Mg，RE(La，Ce)的添加对热浸镀55%Al-Zn-1.6%Si涂层耐蚀性影响

采用热浸镀的方法,通过改变Mg,RE的添加量来制备不同成分合金涂层。通过扫描电子显微镜(Scanning electron microscope,SEM)、盐雾实验、腐蚀失重测试来分别研究Mg,RE添加量对55%Al Zn 1.6%Si Mg RE合金涂层耐蚀性的影响;并通过对最佳成分的合金涂层电化学测试和X射线衍射仪(X-ray diffraction,XRD)物相分析,与55%Al-Zn-1.6%Si进行对比,判断其腐蚀机理。实验结果表明：Mg能细化晶粒,强化晶界,1.5%Mg添加量耐蚀性最为优异;RE可以减小熔液表面张力,细化晶粒,提高耐蚀性,0.12%RE添加量较为合适;Mg和RE的加入使涂层中Al发生了择优取向,使涂层中的择优晶面的数量减少,涂层表面电位趋于均匀化,微电池腐蚀的驱动力变小,从而导致了涂层的腐蚀速度降低,在腐蚀溶液中耐蚀能力增强,55%Al-Zn-1.6%Si-1.5%Mg-0.12%RE合金涂层的自腐蚀电位为-0.983 V,自 腐蚀电流密度仅为16.91 μA/cm2。     

耐高温异氰酸酯/ 环氧树脂固化历程与性能

以异氰酸酯为固化剂固化环氧树脂,通过比较不同固化条件下固化物结构的差异,研究了异氰酸酯与环氧树脂的反应历程;改变异氰酸酯/环氧树脂体系的化学计量比(I/E),采用FTIR/ATR、DSC、DMTA等研究了固化产物的结构与性能。结果表明,异氰酸酯与环氧树脂的固化历程随着温度的升高可分为三个阶段,第一阶段为异氰酸酯的三聚反应;第二阶段是一个复杂的过程,首先环氧树脂和异氰酸酯可反应生成嗯唑烷酮结构,通过嗯唑烷酮环扩链得到端畀氰酸酯基低聚物,可继续发生三聚反应;第三阶段为异氰脲酸酯与残余的环氧基团反应生成嗯唑烷酮结构,异氰脲酸酯六元环向噁唑烷酮五元环的转化是一个可逆的过程。不同的I/E比例可得到结构不同的固化物,不同的结构导致固化物性能的差异:当(I/E)=1.8时,综合力学性能良好,异氰酸酯/环氧树脂/玻璃纤维复合材料的弯曲强度、弯曲模量、层剪强度分别为652.53、33270.63和31.66MPa,优于甲基四氢苯酐/环氧树脂/玻璃纤维复合材料力学性能;当I/E=2.0时,固化物T_g达到了305℃,明显优于传统的环氧树脂固化体系。     

Prediction of shock-layer ultraviolet radiation for hypersonic vehicles in near space

A systemic and validated model was developed to predict ultraviolet spectra features from the shock layer of near-space hypersonic vehicles in the ‘‘solar blind" band region. Computational procedures were performed with 7-species thermal non-equilibrium fluid mechanics, finite rate chemistry, and radiation calculations. The thermal non-equilibrium flow field was calculated with a two-temperature model by the finite volume technique and verified against the bow-shock ultra-violet(BSUV) flight experiments. The absorption coefficient of the mixture gases was evaluated with a line-by-line method and validated through laboratory shock tube measurements. Using the line of sight(LOS) method, radiation was calculated from three BSUV flights at altitudes of 38,53.5 and 71 km. The investigation focused on the level and structure of ultraviolet spectra radiated from a NO band system in wavelengths of 200–400 nm. Results predicted by the current model show qualitative spatial agreement with the measured data. At a velocity of 3.5 km/s(about Mach11), the peak absolute intensity at an altitude of 38 km is two orders of magnitude higher than that at 53.5 km. Under the same flight conditions, the spectra structures have quite a similar distribution at different viewing angles. The present computational model performs well in the prediction of the ultraviolet spectra emitted from the shock layer and will contribute to the investigation and analysis of radiative features of hypersonic vehicles in near space.     

