镁基水反应金属燃料的热分解性能

采用热重-差热分析联用(TG-DTA)、差示扫描量热(DSC)、加压热重(PTG)等热分析方法,研究了镁基水反应金属燃料热分解反应的基本特性及其变化规律。研究发现,燃料热分解过程中先后发生AP分解反应、HTPB分解反应,氩气中不发生Mg的氧化反应;添加催化剂、减小AP粒度、增大氧化剂与粘合剂比例、增大细Mg粉含量等,可以降低燃料中AP的分解温度T,减小表观活化能Ea,增大反应速率常数k;减小AP粒度、增大氧化剂与粘合剂比例可以降低燃料中HTPB的分解温度,减小表观活化能Ea,增大反应速率常数k;随着压强增大,AP与HTPB分解失重速率增大、AP失重百分数增大、燃料热分解凝聚相产物质量百分数减少,压强对AP分解影响较大,对HTPB分解影响较小。     

制泥废水及烧结废水的处理与回用

通过对处理制泥废水及烧结废水工艺、设备、措施及综合利用进行了详细的描述,对拟用新措施将污水二次处理预期达到饮用及绿化水标准提出了建设性的设想,采用现代计算机FLASH软件将生产工艺制作成动画演示,强化了工厂管理体系.     

压缩空气瓶内凝结水水位检测方法的探讨

由于压缩空气瓶在使用过程中会出现瓶内残留凝结水的现象,从而影响压缩空气瓶的容积,并产生化学腐蚀,影响气瓶的整体强度和耐压性能及其的寿命。为此,应掌握气瓶内凝结水水位情况,并且提高检测水位准确度。提出了一种利用气体状态方程来计算压缩空气瓶的冷凝水水位新见解,对压缩空气瓶的安全使用具有重要意义。     

Kinetics of gas-Grain Reactions in the Solar Nebula

Thermochemical equilibrium calculations predict gas phase, gas-grain, and solid phase reactions as a function of pressure and temperature in the solar nebula. However, chemical reactions proceed at different rates, which generally decrease exponentially with decreasing temperature. At sufficiently low temperatures (which vary depending on the specific reaction) there may not have been enough time for the predicted equilibrium chemistry to have taken place before the local environment cooled significantly or before the gaseous solar nebula was dispersed. As a consequence, some of the high temperature chemistry established in sufficiently hot regions of the solar nebula may be quenched or frozen in without the production of predicted low temperature phases. Experimental studies and theoretical models of three exemplary low temperature reactions, the formation of troilite (FeS), magnetite (Fe₃O₄), and hydrous silicates, have been done to quantify these ideas. A comparison of the chemical reaction rates with the estimated nebular lifetime of 0.1-10 million years indicates that troilite formation proceeded to completion in the solar nebula. Magnetite formation was much slower and only thin magnetite rims could have formed on metal grains. Hydrous silicate formation is predicted to be even slower, and hydrous silicates in meteorites and interplanetary dust particles probably formed later on the parent bodies of these objects, instead of in the solar nebula. This revised version was published online in June 2006 with corrections to the Cover Date.     

An assessment of semi-analytical models based on the absorption coefficient in retrieving the chlorophyll-a concentration from a reservoir

Monitoring chlorophyll-a (Chl-a) concentrations in inland waters is crucial for water quality management, since Chl-a is a proxy for phytoplankton biomass and, thus, for ecological health of a water environment. Chl-a concentration can be retrieved through the inherent optical properties (IOPs) of a water system, which, in turn, can be remotely sensed obtained. Quasi-analytical algorithm (QAA), originally developed for ocean waters, can also retrieve IOPs for inland waters after re-parameterizations. This study is aimed at assessing the performance of sixteen schemes composed by QAA original and re-parameterized versions followed by models that use absorption coefficients as inputs for estimating Chl-a concentration in Ibitinga reservoir, located at Tietê River cascading system, São Paulo State, Brazil. It was verified that only QAA_V5 based schemes were able to obtain reasonable estimates for image data and that by four models tested presented similar and acceptable results for QAA_V5 outputs. The best model were applied to a Ocean and Land Colour Instrument (OLCI) image. Light absorption in the reservoir showed to be dominated by colored dissolved organic matter (CDOM), and wide spatial and temporal variability of optical and water quality properties was observed.     

Fronts and thermohaline structure of the Brazil–Malvinas Confluence System

Fronts and thermohaline structure of the Brazil–Malvinas Confluence System (BMCS) are studied from climatic data, “Marathon Exp. Leg.8, 1984” data, and Sea surface temperature (SST) data base “ds277-Reynolds” (1981–2000). The South Atlantic Central Water (SACW) is divided in two main types: tropical (TW) and subtropical water (ST). Water masses, Fronts, Inter-Frontal and Frontal Zones are analysed and classified: (a) the water masses: Tropical Low-Salinity Water, Tropical Surface Water, Tropical Tropospheric Water, Subtropical Low-Salinity Water, Subtropical Surface Water, Subtropical Tropospheric Water. T,S characteristics of intermediate, deep and bottom water defined by different authors are confirmed and completed; (b) the Inter-Frontal Zones: Tropical/Brazil Current Zone, Subtropical Zone and Subantarctic Zone; (c) the Frontal Zones: Subtropical, Subantarctic and Polar, and (d) the Fronts: Subtropical Front of the Brazil Current, Principal Subtropical Front, North Subtropical Front, Subtropical Surface Front, South Subtropical Front, Subantarctic Surface Front, Subantarctic Front and Polar Front. Several stable T–S relationships are found below the friction layer and at the Fronts. The maximum gradient of the oceanographic characteristics occurs at the Brazil Current Front, which can be any of the subtropical Fronts, depending on season. Minimum mean depth of the pycnocline coincides with the Fronts of the BMCS, indicating the paths of low-salinity shelf waters into the open ocean. In the work it is shown how to recover the horizontal and vertical thermohaline structure of waters from satellite data RSMAS SST.     

