聚酰亚胺胶粘剂的粘接性能

 采用等摩尔的酮酐（BTDA）和醚胺（ODA）在N,N 二甲基甲酰胺(DMF)中合成了线形缩聚型聚酰胺酸(PAA),并用红外光谱对其结构进行了表征,用TGA对其热关环亚胺化后进行了分析,结果表明其热分解温度可达600 ℃,所成薄膜具有良好的韧性。同时采用纳迪克酸酐（NA）为封端剂,通过调整NA/BTDA/ODA的比例,合成了不同分子量的PAA预聚体,并用红外光谱对其结构进行了表征,对其热关环亚胺化后进行差热分析,表明其端基交联固化温度为350 ℃左右,且随着分子量的提高峰温向高温方向移动。TGA表明,热固性聚酰亚胺（PI）交联固化后的热分解温度为483 ℃左右。采用上述线形缩聚型PAA与热固性PI共混,将固化后线形缩聚型PI的韧性与热固性PI高温性能结合起来,直接用做耐高温胶粘剂,可以获得较高的室温和高温剪切强度,并具有良好的高温热老化性能。     

直径比对冲击气膜组合冷却流动与换热的影响

 通过数值模拟,研究了涡轮叶片弦中区所采用的新型双层腔冷却结构的冷却特性,系统分析了冲击气膜组合冷却的流动与换热特性,讨论了冷气进口雷诺数Re、吹风比M以及气膜孔与冲击孔的直径比D/d对组合冷却效果的影响。计算参数范围是：冷气进口雷诺数Re＝2 000～5 000,吹风比M＝0.6～2.0。计算结果表明, 冷气进口Re,M以及D/d对双层腔结构冷却效果的影响非常明显,在计算范围内:（1）Re和M越高,冷却效果越好;（2）当冲击孔直径一定时,增加气膜孔的直径,冷却效果会随之增加;（3）当冲击孔直径一定时,增加气膜孔的直径,流阻系数会随之减小。     

低功率激光-TIG电弧复合焊接不锈钢熔深研究

建立了一套低功率YAG脉冲激光-TIG电弧复合热源焊接系统,并用本系统对不锈钢1Cr18Ni9Ti进行焊接.研究了3种热源作用下不锈钢的焊缝熔深.通过引入焊缝有效热输入概念,对复合热源影响熔深的机理进行了分析.     

镀金属碳毡在电磁屏蔽材料中的应用

将三维网络结构的碳毡引入电磁屏蔽材料的应用,对其特有的电磁性能及网络结构作了分析,并进行了复合材料屏蔽效果计算和修正。研究表明：利用碳毡的孔洞结构和尺寸,辅之以金属镀层,能在较宽的频率内对电磁波有良好的屏蔽效率,且不需要很大的填充量。     

Ti6Al4V合金微弧氧化陶瓷膜的组织结构研究

采用微弧氧化技术在钛合金表面成功制备出膜厚约100μm的致密陶瓷膜以提高钛合金的耐磨性.SEM结果表明,陶瓷膜完整连续,与基体呈犬牙状牢固结合.XRD衍射结果表明:陶瓷膜主要由金红石型二氧化钛和Al2TiO4晶体相组成.显微硬度结果表明钛合金微弧氧化陶瓷膜的显微硬度为862HV而基体合金硬度仅为412HV,陶瓷膜的硬度远远高于基体合金的显微硬度.摩擦磨损试验表明,镀膜的钛合金磨损量远小于不镀膜钛合金的磨损量,陶瓷膜能提高基体的摩擦磨损性能.     

钛合金阳极化处理技术

通过对钛合金进行阳极化处理,在航空、航天及医疗等领域得到广泛应用.为了达到一定的装饰效果,可进行彩色阳极化.另外钛合金微弧氧化新工艺的开发,提高了耐磨性和防腐性能,进一步扩大了其应用范围.     

