点击化学在三唑固化体系及固体推进剂中的研究进展

综述了基于GAP的三唑交联固化体系、基于惰性聚醚和聚酯的三唑交联固化体系,指出三唑交联固化体系在高能低特征信号固体推进剂中具有良好的应用前景。分析认为,GAP主链上承载原子的质量分数偏低,且侧链上三唑环的刚性结构及其在GAP主链上的随意分布是基于GAP的三唑交联弹性体力学性能不佳的原因。指出开发兼具优异力学性能和较高能量的三唑交联固化体系将是今后努力的方向。     

胶粘剂拉伸剪切强度不合格原因分析

针对X牌号环氧胶粘剂在试验过程中出现拉伸剪切强度不合格的现象,通过大量的试验查找原因,最终确定了影响胶粘剂拉伸剪切强度的因素。同时,提高了对试片的制备、处理、粘接、固化的理论认识和实际操作水平。     

TDE-85环氧树脂固化动力学的DSC和DMA研究

根据DSC和DMA测试曲线,分别用Kissinger、Flynn-Wall-Ozawa、Friedman-Reich-Levi模型计算了TDE-85/THPA环氧树脂体系的固化动力学参数。Kissering法所得活化能较低,其他几种计算方法所得活化能比较一致,相对误差在10%之内。将Gaussian分布应用于分峰法,计算了每个反应的动力学参数,模拟结果与DSC曲线具有很好的一致性。双峰表明,固化过程包含2个化学反应,缩水甘油脂基的反应活性比脂环基高。利用外推法确定了固化工艺为100℃/6 h 130℃/4 h 160℃/2 h。     

辐射换热对平板气膜冷却性能影响

为了分析辐射换热对平板气膜冷却性能的影响,分别对不考虑辐射换热(耦合计算)与考虑辐射换热两种条件下的平板隔热屏进行了三维流热耦合数值模拟研究,并与绝热壁(不考虑隔热屏固壁导热)的计算结果进行了对比。辐射换热采用离散坐标法。得到了3种不同主/次流总温比(Rt)条件下气膜冷却效果、流场、单位面积冷流体热负荷以及流量系数的对比结果与变化规律。结果表明:气膜冷却效果沿流向逐渐降低,且随总温比的增加而降低;在展向上气膜冷却效果呈现中间高两边低的分布规律,最大与最小相对值在绝热壁条件下达到最大,为94.5%,辐射换热次之,为13.5%,不考虑辐射换热时最小,为9.8%。与不考虑辐射换热结果相比,辐射换热对气膜冷却效果的影响在流动方向逐渐变大,气膜孔附近展向温度梯度增大,冷流体热负荷增加了92.8%,二者计算的流量系数相差不大,为1.1%,与绝热壁计算结果相比,流量系数减小了13.1%。随着总温比增加流量系数减小,最大值与最小值相差不大,为1.1%。     

Clouds and Earth Radiant Energy System (CERES), a review: Past,present and future

The Clouds and Earth Radiant Energy System (CERES) project’s objectives are to measure the reflected solar radiance (shortwave) and Earth-emitted (longwave) radiances and from these measurements to compute the shortwave and longwave radiation fluxes at the top of the atmosphere (TOA) and the surface and radiation divergence within the atmosphere. The fluxes at TOA are to be retrieved to an accuracy of 2%. Improved bidirectional reflectance distribution functions (BRDFs) have been developed to compute the fluxes at TOA from the measured radiances with errors reduced from ERBE by a factor of two or more. Instruments aboard the Terra and Aqua spacecraft provide sampling at four local times. In order to further reduce temporal sampling errors, data are used from the geostationary meteorological satellites to account for changes of scenes between observations by the CERES radiometers.     

Trapped proton fluxes measured on board LEO satellites in comparison with models

The proton fluxes from the low-Earth orbital satellites databases (NPOES-17 and CORONAS-F) were analyzed for the quiet geomagnetic period in April 2005. The satisfactory consent was found between the experimental and the AP8 model fluxes of the trapped protons with energy more than ∼10 MeV. At the same time, trapped proton fluxes with energy less than 10 MeV measured by LEO satellites were higher than the ones predicted by the AP8 model in the region of the SAA (drift shell L < 1.5).     

Solar cycle variation of “killer” electrons at geosynchronous orbit and electron flux correlation with the solar wind parameters and ULF waves intensity

To construct models for hazard prediction from radiation belt particles to satellite electronics, one should know temporal behavior of the particle fluxes. We analyzed 11-year variation in relativistic electron flux (E>2 MeV) at geosynchronous orbit using measurements made by GOES satellites during the 23rd sunspot cycle. As it is believed that electron flux enhancements are connected with the high-speed solar wind streams and ULF or/and VLF activity in the magnetosphere, we studied also solar cycle changes in rank order cross-correlation of the outer radiation belt electron flux with the solar wind speed and both interplanetary and on-ground wave intensity. Data from magnetometers and plasma sensors onboard the spacecraft ACE and WIND, as well as magnetic measurements at two mid-latitude diametrically opposite INTERMAGNET observatories were used. Results obtained show that average value of relativistic electron flux at the decay and minimum phases of solar activity is one order higher than the flux during maximum sunspot activity. Of all solar wind parameters, only solar wind speed variation has significant correlation with changes in relativistic electron flux, taking the lead over the latter by 2 days. Variations in ULF amplitude advance changes in electron flux by 3 days. Results of the above study may be of interest for model makers developing forecast algorithms.     

On the electrodynamics of counter stream in pulsar’s inner annular cap region

The electric properties of pulsar’s inner annular gap are explored in this paper. Under two main assumptions, (1) the pulsar is alive, (2) the total charge of pulsar should not vary with time, the condition for the acceleration of negative particle in the annular region is derived. The acceleration condition is j₋ ? 0.5j₊, i.e., the current carried by negative particles is greater than or equal to 0.5 times of the current carried by positive particles. This condition holds even when the backward flow of positive particles exists in the annular region. It is noted that the outflow of negative particles offers good opportunities to understand the current closure problem of pulsar as well as wide radiation beam of pulsar observed at high energy band.     

新型环氧树脂潜伏性促进剂的合成、表征及性能研究

合成了新型环氧树脂潜伏性促进剂三(乙酰乙酸十八酯)铝,采用DSC,FT-IR,H-NMR、元素分析分别对其热分解机理、化学结构、物质纯度进行了表征.研究了以环氧ZH92-21∶双酚S∶三(乙酰乙酸十八酯)铝=l00∶3∶0.5为配比的树脂体系的固化制度、潜伏性和力学性能,树脂体系的表观粘度在室温储藏7个月后基本没有变化,相分离是其具有优异潜伏性的主要原因.     

New evidence for strong non-thermal effects in Tycho’s supernova remnant

For the case of Tycho’s supernova remnant (SNR), we present the relation between the blast wave and contact discontinuity radii calculated within the nonlinear kinetic theory of cosmic ray (CR) acceleration in SNRs. It is demonstrated that these radii are confirmed by recently published Chandra measurements which show that the observed contact discontinuity radius is very close to the shock radius. Therefore a consistent explanation of these observations can be given in terms of efficient CR acceleration which makes the medium more compressible.