纳米金刚石改性LLDPE的非等温结晶动力学

采用X射线衍射(XRD)、偏光显微镜(POM)以及差示扫描量热(DSC)法,考察了纳米金刚石(Nano-diamond)对线型低密度聚乙烯(LLDPE)的结晶形态以及非等温结晶行为的影响。通过Jeziorny法和莫志深法研究了复合材料的非等温结晶动力学,并利用Kissinger方程计算了LLDPE/Nano-diamond复合材料的非等温结晶活化能。结果表明:Nano-diamond是一种有效的成核剂,为LLDPE结晶提供了更多的活化晶核,起到了异相成核的作用,既提高了LLDPE的结晶起始温度To、结晶峰值温度Tp和结晶速率,又降低了球晶的尺寸,使得球晶的分布更为均匀致密;添加Nano-diamond使得复合材料的结晶迁移活化能降低,当Nano-diamond含量为1%时,复合材料结晶活化能达到最小值。     

孔隙分布对陶瓷材料热辐射特性的影响

通过引入吸收性介质内粒子散射Mie理论,结合多弥散粒子系独立散射理论,针对孔隙具有修正Gamma分布规律的多孔陶瓷提出一种计算热辐射特性的方法,以氧化锆陶瓷为例分析了孔隙分布对热辐射特性的影响.结果表明孔隙分布规律和平均孔径对热辐射特性有显著影响.孔径趋于单弥散分布,将使衰减系数、散射反照率、非对称因子等参数减小,而孔...     

基于CD4046构成的PLL及应用

CD4046构成的PLL在通信、频率处理、自动控制等技术领域中应用较为广泛，正确理解CD4046对掌握电路基本组成、原理及应用。对处理实际工程问题有很大帮助。     

Remote sounding of atmospheric gravity waves with satellite limb and nadir techniques

Recent advances in satellite techniques hold great potential for mapping global gravity wave (GW) processes at various altitudes. Poor understanding of small-scale GWs has been a major limitation to numerical climate and weather models for making reliable forecasts. Observations of short-scale features have important implication for validating and improving future high-resolution numerical models. This paper summarizes recent GW observations and sensitivities from several satellite instruments, including MLS, AMSU-A, AIRS, GPS, and CLAES. It is shown in an example that mountain waves with horizontal wavelengths as short as 30 km now can be observed by AIRS, reflecting the superior horizontal resolution in these modern satellite instruments. Our studies show that MLS, AMSU-A and AIRS observations reveal similar GW characteristics, with the observed variances correlated well with background winds. As a complementary technique, limb sounding instruments like CRISTA, CLAES, and GPS can detect GWs with better vertical but poorer horizontal resolutions. To resolve different parts of the broad GW spectrum, both satellite limb and nadir observing techniques are needed, and a better understanding of GW complexities requires joint analyses of these data and dedicated high-resolution model simulations.     

7715D 高温钛合金铌钼含量的连续测定方法

研究与运用氧化亚氮－乙炔火焰原子吸收光谱法连续测定７７１５Ｄ高温钛合金中的铌钼含量。介绍了铌钼的最佳测定条件及呈良好线性范围的浓度，并对干扰因素进行了综合考虑。该方法灵敏度高，干扰小、选择性和重现性好。对样品进行１０次测定的结果表明，相对标准偏差均小于１．５％，标准加入回收率在９７％～１０３％范围内，完全适用于７７１５Ｄ高温钛合金铌钼含量的测定。     

Detonation waves induced by a confined wedge

An auto-ignition detonation phenomenon can be initiated by a wedge confined in a channel. A new, self-sustaining, normal detonation wave engine concept is proposed. The detonation processes were numerically modeled with a simplified two-dimensional wedged channel flow that was deemed to emulate a real three-dimensional configuration. The results showed that within certain ranges of incoming flow Mach number or wedge angle, detonation could be self ignited in the channel. The study furthermore investigated the detonation waves based on three different detonation initiation positions. Different configurations of the detonation waves were observed and analyzed. The performance of the different detonation wave configurations was estimated and compared.     

ATP/BPS交联体合成及性能研究

以丁二酸和丙炔醇为原料,合成出了丁二酸双丙炔醇酯( BPS),借助于叠氮基与炔基叁键之间的1,3-偶极环加成反应,完成了对叠氮粘合剂ATP 的交联固化。由于异氰脲酸酯基团的引入, ATP 基聚三唑交联体力学性能明显优于GAP基聚三唑。在研究的范围内,常温抗拉强度为0.792~2.05 MPa,延伸率为90%~70%。其中,90.27%ATP/9.73%BPS配方具有较好的综合性能。     

Wave perturbations in the MLT at high northern latitudes in winter,observed by two SATI instruments

To investigate the Mesosphere and Lower Thermosphere (MLT) region, several ground-based instruments called SATI (Spectral Airglow Temperature Imager) were designed and built to measure airglow emission and temperature in the upper mesosphere. One SATI instrument was installed at Resolute Bay (74.7°N, 94.9°W) and has monitored the polar MLT region since November, 2001. In October 2007 another SATI instrument was installed at Eureka (80.0°N, 86.3°W) at the Polar Environment Atmospheric Research Laboratory (PEARL) as part of the Canadian Network for the Detection of Atmospheric Change (CANDAC) project. SATI is a spatial scanning Fabry–Perot spectrometer measuring column emission rates for several rotational lines of OH and O₂ airglow at 87 and 94 km height. The rotational temperatures are inferred from the ratios of these lines. The measurements are divided into 12 sectors with an annular field of view. The phase differences between the sectors yield information on the horizontal atmospheric wave direction and wavelength. Horizontal perturbations of 2–8 h period have correlatively been observed and investigated at both locations. Short-periodic oscillations identified as gravity waves with periods between 2 and 8 h propagate in southward and eastward directions, but in opposite directions in some cases. The wave propagation characteristics are often different at the two locations; the relationship with the lower mean wind is considered.     

硼酸酯键合剂在丁羟四组元推进剂中作用机理研究

采用反相气相色谱仪测试了BA-5键合剂,RDX,AP和HTPB-TDI胶片的表面酸碱性参数,并估算出各组分之间的界面相互作用焓。结果表明ΔHBA-RDX和ΔHBA-AP均显著大于ΔHBA-HTPB,证实键合剂BA-5与RDX,AP作用力远大于与粘合剂作用力,能在混合过程中优先迁移吸附在RDX,AP颗粒表面,并产生强烈吸附。采用电子能谱仪定性表征了RDX,AP从HTPB中吸附BA-5的情况。结果表明:随着电子束加速电压降低,测试厚度变小,AP样品中硼原子含量增加,证实BA-5是吸附在AP的表面。结合组分基团活性分析,阐述了BA-5键合剂的作用机理。     

非正弦时域正交调制系统定时误差抑制方法

定时误差可使非正弦时域正交调制系统的解调性能显著下降。针对该问题,该文提出了基于保护间隔的定时误差抑制方法。在分析非正弦时域正交调制信号特征的基础上,公式推导了定时误差在相关接收时引起的干扰分量,理论分析了码元间插入保护间隔的定时误差抑制方法的可行性,并进行了仿真验证。结果表明,这种方法可有效的提高系统的误码率性能。该方法尤其适合于对定时误差敏感或精确同步困难的通信系统。