镁合金AZ91D在氯化钠溶液中的腐蚀行为

通过容量法、失重法和电化学阻抗谱(EIS)方法研究了镁合金AZ91D铸件及压铸件在5%氯化钠溶液中的腐蚀及电化学腐蚀行为。利用扫描电子显微镜(SEM)、能量色散谱(EDS)和X-射线衍射(XRD)方法研究了腐蚀产物表面形貌及其组成。结果表明:两种合金的腐蚀产物相同,由块状的化合物氢氧化镁[Mg(OH)2]和松枝状的水合氢氧化镁氯化物[Mg2Cl(OH)3.4H2O]组成;镁合金AZ91D压铸件的耐腐蚀性能比镁合金AZ91D铸件好;并通过浸泡过程中电荷转移电阻(Rt)和双电层电容(Y)的变化解释了两种合金的耐腐蚀性能差异。     

小推力高室压NTO/MMH火箭发动机实验系统管路流阻特性实验

为研究小推力高室压NTO/MMH(四氧化二氮/甲基肼)火箭发动机实验系统管路流阻特性,对管路流阻理论、冷流实验及点火实验进行对比分析研究.通过管路介质流动能量损失计算,建立NTO/MMH管路流阻特性理论模型.开展无水乙醇冷流实验及NTO/MMH小推力高室压火箭发动机点火实验,以最小二乘法确定流阻特性实验拟合公式.与冷流实验结果相比,无水乙醇流量分别为0.10~0.40kg/s,0.09~0.36kg/s时,NTO/MMH管路理论流阻平均误差分别为5.42%,3.67%;与点火实验结果相比,真实推进剂流量分别为0.39~0.47kg/s,0.26~0.31kg/s时,NTO/MMH管路理论流阻平均误差分别为2.44%,2.47%,基于冷流实验预测的流阻平均误差分别为5.74%,3.46%,NTO流量为0.47~0.51kg/s(不含0.47kg/s)时,管路理论与冷流实验预测的流阻平均误差分别为16.56%,9.73%.实验与分析结果可应用于小推力高室压NTO/MMH发动机点火实验,并为实验系统设计提供必要支持.      

Effect of sodium tartrate concentrations on morphology and characteristics of anodic oxide film on titanium alloy Ti–10V–2Fe–3Al

The effect of sodium tartrate concentrations on morphology and characteristics of ano-dic oxide film on titanium alloy was investigated. The alloy substrates were anodized in different concentration solutions of sodium tartrate with the addition of PTFE emulsion and their morphol-ogy and characteristics were analyzed. The anodic oxide film presented a uniform petaloid drums and micro-cracks morphology. Additionally, micro-cracks dramatically swelled with the increase of the tartrate concentrations. The thickness of the anodic oxide film increased with the concentra-tions until the concentration reached 15 g/L. The results of Raman analysis illustrate that all sam-ples have similarity in the crystal structure, consisting of mainly amorphous TiO2, some anatase TiO2 and a small amount of rutile TiO2. And the ratios of anatase TiO2 and rutile TiO2 increase with the concentrations until it reaches 15 g/L. Furthermore, the intensity of the peaks increases with enhanced concentrations until the concentration reaches 15 g/L. The corrosion resistance of the anodic oxide film is increased by the sodium tartrate with higher concentrations before 15 g/L. The coefficient of friction of the anodic oxide film reduces with the concentrations until the concentration reaches 15 g/L, then the coefficient of friction of the anodic oxide film increases with the concentrations.     

An equivalent ground thermal test method for single-phase fluid loop space radiator

Thermal vacuum test is widely used for the ground validation of spacecraft thermal control system. However, the conduction and convection can be simulated in normal ground pressure environment completely. By the employment of pumped fluid loops’ thermal control technology on spacecraft, conduction and convection become the main heat transfer behavior between radiator and inside cabin. As long as the heat transfer behavior between radiator and outer space can be equivalently simulated in normal pressure, the thermal vacuum test can be substituted by the normal ground pressure thermal test. In this paper, an equivalent normal pressure thermal test method for the spacecraft single-phase fluid loop radiator is proposed. The heat radiation between radiator and outer space has been equivalently simulated by combination of a group of refrigerators and thermal electrical cooler(TEC) array. By adjusting the heat rejection of each device, the relationship between heat flux and surface temperature of the radiator can be maintained. To verify this method,a validating system has been built up and the experiments have been carried out. The results indicate that the proposed equivalent ground thermal test method can simulate the heat rejection performance of radiator correctly and the temperature error between in-orbit theory value and experiment result of the radiator is less than 0.5 C, except for the equipment startup period. This provides a potential method for the thermal test of space systems especially for extra-large spacecraft which employs single-phase fluid loop radiator as thermal control approach.