C/C复合材料1 800℃抗氧化涂层探索研究

提出并制备了可以应用于1 800℃的抗氧化涂层体系,固渗法制备SiC内层,料浆涂刷法制备高温氧化物釉层和硼硅化物釉层.经扫描电镜分析涂层形貌及电子能谱分析其组成,发现C/C复合材料基材结构完整,没有发生次表面氧化.试验结果表明氧乙炔焰烧蚀20 s后,失重为0.06%;1 800℃自然对流氧化试验条件下,氧化物釉层30 min的平均失重速率为0.06g/(m2·s);硼硅化物釉层60min的平均失重速率为0.2g/(m2·s).说明涂层体系在1 800℃具有良好的抗氧化能力.     

基于静强度分布的复合材料疲劳寿命分布的预测模型(英文)

The reasons of the static strength dispersion and the fatigue life dispersion of composite laminates are analyzed in this article. It is concluded that the inner original defects, which derived from the manufacturing process of composite laminates, are the common and major reason of causing the random distributions of the static strength and the fatigue life. And there is a correlative relation between the two distributions. With the study of statistical relationship between the fatigue loading and the fatigue life in the uniform confidence level and the same survival rate S-N curves of material, the relationship between the static strength distribution and the fatigue life distribution through a material S-N curve model has been obtained. And then the model which is used to describe the distributions of fatigue life of composites, based on their distributions of static strength, is set up. This model reasonably reflects the effects of the inner original defects on the static strength dispersion and on the fatigue life dispersion of composite laminates. The experimental data of three kinds of composite laminates are employed to verify this model, and the results show that this model can predict the random distributions of fatigue life for composites under any fatigue loads fairly well.     

石墨纤维/改性氰酸酯复合材料的应用研究

采用环氧树脂对4,4-二氰酸酯基二苯基丙烷(BADCy)进行共聚改性,通过DSC分析,确定了固化工艺参数,并与石墨纤维(UHMCF)复合制成单向板,测试了不同后处理温度制得的单向板力学性能,并与现用UHMCF/树脂基复合材料单向板的力学性能进行了比较,测试了UHMCF/改性氰酸酯的空间环境性能;制备了UHMCF/改性氰酸酯结构件,测试其性能,并与现用UHMCF/树脂基复合材料同类结构件的性能进行了比较。结果表明:UHMCF/改性氰酸酯不论是单向板还是结构件的性能均优于现用UHMCF/树脂基复合材料的性能,且满足空间环境对航天器结构材料性能的要求。     

复合材料桨叶固有特性计算与试验研究

直升机旋翼的固有特性是直升机动力学问题研究的基础。文中运用有限元方法分析了模型旋翼复合材料桨叶的固有特性。运用ANSYS软件计算了桨叶的固有频率和振型,并通过试验测量了桨叶的固有频率。结果表明用有限元方法计算复合材料桨叶的固有特性与试验值吻合。     

改性双马来酰亚胺树脂在RFI工艺中的应用

通过在改性双马来酰亚胺5405树脂中加入耐高温热塑性塑料聚芳醚砜(PES),获得了满足RFI工艺要求、具有良好成膜性的5405A树脂膜.该树脂膜在室温不粘手,能够任意弯曲.在熔渗温度(130℃)下,低黏度(≤500mPa·s)的保持时间长达70min.在宦温存放3个月后,不溶物含量由1.25%变化为2.02%,DSC曲线表明反应的峰始温度和峰顶温度与放置前无明显差异,130℃凝胶时间由137min变化为135min.参照5405树脂的固化工艺,制备了5405A树脂浇铸体和单向碳纤维帘子布(G0827)增强5405A复合材料,并对性能进行了评价.对比5405和5405A树脂树脂浇铸体的性能表明,5405A力学性能稍有降低,但韧性得到了明显提高.     

先进复合材料格栅结构制造工艺技术的研究进展

介绍了复合材料格栅结构的特点及发展现状,并回顾了传统复合材料成型工艺方法和格栅结构的早期制造方法。另外,介绍2种新型的格栅结构加工方法,即混合加工法、膨胀模块加工法以及改进的格栅结构:互锁复合材料格栅结构、加套管的槽形连接格栅结构和TR IG结构;并分别说明了每种结构的优点。其中重点介绍了混合加工法并从理论上推导其可行性。最后总结了复合材料格栅结构制造工艺的发展趋势。     

Compression Creep Behavior of High Volume Fraction of SiC Particles Reinforced AI Composite Fabricated by Pressureless Infiltration

The compression creep deformation of the high volume fraction of SiC particles reinforced AI-Mg-Si composite fabricated by pressure-less infiltration was investigated. The experimental results show that the creep stress exponents are very high at temperatures of 673 K, 723 K and 773 K, and if taking the threshold stress into account, the true stress exponent of minimum creep strain rate is still approximately 5, although the volume fraction of reinforcements is very high. The creep strain rate in the high volume fraction reinforced aluminum alloy matrix composites is controlled by matrix lattice diffusion. It is found that the creep-strengthening effect of high volume fraction of silicon carbide particles is significant, although the particles do not form effective obstacles to dislocation motion.     

火箭发动机喷管辐射及壁温的计算研究

研究了火箭发动机复合喷管的耦合换热及瞬态壁温的计算方法,考虑了扩散控制的C/C喉衬的稳态烧蚀,建立了封闭腔-净辐射模型计算喷管内的辐射换热,改进了喷管辐射换热的计算方法.计算了两种复合喷管的壁温随时间的变化,并与有关文献的结果进行对比.研究表明:在火箭发动机喷管的入口段,高温燃气对壁面的辐射换热热流比对流换热热流强;采用封闭腔-净辐射法计算火箭发动机喷管的辐射精度较高.      

电子散斑测振技术在航空发动机上的应用

介绍了电子散斑测振技术的发展,侧重阐述了基于该技术的时间平均法测振的原理;重点介绍了该技术在航空发动机零部件振动测量、复合材料结构和蜂窝夹层结构的无损检测中的应用.     

硅基复合材料粘性系数的参数辨识

硅基复合材料是目前国内比较成熟、综合性能较好的烧蚀型热防护材料之一,高温粘性系数是这类材料烧蚀性能的重要表征参数.本文利用系统识别原理,给出这类复合材料粘性系数的参数辨识方法及其应用实例.