Oxidation Properties in CO2 of Inconel Alloy 600 Coated by Simultaneous Aluminizing-Chromizing Process

IN 600 alloy was coated with two different types of coatings, Cr-modified aluminide coating this is called aluminizing-chromizing and Y-doped chromium modified aluminide coating this is called aluminizing-chromizing-yttriumizing. Diffusion coating was carried at 1 050 ℃ for 8 h under Ar atmosphere by simultaneous aluminizing-chromizing process and by simultaneous aluminizing-chromizing- yttriumizing. Cyclic oxidation tests were conducted on the uncoated and on the coated Inconel 600 alloy in the temperature range 800- 1 000 ℃ in CO2 for 100 h at 10 h cycle.The results showed that the oxidation kinetics for uncoated Inconel 600 alloy in CO2 is parabolic and the phases present are NiO, (Fe, Cr)2O3 , NiFe2O4 and NiCrO4. The oxidation kinetics for both coated systems in CO2 was found to be parabolic and the value of kP for both coated systems were found to be lower than that for uncoated Inconel 600 alloy. Oxide phases that formed on coated systems are Al2O3 and NiCrO4. The role of yttrium can be attributed to its ability to improve the adherence of the oxide scale.     

钛合金板超塑性成形/扩散连接成形因素影响的数值模拟

通过对超塑性成形与扩散连接(SPF/DB)成形原理和过程的讨论,以最优成形温度下的Ti-6AL-4V合金材料特性和超塑性成形气压加载理论优化结果为依据,利用Ansys有限元软件的建模和数值模拟,提取夹层板作为研究对象,建立模型和定义材料性能参数,定义接触和加载方式。     

Effect of hygrothermal aging on moisture diffusion and tensile behavior of CFRP composite laminates

Carbon Fiber Reinforced Polymer (CFRP) composites are widely used in aircraft structures, because of their superior mechanical and lightweight properties. CFRP composites are often exposed to hygrothermal environments in service. Temperature and moisture can affect the material properties of composites. In order to make clear the moisture diffusion behavior and the properties degradation of composites, the TG800/E207 composite laminates with four stacking sequences [0]₁₆, [90]₁₆, [±45]_4s, and [(+45/0/0/–45)_s]_s are designed and manufactured. Moisture absorption tests are carried out at 80 ℃, 90 %RH. It is shown that the moisture absorption curves of composite laminates present a three-stage. A modified Fickian model was proposed to capture the diffusion behavior of TG800/E207 composite laminates. The relationships among the non-Fickian parameters, the environmental parameters and the stacking sequences of CFRP were correlated and compared. Results showed that the modified Fickian curve is sensitive to the diffusivity of Stage I and Stage II. Compared with unaged specimens, the maximum tensile stress for [0]₁₆, [90]₁₆, [±45]_4s, and [(+45/0/0/–45)_s]_s decreased by 14.94 %, 28.15 %, 11.96 %, and 26.36 %, respectively. The strains at failure for [0]₁₆, [90]₁₆, [±45]_4s, and [(+45/0/0/–45)_s]_s decreased by 55.38 %, 62.65 %, 46.41 %, and 31.71 %, respectively. The elastic modulus for [0]₁₆, [90]₁₆, [±45]_4s, and [(+45/0/0/–45)_s]_s increased by 90.93 %, 94.57 %, 49.22 %, and 8.22 %, respectively. [90]₁₆ sample has the minimum saturated moisture content and the maximum strength degeneration.     

Aspects related to variability of radiative cooling by NO in lower thermosphere,TEC and O/N2 correlation,and diffusion of NO into mesosphere during the Halloween storms

Nitric Oxide is a very important trace species which plays a significant role acting as a natural thermostat in Earth’s thermosphere during strong geomagnetic activity. In this paper, we present various aspects related to the variation in the NO Infrared radiative flux (IRF) exiting the thermosphere by utilizing the TIMED/SABER (Thermosphere Ionosphere Mesosphere Energetics and Dynamics/ Sounding of the Atmosphere using Broadband Emission Radiometry) observational data during the Halloween storm which occurred in late October 2003. The Halloween storm comprised of three intense-geomagnetic storms. The variability of NO infrared flux during these storm events and its connection to the strength of the geomagnetic storms were found to be different in contrast to similar super storms. The connection between the quantum of energy outflux from the upper atmosphere into space in terms of NO IRF and the duration of storms is established. The NO radiative cooling, and the closely correlated depletion in O/N₂ ratio are controlled by the Joule heating intensity (proxied by AE-index). The collisional excitation rate of NO, calculated using the modelled datasets of WACCM-X (Whole Atmosphere Community Climate Model with thermosphere and ionosphere extension), correlates well with the observed pattern of radiative emission by NO. Observational datasets from TIMED/GUVI (Global Ultra-Violet Imager) and MIT Haystack observatory madrigal GNSS (Global navigation satellite system) total electron content (TEC) database shows that the TEC and O/N₂ enhancement in low-mid northern hemispheric latitudes are mainly controlled by the z-component of Interplanetary magnetic field (IMF-B_z). The penetration of eastward electric field during the storm events is found to be responsible for the overall enhancement of TEC. The contribution of enhanced day-side TEC in observed variation of O/N₂ ratio by GUVI is also reported. It is also seen that during substorms related events the night-time polar region experiences more cooling due to NO than the daytime polar region. The connections between the mid- and low-latitude enhancement in NO IRF with the propagation of LSTIDs (Large-scale traveling ionospheric disturbances) in combination with the O/N₂ variability, and the altitudinal variation in NO flux with the progression of the storm is also investigated. This study presents the evidence on the role of diffusion processes in the large scale enhancement of NO in the mesospheric altitudes.     

燃料电池接触电阻与温度相关性研究

研究双极板与气体扩散层接触电阻的形成机理，分析影响该接触电阻的因素，包括温度、载荷以及粗糙度等参数。通过建立数学模型以及利用仿真工具来预测接触电阻数值与变化规律，并进行金属双极板和碳纸气体扩散层的界面接触电阻测试用于模型验证，模型计算结果与实验结果吻合较好。