Halocarbons, such as CFC-11, CFC-12 and HCFC-22, are important trace gases in the atmosphere through their role as greenhouse gases and their influence on stratospheric ozone chemistry. This paper focuses on an initial study using integration of spectral radiance measurements from a spaceborne limb sounding Fourier Transform Spectrometer (FTS) to retrieve these compounds in the upper troposphere and lower stratosphere (UTLS). The instrument employed in this study is the Michelson Interferometer for Passive Atmospheric Sounding onboard ENVISAT (MIPAS-E) which obtains spectral data in the altitude range of 6–68 km at an unapodized spectral resolution of 0.025 cm−1. We have used optimal estimation techniques to retrieve vertical information for these compounds using a radiometric approach.
It is shown that significant retrieval information is obtained at up to five measured levels in the UTLS for CFC-11, up to six for CFC-12 and up to two levels for HCFC-22. An initial error analysis indicates significant sensitivity of our retrievals to variability in operationally retrieved pressure and temperature data. For each halocarbon, gain, offset and spectroscopic uncertainties generally each contribute less than 10% to the total error. Finally, tracer correlations are used to compare the datasets to equivalent relationships derived here from version 2 ATMOS data with very good agreements for CFC-12 but with more variability in the CFC-11 comparisons. 相似文献
To deeply understand the dynamic recrystallization behavior of as-cast AZ12 magnesium alloy in deformation process, the uniaxial hot compression experiments were implemented through systematic isothermal compression experiments. The true strain of thermal compression experiments was set to 50% with temperatures of 200, 250, 300, 350, 400 °C and the strain rates of 0.001, 0.01, 0.1, 1 s?1. The Dynamic Recrystallization (DRX) kinetic model of AZ12 magnesium alloy was established and the accuracy of this model was verified. The model is used to predict the volume fraction of the sheet obtained by rolling through different rolling passes under the condition of consistent total reduction (50%). And the predicted results are in good agreement with the experimental results. 相似文献
This paper reports the diurnal, seasonal, and long term variability of the E layer critical frequency (foE) and peak height (hmE) derived from Digisonde measurements from 2009 to 2016 at the low-middle latitude European station of Nicosia, Cyprus (geographical coordinates: 35°N, 33°E, geomagnetic lat. 29.38°N, I = 51.7°). Manually scaled monthly median values of foE and hmE are compared with IRI-2012 predictions with a view to assess the predictability of IRI. Results show that in general, IRI slightly overestimates foE values both at low and high solar activity. At low solar activity, overestimations are mostly limited to 0.25?MHz (equivalent electron density, 0.775?×?103?el/m?3) but can go as high as 0.5?MHz (equivalent electron density, 3.1?×?103?el/m?3, during noon) around equinox. In some months, underestimations, though sporadic in nature, up to 0.25?MHz are noted (mostly during sunrise and sunset). At high solar activity, a similar pattern of over-/underestimation is evident. During the entire period of study, over-/under estimations are mostly limited to 0.25?MHz. In very few cases, these exceed 0.25?MHz but are limited to 0.5?MHz. Analysis of hmE reveals that: (1) hmE remains almost constant during ±2 to ±4?h around local noon, (2) hmE values are higher in winter than in spring, summer and autumn, (3) there are two maxima near sunrise and sunset with a noontime minimum in between. During the entire period of study, significant differences between observed hmE and the IRI predictions have been noted. IRI fails to predict hmE and outputs a constant value of 110?km, which is higher than most of the observed values. Over- and under estimations range from 3 to 13?km and from 0 to 3?km respectively. 相似文献