Cometary Deuterium

Deuterium fractionations in cometary ices provide important clues to the origin and evolution of comets. Mass spectrometers aboard spaceprobe Giotto revealed the first accurate D/H ratios in the water of Comet 1P/Halley. Ground-based observations of HDO in Comets C/1996 B2 (Hyakutake) and C/1995 O1 (Hale-Bopp), the detection of DCN in Comet Hale-Bopp, and upper limits for several other D-bearing molecules complement our limited sample of D/H measurements. On the basis of this data set all Oort cloud comets seem to exhibit a similar ratio in H₂O, enriched by about a factor of two relative to terrestrial water and approximately one order of magnitude relative to the protosolar value. Oort cloud comets, and by inference also classical short-period comets derived from the Kuiper Belt cannot be the only source for the Earth's oceans. The cometary O/C ratio and dynamical reasons make it difficult to defend an early influx of icy planetesimals from the Jupiter zone to the early Earth. D/H measurements of OH groups in phyllosilicate rich meteorites suggest a mixture of cometary water and water adsorbed from the nebula by the rocky grains that formed the bulk of the Earth may be responsible for the terrestrial D/H. The D/H ratio in cometary HCN is 7 times higher than the value in cometary H₂O. Species-dependent D-fractionations occur at low temperatures and low gas densities via ion-molecule or grain-surface reactions and cannot be explained by a pure solar nebula chemistry. It is plausible that cometary volatiles preserved the interstellar D fractionation. The observed D abundances set a lower limit to the formation temperature of (30 ± 10) K. Similar numbers can be derived from the ortho-to-para ratio in cometary water, from the absence of neon in cometary ices and the presence of S₂. Noble gases on Earth and Mars, and the relative abundance of cometary hydrocarbons place the comet formation temperature near 50 K. So far all cometary D/H measurements refer to bulk compositions, and it is conceivable that significant departures from the mean value could occur at the grain-size level. Strong isotope effects as a result of coma chemistry can be excluded for molecules H₂O and HCN. A comparison of the cometary ratio with values found in the atmospheres of the outer planets is consistent with the long-held idea that the gas planets formed around icy cores with a high cometary D/H ratio and subsequently accumulated significant amounts of H₂ from the solar nebula with a low protosolar D/H. This revised version was published online in June 2006 with corrections to the Cover Date.     

水工质微波加热推力器的击穿点火与离解损失估算

对水工质微波等离子推力器(MPT),用微波击穿气体放电产生等离子体的条件,数值估算了其点火的可行性;通过化学动力学计算证明了水工质MPT中离解损失的存在,并初步估算了理解损失的大小。结果表明,在1 kW的输入功率下水工质MPT的点火启动并不特别困难,从点火到稳定工作,能量吸收从场致电离、碰撞电离转变为热电离、碰撞电离和场致电离;水在MPT工作过程中会发生离解,离解损失在各类能量损失中所占的比重较大。     

Tomographic determination of the spatial distribution of water vapor using GPS observations

With the advent of the GPS navigation system, a promising ground based technique has been introduced which makes it possible to estimate the amount of water vapor in the troposphere from operational GPS networks at relatively low additional costs. While the estimation of the integrated amount is currently well established, the determination of the spatial water vapor distribution and its temporal variation are still a major challenge. To account for the vertical resolution, several tomographic approaches were pursued. We developed the software package AWATOS (atmospheric water vapor tomography software) which is based on the assimilation of double differenced GPS observations. Applying a least-squares inversion, the inhomogeneous spatial distribution of water vapor is determined. An extensive investigation has been carried out in Switzerland. GPS measurements are performed by the dense permanent Swiss national GPS network AGNES of the Swiss Federal Office of Topography (swisstopo). A total of 40 equally distributed water vapor profiles have been estimated on an hourly basis. For the purpose of validation, 22 radiosonde profiles were used at the GPS and meteorological station Payerne. Furthermore, data of the numerical weather model aLMo (alpine model in Switzerland, MeteoSwiss) were compared with the tomographic results. An overall good agreement of the three methods with an rms of better than 1.6 g/m³ absolute humidity was achieved. The results show that AGNES can be used as a dedicated network for the purpose of GPS-tomography, using a horizontal resolution of approximately 50 km and height layers of 300–500 m thickness in the lower troposphere.     

高温风洞收集口喷水降温数值仿真研究

针对高温风洞中扩压器前段壁面防热问题,提出对高温气流外缘喷水降温的方法。通过在收集器入口与喷管出口间安装喷水环,利用液态水汽化吸热对高温气流进行降温,使扩压器壁面形成低温保护层。为了解该方法降温效果,本文利用DPM、组分输运等模型的耦合建立了超声速两相流CFD模型,对向超声速热气流喷水进行降温的过程进行了数值计算,计算结果表明,扩压器启动后有显著的降温保护效果。同时,为探索风洞排气背压和喷水量对风洞流场和壁面降温效果的影响,通过计算得出了变排气背压、变喷水量与降温效果之间的关系,为高温风洞收集口喷水降温装置的优化设计提供了参考。