芳纶复合材料用湿法环氧配方的研究

在综合考虑粘度，力学性能和储存期的基础上，研制了以混合芳香胺为固化剂的芳纶用湿法环氧配方， 注浇体力学与俄，美等国家湿法环配方及我国高性能干法配方性能相当，实验证明该湿法环氧配方与Ｆ－１２纤维浸润性及界面粘接性能均较高，其ＮＯＬ环强度转化率均达８７％。     

碳/环氧复合材料两次表面镜基板研制

文章介绍了碳/环氧复合材料两次表面镜基板的结构与铺层、选材与成型工艺,性能测试等内容。     

碳纤维复合壳体用基体环氧树脂研究进展

介绍了固体火箭发动机碳纤维缠绕用基体环氧树脂的种类、选择原则及适于碳纤维缠绕用基体树脂的研究进展.     

Investigation on Thermal and Dimensional Stability of Epoxy Resin In-Situ Modified by Cyanate Ester Resin and Polydimethylsiloxane

The thermal and dimensional stability of epoxy resin (EP) in-situ modified by cyanate ester (CE) and polydimethylsiloxane (PDMS) are investigated by means of experiments and numerical simulation. Thermal gravimetric analysis (TGA) and differential scanning calorimeter (DSC) are used to analyze the heat resistance of the modified EP. The dimensional stability is characterized by the volume shrinkage of the series PDMS/CE/EP obtained by the density method. The chemical structure of the PDMS/CE/EP is analyzed by Fourier transform infrared spectroscopy (FTIR). The results of TGA and DSC indicate that the thermal stability of PDMS/CE/EP decreases firstly and then increases with the increase in the amount of CE. The addition of PDMS shows a slight effect on the thermal stability. The 40% CE makes the blending system exhibit the lowest initial decomposition temperature, which reduces by 15.5% and 40.8% compared with pure EP and CE, respectively. The FTIR results suggested that the influence of CE on the thermal stability of the modified EP is mainly ascribed to the generation of oxazolidinone ring with low thermal stability and the increase in the triazine ring with high thermal stability. The volume shrinkage measurement results show that the introduction of CE and PDMS are both beneficial to the improvement of the dimensional stability of the blending systems. The in-situ addition of 80% CE shows the lowest volume shrinkage of 6.11%. The thermal stress distribution of PDMS/CE/EP generated during the solidification process is simulated by the finite element analysis. The results suggested that the introduction of 80% CE into EP results in the lowest thermal stress in the blending system, which indicates that the system has the lowest volume shrinkage, which agrees well with the experimental results.     

一种活性环氧增韧固化剂性能分析

以壬基酚和甲醛所形成的二聚体为原料,合成了一种新型结构的环氧固化剂双(2-羟基-3 -胺乙基胺甲基-5-壬基苯基)甲烷(BA),利用红外光谱(IR)、核磁共振谱(1HNMR)表征了产物结构.通过差 示扫描量热(DSC)研究了该固化剂的反应活性,确定固化剂最佳质量分数为43.19%.固化 树脂动态力学分析(DMA)表明,由于BA分子结构中存在正壬基,固化后会发生β- 松弛, 能够提高树脂韧性.力学性能测试发现BA固化树脂的冲击强度比普通芳香胺固化树脂提高了 36.91％,证明BA具有高活性和增韧双重效果.      

环氧树脂基导电复合材料力电性能研究

实验研究了填充炭黑的环氧树脂基导电复合材料的导电机理,不同炭黑掺量复合材料在一次加载及反复加载卸载下的力电效应。结果表明,炭黑掺量为20%试件的力电效应明显且稳定;各掺量试件卸载后均存在较大残余电阻,经多次加载卸载后,电阻变化率逐渐减小并趋于稳定值;卸载后电阻恢复率不断增加,最终可完全恢复。     

飞机用固体膜润滑剂

针对新机种对固体膜润滑剂的需求,研制了两种固体膜润滑剂-HR-7201和HR-7101.润滑剂采用国产原材料,具有摩擦系数低,耐高低温及耐介质等优良性能,使用温度HR-7201为-60～300℃,HR-7101为-60～200℃,短期可到250℃.已通过飞机典型零部件试验及长期试车考核,并在飞机上应用.     

环氧改性氰酸酯树脂研究

分别采用E20和E51环氧树脂与双酚A型二氰酸酯(BADCy)共聚来改善氰酸酯树脂的力学性能.用DSC,FTIR研究了两种不同分子量的环氧改性氰酸酯体系的反应性,发现E20和E51对BADCy的固化反应均有催化作用,但E20的催化作用强于E51.断面SEM表明,经E20和E51改性的BADCy断口处存在大量的韧涡.但改性体系的热变形温度(HDT)和吸水率有所下降,当配比(质量)相同时,E51/BADCy体系比E20/BADCy体系具有更高的HDT和较小的吸水率.     

关于粘土/高性能环氧纳米复合材料的形态及力学性能的研究

对粘土片层在纳米粘土／高性能环氧树脂体系中的分散状态及力学性能进行了研究。通过加入较少的粘土（含量≤5wt％）得到插层型纳米复合材料。纳米粘土的存在使环氧树脂的玻璃化转变温度有所降低。粘土质量含量为2％时，复合材料的冲击强度约上升10％，但超过2％后。冲击强度随之下降。材料的弯曲强度则随着粘土含量的升高而逐步降低。     

雷达罩应用5258树脂基复合材料的试验研究

通过试验研究了雷达罩所用主要材料5258环氧树脂、预浸料和复合材料制备方法，进行了这些材料及结构的拉伸、弯曲、剪切和介电常数等性能的测试，结果表明5258树脂基体制备的复合材料均具有良好的力学和电学性能，能够满足雷达罩的设计要求。