高体积分数SiCp/Al激光诱导氧化辅助铣削研究

为了解决高体积分数的SiC_p/Al复合材料在常规切削加工中存在切削力大、刀具磨损快、表面完整性差等问题。本文针对高体积分数SiC_p/Al材料开展激光诱导氧化辅助铣削技术研究，通过激光辐照铣削区域形成易于去除的疏松氧化层提高切削性能，同时开展氧化层调控策略及激光诱导氧化辅助下的铣削参数优化工艺研究，研究不同激光能量密度、辅助气体对氧化层质量的影响及铣削参数优化。结果表明随激光能量密度的增大热影响区宽度和烧蚀沟槽深度随之增加，在氧气辅助下易形成疏松且易于去除氧化层。选取较高的激光能量密度可获得较好的氧化效果，而使用PCD金刚石铣刀，主轴转速为10 000 r/min，在每齿进给量为7.5 μm /s可获得最佳表面质量。     

聚醚砜改性Cf / BMI 复合材料的制备与性能

基于“离位”增韧技术,将“离位”增韧剂聚醚砜(PES)均匀地附载在碳纤维织物上,采用RTM 工 艺制备了Cf / BMI 复合材料(U3160/6421),通过低速冲击、DMA、SEM 和基本力学性能测试分析,研究了PES 对U3160/6421 复合材料性能的影响。结果表明,采用PES 附载的ES-Fabric 织物制备的复合材料具有良好的 增韧效果,其CAI 值提高了85%。由于PES 的加入,在复合材料层间出现了PES 和树脂BMI6421 的相反转结 构,改善了复合材料的损伤阻抗,提高了复合材料的损伤容限,并且“离位”层间增韧对复合材料的力学性能影 响不大。     

超高温抗氧化碳陶复合材料研究进展

综述了国内外近年来陶瓷涂层抗氧化改性C/ C 复合材料和陶瓷基体抗氧化C/ C 复合材料研究

与应用的新进展, 主要包括1 800℃以下、1 800 ~2 200℃和2 200℃以上不同使用温度范围的抗氧化陶瓷涂层

以及SiC 陶瓷和超高温陶瓷基体改性复合材料。指出了目前高超声速飞行器2 200℃以上超高温抗氧化热防

护材料研究中存在的问题,提出了今后研究的方向。

     

前驱体浸渍裂解过程中SiC/SiC复合材料微观工艺应力模拟研究

前驱体浸渍裂解工艺（PIP）是SiC/SiC复合材料的一种近净成形制备方法，但前驱体裂解过程中产生的应力阻碍了该工艺的产业化应用。本文构建了一种化学-力学耦合模型来研究前驱体裂解过程中应力的产生和演化机理。首先以反应动力学模型描述了前驱体的裂解过程；其次基于三相球模型建立了一个解析模型计算基体的均匀化力学性质；最后结合上述模型构建了有限元模型，在微观尺度模拟计算了代表性体积单胞（RVC）内的工艺应力演变。结果表明：基体在贫基体的界面处承受显著的环向拉伸应力；对于由纯前驱体组成的基体，基体内的工艺应力主要是由裂解过程引起的化学收缩导致的，受温度引起的热膨胀影响较小；随着PIP循环次数的增加，化学收缩和热膨胀的角色发生互换。     

熔融渗硅对不同类型C/C复合材料微观结构及性能的影响

选用了三种不同结构的C/C多孔体进行液硅熔渗,采用扫描电镜、X-射线衍射、微纳CT、压汞等方法表征了熔渗前后材料的微观形貌、物相组成及孔隙结构.结果 表明,熔渗后材料显气孔率均小于2％,实现了较好的致密化,C/C多孔体熔渗过程中可以采用高残碳树脂裂解形成的树脂碳或化学气相沉积形成的裂解碳进行保护,熔渗后其弯曲强度分别提...     

碳纤维特性对C/ C 复合材料界面性能的影响

分别采用扫描电镜、比表面积与孔体积分析仪等手段对日丝(RS-Cf ) 和美丝(MS-Cf ) 两种碳纤 维进行表面状态表征分析,通过纤维顶出试验、冲剪强度和弯曲强度对两种纤维制备的C/ C 复合材料界面性 能进行了微观和宏观测试,研究了不同表观结构纤维对C/ C 复合材料界面性能的影响。纤维表面形貌观察结 果表明:圆形RS-Cf 表面沟槽比腰果形MS-Cf 明显,但沟槽数量少于MS-Cf,而MS-Cf 的比表面积、孔体积和 孔径均大于RS-Cf。RS-C/ C、MS-C/ C 复合材料界面强度分别为2. 98 和3. 80 MPa;RS-C/ C 复合材料的弯曲 和冲剪强度分别为55. 9 和32. 0 MPa,低于MS-C/ C 复合材料的65． 0 和35. 2 MPa,微观和宏观力学性能均表 明MS-C/ C 复合材料的界面强度高于RS-C/ C 复合材料。     