WC/C复合涂层海水环境的耐蚀性与摩擦性能

采用非平衡磁控溅射技术在304L不锈钢和单晶硅基底上沉积WC/C多层复合涂层,利用扫描电镜、Raman光谱仪、X射线衍射仪等研究WC/C复合涂层的微观结构,采用纳米压痕仪、划痕测试系统测试涂层的力学性能,利用电化学测试系统和摩擦磨损试验机分别研究涂层在人工配置的海水环境的耐蚀性能和摩擦性能。结果表明:WC/C复合涂层内含有较多类石墨sp2键结构,存在WC1-x相并镶嵌在非晶碳基质中。较之于304L不锈钢基底,WC/C复合涂层在海水环境中表现出更好的耐蚀性与更优异的摩擦适应性。     

ERT/UTT双模态传感器尺寸优化仿真

针对电阻/超声双模态层析成像传感器配置优化问题,提出管道同一截面内配置电极与超声探头,实现对管道内同一被测对象同一时间的检测。采用数值仿真方法,考察电学敏感场与超声敏感场在管道内分布情况,优化双敏感场的互补信息获取范围,获得被测场域内同一被测对象的多敏感信息。为降低被测截面内电极对超声敏感场的影响,定义双敏感场的最优灵敏度与均匀度,利用数值仿真方法对电极与超声探头的安装结构与尺寸进行优化,最终获得16电极与16超声探头间隔放置的最优空间结构与相对尺寸。     

薄膜电阻温度计原理性误差分析及数据处理方法研究

薄膜电阻温度计是高超声速测热试验中一种常用的传感器,多用于激波风洞中.改进薄膜电阻温度计测热数据的后处理方法,分析其原理性误差,提出修正方法,可以进一步提高热流测量精度,为防热设计提供可靠数据.应用三维热传导理论,考虑热流和温升的耦合影响,计算了气动加热条件下薄膜电阻温度计结构温升情况,得到了铂层内的温度分布规律,并与一维半无限简化理论得到的薄膜电阻温度计表层温度相互对比,得到了模型简化带来的原理性误差;建立了由表面温升计算表面热流的导热反问题计算方法,与经典的Cook-Felderman处理公式和热电模拟网络处理方法相互对比,提出了修止热流值的方法,为提高热流测量精度提供了一种可行的手段.     

复合材料抗冲击性能和结构压缩设计许用值

 从复合材料结构压缩设计许用值的概念和复合材料的冲击后压缩强度性能出发,讨论按NASA标准得到的CAI值与它们的关系,指出传统的CAI值不能充分反映复合材料体系的抗冲击性能,且与结构压缩设计许用值无任何联系。在对复合材料结构完整性要求和作者的试验研究,和对国外文献总结的基础上,提出复合材料抗冲击性能应包括损伤阻抗和损伤容限两方面。大量的试验数据证实复合材料层压板抗冲击性能存在拐点现象,在对拐点附近复合材料层压板的破坏机理研究基础上,建议用拐点附近的性能建立复合材料层压板抗冲击性能的评定体系,即可以用表面层在冲击下保持其完整性的最大能力(最大接触力)来表征复合材料体系的损伤阻抗(韧性);用出现拐点后基本不变的压缩强度(破坏应变)门槛值来表征复合材料体系的损伤容限。     

基于双环滑模控制的直/气复合控制系统设计

直/气复合控制导弹具有强干扰、强非线性以及强耦合等特点,传统的姿态控制器难以适用于该种复杂干扰并存的情况,文章提出了基于双环滑模控制的直/气复合控制器。首先采用有限时间收敛趋近律分别构造内外环滑模控制器,并将角速度回路的滑模变量量化为直接力指令,以解决空气舵与姿控发动机之间的耦合问题。接着使用非线性扩张状态观测器估计综合干扰,从而设计控制器补偿侧向喷流干扰及模型不确定性等综合干扰的影响。然后基于李雅普诺夫方法证明了控制系统闭环稳定,分析了干扰补偿对控制器收敛域的影响。最后仿真结果表明,该方法跟踪速度快,动态过程平稳,具有较强的干扰抑制能力,具有很强的鲁棒性。     

Tear Resistance of Orthogonal Kevlar-PWF-reinforced TPU Film

This work seeks to investigate the notch sensitivity and fracture behaviour of orthogonal Kevlar-plain woven fabric (PWF)-reinforced thermoplastic polyurethanes (TPU) film applied to high altitude balloon. Four types of specimens are implemented to measure notched strength and fracture toughness by conducting static tension and tear tests on an MTS system respectively. The damage and failure mechanisms are discussed and the results for notched strength and tear resistance are evaluated and compared with each other. From the experiments, it is found that the notch sensitivity of the film increases with the increase in the size of the hole, but the notch sensitivity and the stress concentration of the notch are insignificant and there is a decrease of only about 4%-10% in tensile strength for the notched specimens with different hole sizes in diameter compared with the unnotched specimen. In contrast, the tear resistance containing a central slit with only 1 mm length is about half of tensile strength of the unnotched film, which implies that the tear resistance exists an significant notch sensitivity. The results of this study provide an insight into notch sensitivity and fracture behaviour of the Kevlar-PWF-reinforced TPU film and constitute a fundamental basis for the design of high altitude balloon.     

碳硼复合渗研究及其应用

本文研究了２０钢和４５钢的碳硼复合渗渗层组织及耐磨性能。结果表明：复合渗可得到较强支撑作用的过渡层,从而使渗硼层耐磨性提高。饲料粉碎机锤片采用复合渗工艺处理后试用效果良好。