Influences of pulse frequency on formation and properties of composite anodic oxide films on Ti-10V-2Fe-3Al alloy

A thick composite anodic oxide film was fabricated in an environmentally friendly malic acid electrolyte containing PolyTetraFluoroEthylene (PTFE) nanoparticles on Ti-10V-2Fe-3Al alloys. The influence of pulse frequency on the morphology, microstructure and composition of composite anodic oxide films containing PTFE nanoparticles was investigated using Field Emission Scanning Electron Microscopy (FE-SEM) equipped with Energy Dispersive Spectroscopy (EDS), Atomic Force Microscopy (AFM) and Raman spectroscopy. The tribological properties in terms of the friction coefficient, wear loss and morphology of worn surfaces were measured by ball-on-disc tests. The electrochemical property was evaluated by potentiodynamic polarization. The results indicated that the titanium dioxide of composite anodic oxide films transformed from anatase to rutile with the change of pulse frequency, which could result from the electrochemical dynamic equilibrium. The combination of PTFE nanoparticles and malic acid electrolyte molecules can influence the energy fluctuation of electrochemical equilibrium and formation of composite anodic oxide films. Moreover, composite anodic oxide films fabricated under the condition of 1.0–2.0 Hz exhibited the best wear resistance and corrosion property. The schematic diagram of the film formation and PTFE nanoparticles spreading process under different frequencies was elucidated.     

电磁搅拌对铸锭凝固组织的影响

疏松和偏析是铝合金铸锭中的常见缺陷，它们的存在严重影响了产品的使用性能与使用寿命。获得致密、均匀的凝固组织是提高金属材料综合机械性能的重要途径，旋转型电磁搅拌在钢的连铸工艺中已得到广泛应用，研究了旋转型电磁搅拌对铝合金铸锭凝固组织的影响。研究结果表明：在凝固过程中施加电磁搅拌，能明显细化晶粒，增加铸锭断面上的等轴晶区宽度，减轻疏松，抑制铝合金铸锭中铜的逆偏析。     

TC21-0.28%H钛合金微观组织及其高温变形行为研究

利用光学金相及X射线衍射,研究了TC21-0.28%H(质量分数,下同)钛合金的组织结构,通过热模拟压缩实验,研究了TC21-0.28%H钛合金在800～920℃温度范围和0.01～1s-1应变速率范围的高温变形行为,建立了钛合金高温变形本构方程。结果显示,与TC21钛合金相比,TC21-0.28%H钛合金β相比例显著增加,并且有新相马氏体α″与氢化物δ生成,TC21-0.28%H钛合金在α+β相区与β相区的变形激活能分别为233kJ/mol与153kJ/mol,软化机制为动态回复,与TC21钛合金相比,TC21-0.28%H钛合金变形激活能降低,热加工性能得到改善。     

固溶时效对热等静压制备的TC4钛合金性能的影响

采用热等静压工艺对Ti一6A1—4V(简称TC4)雾化预合金粉的粉末冶金技术进行了研究,采用不同的固溶温度、时效温度以及时效时间,研究了热处理工艺对TC4钛合金组织和性能的影响。结果表明,采用预合金粉工艺制备的Ti一6A1—4V粉末钛合金材料力学性能良好,于965℃固溶并采用水冷,然后在470℃时效,试样具有优良的力学性能,适宜冷加工生产。     

利用计算机串口实现PPT传感器的网络测量

介绍了PPT传感器的使用方法。给出了利用计算机的RS232和RS485串口进行PPT传感器网络测量的方法。     

Effects of Nb Content on Yield Strength of NiTiNb Alloys in Martensite State

Two near single-phase NiTiNb alloys—Ni₅₀Ti₄₈Nb₂ and Ni_49.5Ti_46.5Nb₄—are prepared and studied by means of scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), differential scanning calorimetry (DSC) and tensile tests in order to unearth the effects of Nb-atom solid solution in NiTi phase on the yield strength induced by self-accommodation of martensite variants. The results show that the yield strength of near single-phase NiTiNb alloys varies inversely with the amount of Nb-atoms solid-dissolved in NiTi phase. From the results out of the prior and current studies, it can be surmised that the effects of Nb content on the yield strength of NiTiNb alloys in martensite state depend on the coaction. Nb solid solution weakening mechanism and β-Nb phase composite strengthening mechanism. This inference might be a satisfactory explanation to the fact that the yield strength of (NiTi)_50–0.5xNb_x alloys in martensite state begins with decline and then rises when the Nb content increases.     

某型起动机高温合金整体涡轮材料的改进与分析

针对某型起动机高温合金整体涡轮断裂故障率高的情况,本文从国内外涡轮材料的发展趋势和应用现状出发,介绍了一种新型涡轮材料,并通过对比新旧材料的性能证明了材料改进的可行性和有效性。     

Electrochemical behavior of Ti-6.5Al-2Zr-1Mo-1V alloy under rotating condition with periodically fluctuating current density

Titanium alloy plays a crucial role in the electrochemical field due to its excellent corrosion resistance. The passivation and dissolution behaviors of Ti-6.5Al-2Zr-1Mo-1V（TA15） alloy in Na Cl solution were studied by simulating the electrochemical machining process in a rotating condition, which made the anode in a state with alternating high and low current density. Electron probe micro analysis, ultra-depth microscope, scanning electron microscope, and X-ray photoelectron spectrometer were u...     

BT20钛合金激光焊技术研究

针对2.5 mm厚BT20钛合金进行了CO2激光焊和YAG激光焊研究,结果表明由于激光特性不同,形成的焊缝几何特征不同,当焊接工艺适当,可保证焊接过程的稳定性和焊接接头的质量.在激光自熔焊时主要的焊缝缺陷是咬边,这是由于钛合金物理性能和激光高能束流焊特性所致.这种咬边缺陷不利于焊接接头性能,尤其是接头的疲劳性能和断裂韧性.采用活性剂和填丝焊,以及激光旋扫焊可以改善焊缝咬边缺陷,提高钛合金激光焊接头的力学性能.     

GH4169合金直接时效锻造过程的数值模拟

直接时效（DA）锻造工艺已成为生产GH4169合金涡轮盘锻件的基本方法之一。但实施DA锻造工艺时,锻造过程的各个环节要求严格控制,而且要有足够吨位的设备。参照在压力机上实施DA工艺的终锻过程,用有限元变形-传热耦合分析方法对直径520mm和高度190mm的GH4169合金坯料在不同情况下的镦粗过程进行了数值模拟。大量计算结果表明,在压力机上实施DA锻造工艺时,为了获得优质GH4169合金涡轮盘锻件,应合理确定压力机滑块速度,尽可能改善润滑情况及适当提高模具预热温度。对于GH4169合金涡轮盘锻件,采用等温DA锻造工艺可能是最佳的选择。研究结果对于在国内的生产条件下实施GH4169合金DA锻造工艺具有指导作用。