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概述了世界主要聚丙烯腈(PAN)基碳纤维生产厂家在各自生产工艺下的碳纤维原丝或碳纤维的质量状况。综述了提高PAN基碳纤维原丝质量的研究进展。重点讨论了我国以丙烯腈(AN)、丙烯酸甲酯(MA)、衣康酸(ITA)为单体,以硫氰酸钠(NaSCN)为溶剂,采用一步法均相溶液聚合制得聚丙烯腈原液,经纺丝制得碳纤维原丝过程中存在的问题。指出我国原丝质量不能真正过关的根本原因,提出了我国现阶段碳纤维的发展方向。 相似文献
464.
电火花小孔加工中存在工具电极损耗严重、加工速度慢、棱角变钝出现锥度等问题。分析其存在问题的原因,提出采用铜铬复合电极进行电火花小孔加工。分析其加工机理并进行实验,实验结果表明:采用铜铬复合电极进行小孔加工比采用铜电极进行小孔加工能显著提高加工速度,减小锥度和电极相对损耗。 相似文献
465.
Physiologic and metabolic responses of wheat seedlings to elevated and super-elevated carbon dioxide
Lanfang H. Levine Hirokazu Kasahara Joachim Kopka Alexander Erban Ines Fehrl Fatma Kaplan Wei Zhao Ramon C. Littell Charles Guy Raymond Wheeler John Sager Aaron Mills Howard G. Levine 《Advances in Space Research (includes Cospar's Information Bulletin, Space Research Today)》2008
The metabolic consequence of suboptimal (400 μmol mol−1 or ppm), near-optimal (1500 ppm) and supra-optimal (10,000 ppm) atmospheric carbon dioxide concentrations [CO2] was investigated in an attempt to reveal plausible underlying mechanisms for the differential physiological and developmental responses to increasing [CO2]. Both non-targeted and targeted metabolite profiling by GC–MS and LC–MS were employed to examine primary and secondary metabolites in wheat (Triticum aestivum, cv Yocoro rojo) continuously exposed to these [CO2] levels for 14, 21 and 28 days. Metabolite profile was altered by both [CO2] and physiological age. In general, plants grown under high [CO2] exhibited a metabolite profile characteristic of older plants under ambient CO2. Elevated [CO2] resulted in higher levels of phosphorylated sugar intermediates, though no clear trend in the content of reducing sugars was observed. Transient starch content was enhanced by increasing [CO2] to a much greater extent at 10,000 ppm CO2 than at 1500 ppm CO2. The percentage increase of starch content resulting from CO2 enrichment declined as plants develope. In contrast, elevated [CO2] promoted the accumulation of secondary metabolites (flavonoids) progressively to a greater extent as plants became mature. Elevated [CO2] to 1500 ppm induced a higher initial growth rate, while super-elevated [CO2] appeared to negate such initial growth promotion. However, after 4 weeks, there was no difference in vegetative growth between 1500 and 10,000 ppm CO2-grown plants, both elevated CO2 levels resulted in an overall 25% increase in biomass over the control plants. More interestingly, elevated atmospheric [CO2] reduced evapotranspiration rate (ET), but further increase to the supra-optimal level resulted in increased ET (a reversed trend), i.e. ET at 1500 ppm < ET at 10,000 ppm < ET at 400 ppm. The differential effect of elevated and super-elevated CO2 on plants was further reflected in the nitrogen dynamics. These results provide the potential metabolic basis for the differential productivity and stomatal function of plants grown under elevated and super-elevated CO2 levels. 相似文献
466.
LIU Hua YANG Jia-ling LIU Kai-xin 《中国航空学报》2007,20(3):210-214
Theoretical analysis and numerical calculations of Love wave propagation in layered graded composites with imperfectly bonded interface are described in this paper. On the basis of WKB method, the approximate analytic solutions for Love waves are obtained. By the interface shear spring model, the dispersion relations for Love waves in layered graded composite structures with rigid, slip, and imperfectly bonded interfaces are given, and the effects of the interface conditions on the phase velocities of Love waves in SiC/Al lay- ered graded composites are discussed. Numerical analysis shows that the phase velocity decreases when the defined flexibility parameter is greater. For the general imperfectly bonded interface, the phase velocity changes in the range of the velocities for the rigid and slip interface conditions. 相似文献
467.