Assessment of two quasi-static approaches to mimic repeated impact response and damage behaviour of CFRP laminates

Full impact damage tolerance assessment requires the ability to properly mimic the repeated impact response and damage behaviour of composite materials using quasi-static approximations. To this aim, this paper reports an experimental investigation evaluating two quasi-static methods for mimicking repeated impact response and damage behaviour of Carbon Fibre Reinforced Polymer (CFRP) composite laminates. In this study, an 8.45-J single impact was repeated 225 times and mimicked with 225 times 6.51-J quasi-static (energy equivalent) indentations and with 225 quasi-static (force equivalent) indentations following the recorded impact peak force variation. Results show that the loading rate and the inertial effect are the two major factors affecting the responses of the composite laminates under out-of-plane concentrated loading. Both the energy- and force-equivalent quasi-static indentations failed to reproduce the impact responses greatly associated with high loading rate and inertial effect. The force-equivalent quasi-static indentations were performed in a semi-automatic way and induced damage states more similar to those of the repeated impacts than those of the energy-equivalent quasi-static indentations, whereas the latter can be better automated and has better reproducibility compared to that of the repeated impact responses, as it is less dependent on high loading rate and inertial effect.     

先驱体转化─热压烧结法制备C_f/SiC复合材料

以Y2 O3-Al2 O3和MgO -Al2 O3为烧结助剂体系 ,研究了烧结助剂体系及其含量对Cf/SiC复合材料密度与力学性能的影响。结果表明 ,以Y2 O3-Al2 O3为烧结助剂时 ,复合材料的力学性能优于烧结助剂为MgO -Al2 O3时复合材料的力学性能。当烧结助剂为Y2 O3-Al2 O3时 ,随着烧结助剂含量的增加 ,复合材料力学性能不断提高 ,断裂韧性在烧结助剂含量为 12 %时达到最大值 14.83MPa·m1/ 2 。进一步增加烧结助剂的含量 ,复合材料的抗弯强度虽有提高 ,但断裂韧性急剧降低。烧结助剂含量超过 15%后 ,抗弯强度也急剧降低。结果同时证明 ,复合材料的断裂行为取决于纤维 /基体间的界面结合强度 ,即纤维 /基体间的界面结合情况是决定纤维增强陶瓷基复合材料力学性能的关键因素     

碳纤维表面状态对C/C复合材料性能影响的研究

用两种经高温处理的碳纤维织物,以酚醛树脂作为基体先驱体,制备了二维C／C复合材料。通过扫描电镜（SEM）,X－射线光电子能谱（XPS）研究了两种碳纤维（TCF和JCF）的表面状态,测试了C／C复合材料（TCC和JCC）的层间剪切强度,拉伸性能,SEM观察表明,TCF及JCF表面都有沟槽,但TCF横断面呈腰子形非圆形,XPS分析表明TCF表面含氧官能团数量多,力学测试结果为：TCC层间剪切强度（ILSS）高于JCC,达到16．1MPa;TCC拉伸强度,模量均高于JCC,而JCC断裂延伸率达1．1％,是TCC的3倍,拉伸断口SEM分析表明,TCC断口平整,无纤维拔出,呈脆断,JCC断口有纤维拨出,是纤维控制的多层基体断裂。     

Experimental and numerical investigation of mechanical behavior of plain woven CFRP composites subjected to three-point bending

The mechanical behavior of plain woven Carbon Fiber-Reinforced Polymer (CFRP) composites under Three-Point Bending (TPB) is investigated via experimental and numerical approaches. Multiscale models, including microscale, mesoscale and macroscale models, have been developed to characterize the TPB strength and damages. Thereinto, Representative Volume Elements (RVEs) of the microscale and mesoscale structures are established to determine the effective properties of carbon-fiber yarn and CFRP composites, respectively. Aimed at accurately and efficiently predicting the TPB behavior, an Equivalent Cross-Ply Laminate (ECPL) cell is proposed to simplify the inherent woven architecture, and the effective properties of the subcell are computed using a local homogenization approach. The macroscale model of the TPB specimen is constructed by a topology structure of ECPL cells to predict the mechanical behavior. The TPB experiments have been performed to validate the multiscale models. Both the experimental and numerical results reveal that delamination mainly appears in the top and bottom interfaces of the CFRP laminates. And matrix cracking and delamination are identified as the significant damage modes during the TPB process. Finally, the quasi-static and dynamic behaviors of plain woven composites are discussed by comparing the results of Low-Velocity Impact (LVI) and TPB simulations.