含炔基有机硅杂化聚合物的合成及热稳定性

采用双乙炔基封端的硅氮烷单体(双(4-乙炔基苯胺基) 二苯基硅烷,M1) 与含不同二甲基硅基
结构单元[—Si( CH3 )2—,—Si( CH3 )2—O—Si( CH3 )2—和—Si( CH3 )2—O—Si( CH3 )2—O—Si( CH3 )2—] 的
双溴苯基封端单体进行Sonogashira 交叉偶联反应,制备出一系列含炔基有机硅杂化聚合物。通过红外( FTIR)
、核磁氢谱(1H-NMR) 和凝胶渗透色谱( GPC) 对聚合物的结构和分子量进行了表征,并采用热重分析
(TGA)对聚合物的热性能进行了研究。结果表明,二甲基硅基结构的引入显著提高聚合物的溶解性,各组聚
合物均展现出良好的热稳定性能,其中引入—Si(CH3)2—结构的聚合物具有相对最好的热稳定性。     

Prediction of shock-layer ultraviolet radiation for hypersonic vehicles in near space

A systemic and validated model was developed to predict ultraviolet spectra features from the shock layer of near-space hypersonic vehicles in the ‘‘solar blind" band region. Computational procedures were performed with 7-species thermal non-equilibrium fluid mechanics, finite rate chemistry, and radiation calculations. The thermal non-equilibrium flow field was calculated with a two-temperature model by the finite volume technique and verified against the bow-shock ultra-violet(BSUV) flight experiments. The absorption coefficient of the mixture gases was evaluated with a line-by-line method and validated through laboratory shock tube measurements. Using the line of sight(LOS) method, radiation was calculated from three BSUV flights at altitudes of 38,53.5 and 71 km. The investigation focused on the level and structure of ultraviolet spectra radiated from a NO band system in wavelengths of 200–400 nm. Results predicted by the current model show qualitative spatial agreement with the measured data. At a velocity of 3.5 km/s(about Mach11), the peak absolute intensity at an altitude of 38 km is two orders of magnitude higher than that at 53.5 km. Under the same flight conditions, the spectra structures have quite a similar distribution at different viewing angles. The present computational model performs well in the prediction of the ultraviolet spectra emitted from the shock layer and will contribute to the investigation and analysis of radiative features of hypersonic vehicles in near space.     

发动机气瓶热防护产品绝热性能评定研究

通过批抽检热真空试验,能够评定发动机气瓶热防护产品的绝热性能,由于试验设备和试验工艺过程对产品温升会产生巨大影响,依据绝热材料导热系数测试方法,在试验方法不变的条件下,提出新的试验评定要求:稳态过程中产品温升速率。新的产品测试评定要求,能够客观准确的评定产品的隔热性能,排除设备和工艺过程对评定结果的影响。此评定方法也可用于形状不规则、厚度不一致的整件产品绝热性能评定。     

阶跃热流冲击加热半无限体动态热应力分析

考虑超快速加热引起传热过程的非傅立叶效应，建立了第二类边界条件下的半无限体的动态热流场，热应力场方程组。用拉普拉斯变换法对方程组进行求解。结果表明，快速加速在半无限体内产生一个热波和两种热应力波。热波通过之时引起当地温度突然升高。应力波的波前通过之时该处应力突然增加；并对热波和弹性膨胀波波速比率对半无限体动态应力的影响作了研究分析。     

Investigation on the Thermal Conductivity of 3-Dimensional and 4-Directional Braided Composites

It is vital to choose a factual and reasonable micro-structural model of braided composites for improving the calculating precision of thermal property of 3-D braided composites by finite element method (FEM). On the basis of new microstructure model of braided composites proposed recently, the model of FEM calculation for thermal conductivity of 3-dimennsional and 4-directional braided composites is set up in this paper. The curves of coefficient of effective thermal conductivity versus fiber volume ratio and interior braiding angle are obtained. Furthermore, comparing the results of FEM with the available experimental data,the reasonability and veracity of calculation are confirmed at the same time.     

轴对称锻件成形过程的热力耦合有限元分析技术的研究

锻件成形过程中,非稳态、不均匀的温度场对金属的塑性流动有很大的影响，尤其是高温成形过程。本文对轴对称段件成形过程的热力耦合有限元分析技术进行了研究。论述了刚塑性有限元分析方法，建立了热力耦合分析模型，开发了轴对称锻件成形过程的热力耦合有限元分析软件。通过将圆柱体镦粗过程的模拟结果与有关文献中的实验结果和模拟结果的比较，说明了该方法和软件的正确性。     

空间站大面积太阳翼热分析

本文在一定的假设条件下，对空间站大面积太阳翼进行了系统的热流和温度场计算。在计算中利用矢量分析和坐标变换的方法求解出了太阳直接辐射1地球红外辐射和地球反照的辐射角系数，再根据传热学理论建立了瞬态热平衡方程，应用有限单元法对热平衡方程进行了求解。本文通过计算给出了各项热流的大小及在总热流中所占的比例和太阳民办的瞬态温度场分布，对空间站大面积太阳翼设计及热控制具有一定的参考价值。     

MLI碎片防护能力增强措施对隔热性能的影响

从原理上、实验测试和理论建模三个角度分析了MLI碎片防护增强措施对ML I隔热性能的影响。研究表明,在一定范围内增加MLI单元数、添加增强性材料、增加反射屏 之间距离的措施均不会明显改变MLI的隔热性能,真空状态下20单元MLI隔离物的接触率约为 40％。由于增强防护性能的措施会影响到MLI的放气性能,应研究改善增强型MLI的放气性 能的措施,并在反射屏与增强性材料之间及增强性材料之间添加间隔材料。
     

点阵结构空气舵及内部流体热流固耦合研究

开展了钛合金TC4材料激光粉末床熔融(LPBF)工艺研究,在此基础上设计了多孔轻质空气舵模型,并基于有限差分法(FDM),采用三维流固耦合共轭传热数值计算方法,利用流体体积法(VOF)追踪流体自由液面,研究了典型的点阵夹层结构的空气舵内部冷却液动态换热过程的相互影响过程,考虑了冷却液与钛合金材料蒙皮间的耦合传热及湍流换热。结果表明,空气舵的内部流体压强随速度的增加而增加,从而导致流体出口的速度增加。当压强增加到一定程度时,流体的出口以水柱形式喷出。虽然较大的流体速度可以带走较多的热量,但是影响远小于对压强的影响。综合考虑空气舵的服役要求,获得了合适的冷却水入口速度。     

陶瓷隔热瓦的缺陷修补

分别采用了MgO、YSZ和Al₂O₃三种陶瓷粉体和一种含隔热瓦本体成分的粉料对陶瓷隔热瓦缺陷进行修补。研究了修补前后材料的微观形貌、力学及隔热性能。结果表明：采用含隔热瓦本体组成的粉料对陶瓷隔热瓦进行修补,修补部位与本体部位相容性好,且微观形貌相似,仍保持纤维搭接的多孔空间网络结构;修补后试样密度0.24 g/cm³、室温热导率0.044 W/（m·K）、压缩强度0.58 MPa;1 200℃、30 min热处理后,修补部位与本体部位结合性好,未出现裂纹、凹陷等缺陷,是有效的缺陷修补方法。