电沉积CeO2/Zn纳米复合涂层

将纳米氧化铈颗粒加入镀锌液中进行复电沉积制得纳米复合涂层。通过失重法，ICP，SEM和XRD方法探讨了纳米氧化铈颗粒对电沉积锌涂层的影响。结果表明，在同样的电沉积条件下，纳米复合涂层的耐蚀性明显提高，而微米复合涂层的耐蚀性只稍有改善；纳米复合涂层中氧化铈的含量高于微米复合涂层中的氧化铈含量。纳米氧化铈颗粒改变了锌涂层的表面组织形貌和晶体结构，从而提高了涂层的耐蚀性。     

回归设计铝合金7075微弧氧化形膜控制及膜特性

通过二次回归通用旋转组合设计了铝合金7075微弧氧化实验,建立了回归模型,量化了对陶瓷膜的多变量互约组合的影响趋势,解决了对生长陶瓷膜可预测、可控制的工艺。通过工艺特性曲线、金相分析、X射线衍射、扫描断层分析、摩擦磨损实验等手段,对形成的陶瓷膜特性进行了分析。结果表明:采用回归设计铝合金7075微弧氧化工艺是可行有效的,可在很大范围内调节陶瓷膜的微观和宏观结构,调节陶瓷膜相的比例关系,获得防腐、耐磨、电绝缘等高品质陶瓷膜。     

光学太阳反射器的性能评价试验规范

航天器在地面待发射期间和空间实际飞行过程中，热控元件光学太阳反射器要遇到各种地面和空间环境，为了航天器的可靠和长寿命，必须对所制备的ＯＳＲ涂层进行各种地面和空间环境试验并对其各项性能检验与考核，该文就这一系列试验的目的和规范进行了讨论。     

防静电白色热控涂层的空间环境性能试验

通过在氧化锌晶格中掺入重金属离子，得到具有防静电功能的白色颜料，再以丙烯酸树脂为粘合剂制备出空间飞行器外表面用的ACR－1防静电白色热控涂层；研究了空间环境效应（包括紫外辐照，电子和质子辐照）对该热控涂层太阳吸收率的影响并与有机硅白色热控涂层进行了比较，地面模拟空间环境试验研究结果证明，ACR－1防静电白色热控涂层具有良好的空间稳定性。     

Flow mechanism between purge flow and mainstream in different turbine rim seal configurations

The rim seal is used to prevent mainstream ingestion to the gap between the vane of a turbine and its blade. In this article, the dolphin lip with a hook configuration and a large seal cavity with hook structures are designed based on the high-pressure turbine datum single shark lip rim seal configuration. The sealing effect and parameters of the flow field are measured by an experiment method and a numerical simulation is used to explain the mechanism. For three configurations, the effect of the leakage slot vortex on the efficiency of the seal and the influence of leakage vortex, generated by the interaction between purge flow and mainstream flow, are discussed in depth. The result shows that the reverse vortex formed by the dolphin lip rim seal with hook structure will increase the sealing efficiency. The seal configuration with a large cavity improves sealing efficiency to a greater extent than the datum structure. At different purge flow rates and with unequal seal structures, the purge flow produces three types of leakage vortices in the passage. Besides, the seal configuration with dolphin lip produces a Kelvin-Helmholtz instability at the interface of the purge and the mainstream flows at a low purge flow rate to induce new leakage vortex branches in the passage of the blade.     

聚氨酯涂层体系特性与性能分析研究

为了获得不同聚氨酯涂层的防护特性试验数据,采用漆层参数指标特性分析和样件耐受环境试验的方法,对装备表面起防护作用的聚氨酯防护涂层的综合特性进行分析和研究。研究结果可作为工艺研究和指导生产的参考依据。     

Corrosion mechanism investigation of TiN/Ti coating and TC4 alloy for aircraft compressor application

It is imperative to develop multifunctional erosion and corrosion resistant coatings for compressor blades of aircraft engines in harsh environment. PVD (Physical Vapor Deposition) technology has the advances in processing erosion-resistant coatings; however, the performance of PVD coatings to combat corrosion depends on various coating defects. Determining and comparing the corrosion performances of PVD TiN/Ti coating and uncoated TC4 alloy was the main objective of present work. The 960 h salt spray corrosion and 116 h hot corrosion tests were conducted to simulate the grounding and working environments of the aircraft compressors. The corrosion mechanisms due to the coating defects such as pinhole, columnar boundary and large grain were analyzed based on the OM, Confocal microscope, electrochemical measurements, SEM, XRD and EDS results. Owing to the disordered state associated with the columnar boundary and the coating defect, nitrogen could be easily replaced by oxygen in the hot corrosion process, these structures were channels for fast diffusion of oxygen. Moreover, the Gibbs energy changes of Ti oxidation and TiN oxidation were thermodynamically calculated according to the working condition of aircraft compressors, and considerable research effort was focused on mapping out the phase diagram of Ti, TiN and high pressure gases. The findings of this research can provide insights into developing multifunctional coatings for future aircraft engines.     

刷式封严初期使用特性的实验和数值研究

为了获得刷式封严在使用初期的泄漏特性,分别对两组实验件进行了27小时和50小时的泄漏特性实验,并利用多孔介质模型对实验结果进行了数值分析。实验表明:在使用初期,刷式封严的泄漏量与上下游的压差成正比;随着使用时间的增加,其泄漏水平逐渐降低直至最后趋于稳定。数值分析表明:在使用初期,刷丝排列由最初的疏松状态逐渐趋于紧密,并最终稳定在接近于紧密差排的状态,刷丝排列状态的变化改变了刷束的孔隙率,从而改变了刷束对流体泄漏的阻力,导致了刷式封严泄漏水平的变化。     

纳米复合镍粉雷达吸波涂层研究

采用机械化学法将纳米SiC包覆在镍粉表面制备复合吸波材料,将该材料喷涂在基体上制备吸波涂层,并研究了SiC在复合材料中的含量变化对涂层吸波性能的影响.研究表明,SiC含量为10%时,纳米复合涂层的吸波性能最佳.与镍粉吸波涂层相比,该纳米复合涂层中频段的吸波性能明显提高,发射率小于-5 dB的带宽由7 GHz增加到10.4 GHz,涂层最高吸收值达到-23.4 dB.     

划痕法表征TD处理制备的VC涂层界面结合强度

 为了测定碳化钒(VC)涂层与基体之间的结合强度,分析涂层与基体的结合机制,采用热扩散(TD)处理在冷作模具钢Cr12MoV表面制备了VC涂层,通过扫描电镜(SEM)观察了其表面与界面形貌,利用能谱议(EDS)分析了结合界面的V、C元素的分布,用划痕法测定了涂层与基体的界面结合强度,并对涂层失效机理进行了分析.结果表明,经TD处理制备的VC涂层与基体结合界面为成分梯度界面,二者结合面为成分含量呈梯度变化的过渡层,V元素含量从表面到基体逐渐下降,而C元素含量逐渐上升;其结合界面处化学元素相互结合,形成冶金结合,测得涂层与基体的结合强度平均值为45.7 N;涂层失效形式为界面层的压裂,其结合强度主要与VC涂层残余压应力有关.