Formation and Role of H2O2 During Ozonation of Nitrobenzene

To better understand the formation of H2O2 in the ozonation of nitrobenzene and its role for the oxidation,a batch reactor of nitrobenzene ozonation was set up.The variables such as pH value,ozone dosage,and the presence of hydroxyl radical scavenger were investigated.The results showed that high accumulations of H2O2 were generally formed at low pH values and low ozone dosages.Moreover,H2O2 mainly formed after nitrobenzene was oxidized by hydroxyl radical during ozonation of the intermediates,such as p-nitrophenol,which reacted with ozone quickly in water.A small amount of additional H2O2 enhanced the nitrobenzene removal slightly.The kinetic study showed that nitrobenzene degradation fitted with pseudo-second-order kinetics well in the experiment.The kinetic constant values correlated linearly with the concentrations of H2O2 added.Thus,it is expected that the H2O2 formed in oxidation of nitrobenzene may initiate ozone decomposition to form hydroxyl radical and finally enhance the degradation of aromatic compounds to a certain extent.     

月面冯·卡门撞击坑的着陆选址和科学探测目标浅析

冯·卡门（Von Kármán）撞击坑位于月球背面南极—艾肯（South Pole-Aitken,SPA）盆地中部,是中国“嫦娥4号”计划的优先级较高的探测目标。对该撞击坑的着陆和探测,有助于揭示月球形成和演化的一些关键问题,在月球科学研究中具有重大的意义。论文概要总结了冯·卡门撞击坑的研究意义和科学价值;结合LRO卫星LOLA数据、Clementine UV-VIS数据、GRAIL数据、“嫦娥2号”卫星CELMS等数据,简要分析了冯·卡门撞击坑的地形、成分、深部结构和亮?%rater are analyzed with LRO satellite LOLA data,Clementine UV-VIS data,GRAIL data,and Chang''E-2 CELMS data and their scientific meanings are also presented. Finally,combined with our results and the previous prospects about theVon Kármán crater,three candidate landing sites and the possible scientific discoveries are proposed.     

基于流体速度势的非线性晃动问题的ALE有限元分析

基于流体速度势，本导出了非线性晃动问题的ALE有限元格式。通过引入ALE运动学描述，使网格的运动独立于流体的运动，通过采用与贮箱固连的非惯性参考系建立控制方程，使网格只须相对贮箱更新，因此运动边界和自由液面的跟踪算法不仅非常简单，而且不会引起网格畸变．本分别采用有限元法和有限差分法进行空间和时间离散，中的算例分别模拟了贮箱受横向激励和俯仰激励时流体的非线性晃动问题，所得结果证实了本方法的有效性与可靠性。中的方法还可进一步推广用于流体—结构耦合问题．     

A comparative and numerical study of effects of gravity waves in small miss-distance and miss-time GPS radio occultation temperature profiles

The Global Positioning System (GPS) Radio Occultation (RO) technique has global coverage and is capable of generating high vertical resolution temperature profiles of the upper troposphere and lower stratosphere with sub-Kelvin accuracy and long-term stability, regardless of weather conditions. In this work, we take advantage of the anomalously high density of occultation events at the eastern side of the highest Andes Mountains during the initial mission months of COSMIC (Constellation Observing System for Meteorology, Ionosphere and Climate). This region is well-known for its high wave activity. We choose to study two pairs of GPS RO, both containing two occultations that occurred close in time and space. One pair shows significant differences between both temperature profiles. Numerical simulations with a mesoscale model were performed, in order to understand this discrepancy. It is attributed to the presence of a horizontal inhomogeneous structure caused by gravity waves.     

Gravity wave momentum flux generation close to mid-latitude Andes in mesoscale simulations of late 20th and 21st centuries

Adequate representations of diverse dynamical processes in general circulation models (GCM) are necessary to obtain reliable simulations of the present and the future. The parameterization of orographic gravity wave drag (GWD) is one of the critical components of GCM. It is therefore convenient to evaluate whether standard orographic GWD parameterizations are appropriate. One alternative is to study the generation of gravity waves (GW) with horizontal resolutions that are higher than those used in current GCM simulations. Here we assess the seasonal pattern of topographic GW momentum flux (GWMF) generation for the late 20th and 21st centuries in a downscaling using the Rossby Centre regional atmospheric model under the Intergovernmental Panel on Climate Change A1B emission conditions. We focus on one of the world’s strongest extra-tropical GW zones, the Andes Mountains at mid-latitudes in the Southern Hemisphere. The presence of two GCM sub-grid scale structures locally contributing to GWMF (one positive and one negative) is found to the East of the mountains. For the late 21st century the strength of these structures during the GW high season increases around 23% with respect to the late 20th century, but the GWMF average over GCM grid cell scales remains negative and nearly constant around −0.015 Pa. This constitutes a steady significant contribution during GW high season, which is not related to the GWMF released by individual sporadic strong GW events. This characteristic agrees with the fact that no statistically significant variation in GWMF at source level has been observed in recent GCM simulations of atmospheric change induced by increases in greenhouse gases.     

