丝熔化特性及影响因素。单光束激光焊接时,由于能量密度较高,熔池及匙孔波动剧烈;双光束模式中降低了输入的能量密度,在光斑距离1.5 mm时形成两个独立匙孔的开口面积仅为单激光时的34%,匙孔无闭合现象,熔化焊丝以双液桥形式过渡。光丝分离距离1 mm范围内,焊丝熔化过程稳定;光丝重合范围达到1 mm时焊接过程稳定性下降;光丝部分重叠的条件下,熔化过渡过程最为稳定。     

Effects of cerium salts on corrosion behaviors of Si–Zr hybrid sol–gel coatings

The present work examines the effects of cerium salts on corrosion behaviors of Si–Zr hybrid sol–gel coatings. The Si–Zr hybrid sol–gel coatings on a 2A12 aluminum substrate were prepared through hydrolysis and condensation of glycidoxypropyl-trimethoxy-silane(GTMS) and zirconium(IV) n-propoxide(TPOZ). Used as inhibitors for corrosion, three types of cerium salts(Ce(NO_3)_3, CeCl_3, and Ce(CH_3COO)_3) were doped into the sol–gel coatings. Fourier transform infrared(FTIR) and scanning electron microscopy(SEM) were employed to investigate the structures and morphologies of various coatings, and the corrosion resistances of the coatings were evaluated by electrochemical methods and neutral salt spray tests. Experimental results indicate that the addition of cerium salts can hinder the process of corrosion due to their self-healing abilities. Furthermore, the sol–gel coating doped with Ce(CH_3COO)_3 has the best corrosion resistance because of the promotions of hydrolysis and condensation provided by CH_3COO.     

Synthesis of TiNi/Ti_2Ni Composite Particles in Molten Salts

A new process of synthesizing TiNi/Ti2Ni composite particles, high temperature molten salts method, is introduced. This method uses molten salts as a reaction medium that does not take part in the chemical reaction and can be easily dissolved in rinsing water. Ac-cording this method, the composite particles were prepared in molten salts at 700 ℃-900 ℃. By means of differential scanning calo-rimetry (DSC), the reversible martensitic transformation of TiNi particles in these composite particles was confirmed.