The friction and wear properties of amorphous carbon nitride(a-CN x)coatings in water lubrication were reviewed.The influences of mating materials and tribological variables such as normal load(W)and sliding speed(V)on the friction and wear properties of the a-CN x coatings were analyzed.It was indicated that the specific wear rate of the a-CN x coatings was related to the hydration reaction of mating materials with water.If the mating materials were easily hydrated,the specific wear rate of a-CN x coatings was low.The water-lubricated properties of the a-CN x coatings were better in comparison to the a-C coatings.The a-CN x/Si-based non-oxide ceramics tribo-pairs exhibited the lowest friction coefficient and wear rate.To describe their friction and wear properties at the normal loads of 3—15Nand the sliding speeds of 0.05—0.5m/s,the wear-mechanism maps for the a-CN x/SiC(Si3N4)tribo-pairs in water were developed. 相似文献
468.
为研究复合材料层合板在雷电流作用下的烧蚀损伤力学特性,建立复合材料雷击热力耦合有限元分析模型,与文献实验结果对比验证模型的有效性。根据Hashin三维失效准则编写用户材料子程序,分别得出层合板雷击烧蚀区域周围出现的力学损伤、各层力学损伤分布以及首层在不同方向上的应力分布,分析得出层合板的烧蚀损伤随雷电流持续时间的变化规律。结果表明:由于存在较高的温度梯度,导致层合板出现较大的热膨胀应力,进而导致层合板内部产生各种力学损伤,即基体开裂、分层及纤维断裂;雷击电流施加时间、峰值电流与温度场均对层合板烧蚀面积产生较大的影响。 相似文献
469.
复合材料层合板下陷是飞机结构中应用广泛的典型结构细节。以下陷长深比、相同方向下陷区间距、两个不同方向下陷区间距为下陷区设计变量,建立参数化有限元模型;通过下陷应力应变分布、初始失效和最终承载能力分析,确定各设计变量对下陷区结构力学性能的影响,并进行参数化设计。分析结果表明:下陷区结构最先发生损伤的部位为下陷区转折处;合理的下陷参数设计变量取值为长深比B/A≥20、主受力方向上两个下陷区间距A/H≥12、不同方向上两个下陷区间距C/A_(min)≥1.5。 相似文献
470.
《中国航空学报》2020,33(5):1541-1548
Uni-directional carbon/carbon composites with high thermal conductivity are suitable to supply continuous thermal protection for future reentry vehicles since they could reduce surface temperature and ablation rates simultaneously in harsh environments. In this work, the high thermal conductivity carbon/carbon composites were prepared by chemical vapor infiltration. After heat-treatment, both their open porosity and internal friction increase due to the fiber/matrix thermal expansion mismatch; while their thermal conductive performance become better due to more complete carbon structure. With raising heat-treatment temperature from 1800 °C to 2450 °C, the mass and linear ablation rates of C/C composites with fibers vertical to the oxyacetylene torch for 60 s decrease from 0.66 mg/s and 2.95 μm/s to 0.51 mg/s and 2.05 μm/s respectively. The improved ablation resistance is resulted from the increased thermal conductivity from 282 to 508 W/(m·K) and more carbon fibers exposed to the flame during ablation, which have better oxidation resistance than those of carbon matrix. While such ablation rates become larger for composites with fibers parallel to the flame, from 1.02 mg/s and 3.73 μm/s to 1.28 mg/s and 5.01 μm/s respectively since the ablation occurred more easily through gaps at the fiber/matrix interfaces, which become larger and are always exposed to the flame for this case. 相似文献