功能梯度压电材料层状结构中的SH波

基于线性压电弹性理论,利用传递矩阵法,分析了功能梯度压电材料层状结构中的SH波传播特性,研究了压电梯度覆盖层中初始应力对SH波传播的影响。压电覆盖层的材料性能如弹性、压电、介电系数和密度沿厚度方向呈梯度变化。数值分析结果表明,适当的材料梯度分布,可使SH波倾向于沿覆盖层表面传播,由此能够获得更好的机电耦合性能;同时,初始应力使得波传播的相速度减小,但增大了机电耦合系数。文中的分析方法和结论,对固体火箭发动机超声探伤及其压电类传感器的研制和选择有一定的参考意义。     

电磁波与TVP相互作用

基于时变等离子体(TVP)的场方程,根据麦克斯韦方程,推导了TVP对入射电磁波的频率上移、时间衰减常数、反射系数,以及TVP的透射波和反射波电场幅值计算公式。通过实例计算分析了不同时间的新波频率、时间衰减常数和电场幅值。方法简单易行,可为TVP的应用提供一定的理论依据。     

Numerical modeling of inhomogeneous orographic wave influence on planetary waves in the middle atmosphere

Parameterization of dynamical and thermal effects of stationary orographic gravity waves (OGWs) generated by the Earth’s surface topography is incorporated into a numerical model of general circulation of the middle and upper atmosphere. Responses of atmospheric general circulation and characteristics of planetary waves at altitudes from the troposphere up to the thermosphere to the effects of OGWs propagating from the earth surface are studied. Changes in atmospheric circulation and amplitudes of planetary waves due to variations of OGW generation and propagation in different seasons are considered. It is shown that during solstices the main OGW dynamical and heat effects occur in the middle atmosphere of winter hemispheres, where changes in planetary wave amplitudes due to OGWs may reach up to 50%. During equinoxes OGW effects are distributed more homogeneously between northern and southern hemispheres.     

Spectroscopic Constraints on Models of Ion-cyclotron Resonance Heating in the Polar Solar Corona

Using empirical velocity distributions derived from UVCS and SUMER ultraviolet spectroscopy, we construct theoretical models of anisotropic ion temperatures in the polar solar corona. The primary energy deposition mechanism we investigate is the dissipation of high frequency (10-10000 Hz) ion-cyclotron resonant Alfvén waves which can heat and accelerate ions differently depending on their charge and mass. We find that it is possible to explain the observed high perpendicular temperatures and strong anisotropies with relatively small amplitudes for the resonant waves. There is suggestive evidence for steepening of the Alfvén wave spectrum between the coronal base and the largest heights observed spectroscopically. Because the ion-cyclotron wave dissipation is rapid, even for minor ions like O⁵⁺, the observed extended heating seems to demand a constantly replenished population of waves over several solar radii. This indicates that the waves are generated gradually throughout the wind rather than propagated up from the base of the corona. This revised version was published online in June 2006 with corrections to the Cover Date.     

斜激波极值规律的边界层影响

采用边界层理论与斜激波/膨胀波精确算法，建立一种结合Eckert参考温度法和Illingworth-Stewartson变换法优势的边界层权重算法，用于研究超声速黏性楔面边界层位移厚度对斜激波极值规律的影响。分别应用层流Navier-Stokes方程和湍流Navier-Stokes方程的CFD解算器对边界层新模型进行了算例精度评估。在来流马赫数为1.2~2.4和楔面角为3°~20°的范围内，压强比的相对误差小于0.1%。计入层流与湍流边界层影响的理论模型研究表明，边界层影响使得最优马赫数增加；对于层流边界层，最优马赫数增量约为0.001 5~0.003 3；对于湍流边界层，最优马赫数增量约为0.002 8~0.006 1。