锂离子电池单离子导体聚合物电解质研究进展

锂离子电池在3C电子产品和动力汽车电池行业广泛应用,在航天电源领域也展现出一定的前景。单离子导体是基本仅由参与电化学反应的锂离子迁移的电解质体系,解决传统锂离子电池液态电解质存在的副反应和阴离子的浓差极化等问题,改善电池的库伦效率和循环寿命。研究者们发展了多种类型的单离子导体电解质。本文总结了近5年来不同阴离子类型的单离子导体聚合物电解质合成策略以及分子动力学模拟计算的最新进展。     

四极－十六极分区式线型阱中汞离子囚禁仿真研究

利用SIMION软件建立了四极-十六极分区式线型离子阱系统模型，在此基础上仿真模拟了汞离子在四极阱和十六极阱中被囚禁时的第一稳定区，并分析了离子在不同阱中的运动特性。研究了汞离子云在分区式阱中的囚禁体积和速度分布，以及在不同囚禁区域之间的穿梭过程。模拟得出了稳态情况下分区式阱中不同囚禁区域的粒子数密度分布，验证了分区式离子阱中离子云被连续囚禁、穿梭时粒子数衰减和补偿。同时，根据以上数据分析讨论了汞离子囚禁时的多普勒效应，估算了基于此分区式离子阱的汞离子微波钟的性能水平。     

Characterization of the low latitude plasma density irregularities observed using C/NOFS and SCINDA data

Complex electrodynamic processes over the low latitude region often result in post sunset plasma density irregularities which degrade satellite communication and navigation. In order to forecast the density irregularities, their occurrence time, duration and location need to be quantified. Data from the Communication/Navigation Outage Forecasting System (C/NOFS) satellite was used to characterize the low latitude ion density irregularities from 2011 to 2013. This was supported by ground based data from the SCIntillation Network Decision Aid (SCINDA) receivers at Makerere (Geographic coordinate 32.6°E, 0.3°N, and dip latitude ?9.3°N) and Nairobi (Geographic coordinate 36.8°E, ?1.3°N, and dip latitude ?10.8°N). The results show that irregularities in ion density have a daily pattern with peaks from 20:00 to 24:00 Local Time (LT). Scintillation activity at L band and VHF over East Africa peaked in 2011 and 2012 from 20:00 to 24:00 LT, though in many cases scintillation at VHF persisted longer than that at L band. A longitudinal pattern in ion density irregularity occurrence was observed with peaks over 135–180°E and 270–300°E. The likelihood of ion density irregularity occurrence decreased with increasing altitude. Analysis of C/NOFS zonal ion drift velocities showed that the largest nighttime and daytime drifts were in 270–300°E and 300–330°E longitude regions respectively. Zonal irregularity drift velocities over East Africa were for the first time estimated from L-band scintillation indices. The results show that the velocity of plasma density irregularities in 2011 and 2012 varied daily, and hourly in the range of 50–150 m s^?1. The zonal drift velocity estimates from the L-band scintillation indices had good positive correlation with the zonal drift velocities derived from VHF receivers by the spaced receiver technique.     

Effects of adiabaticity and non-adiabaticity of dust charge fluctuation on the propagation of the dust ion acoustic waves in inhomogeneous dusty plasma

A theoretical investigation has been made for adiabatic positive and negative dust charge fluctuations on the propagation of dust-ion acoustic waves (DIAWs) in a weakly inhomogeneous, collisionless, unmagnetized dusty plasmas consisting of cold positive ions, stationary positively and negatively charged dust particles and isothermal electrons. The reductive perturbation method is employed to reduce the basic set of fluid equations to the variable coefficients Korteweg–de Vries (KdV) equation. Either compressive or rarefactive solitons are shown to exist depending on the critical value of the ion density, which in turn, depends on the inhomogeneous distribution of the ion. The dissipative effects of non-adiabatic dust charge variation has been studied which cause generation of dust ion acoustic shock waves governed by KdV-Burger (KdVB) equation. The results of the present investigation may be applicable to some dusty plasma environments, such as dusty plasma existing in polar mesosphere region.     

Cassini Plasma Spectrometer Investigation

The Cassini Plasma Spectrometer (CAPS) will make comprehensive three-dimensional mass-resolved measurements of the full variety of plasma phenomena found in Saturn’s magnetosphere. Our fundamental scientific goals are to understand the nature of saturnian plasmas primarily their sources of ionization, and the means by which they are accelerated, transported, and lost. In so doing the CAPS investigation will contribute to understanding Saturn’s magnetosphere and its complex interactions with Titan, the icy satellites and rings, Saturn’s ionosphere and aurora, and the solar wind. Our design approach meets these goals by emphasizing two complementary types of measurements: high-time resolution velocity distributions of electrons and all major ion species; and lower-time resolution, high-mass resolution spectra of all ion species. The CAPS instrument is made up of three sensors: the Electron Spectrometer (ELS), the Ion Beam Spectrometer (IBS), and the Ion Mass Spectrometer (IMS). The ELS measures the velocity distribution of electrons from 0.6 eV to 28,250 keV, a range that permits coverage of thermal electrons found at Titan and near the ring plane as well as more energetic trapped electrons and auroral particles. The IBS measures ion velocity distributions with very high angular and energy resolution from 1 eV to 49,800 keV. It is specially designed to measure sharply defined ion beams expected in the solar wind at 9.5 AU, highly directional rammed ion fluxes encountered in Titan’s ionosphere, and anticipated field-aligned auroral fluxes. The IMS is designed to measure the composition of hot, diffuse magnetospheric plasmas and low-concentration ion species 1 eV to 50,280 eV with an atomic resolution M/ΔM ∼70 and, for certain molecules, (such asN ₂ ⁺ and CO⁺), effective resolution as high as ∼2500. The three sensors are mounted on a motor-driven actuator that rotates the entire instrument over approximately one-half of the sky every 3 min.This revised version was published online in July 2005 with a corrected cover date.     

马尔科夫尼可夫规则机理的讨论

不对称烯烃与不对称试剂进行亲电加成反应时,遵守马尔科夫尼可夫规则,本文从生成碳正离子和环状高价正离子的两种反应途径对其反应机理加以讨论,并指出决定两种途径的主要因素.     

IMF Direction Derived from Cycloid-Like Ion Distributions Observed by Mars Express

Although the Mars Express (MEX) does not carry a magnetometer, it is in principle possible to derive the interplanetary magnetic field (IMF) orientation from the three dimensional velocity distribution of pick-up ions measured by the Ion Mass Analyser (IMA) on board MEX because pick-up ions' orbits, in velocity phase space, are expected to gyrate around the IMF when the IMF is relatively uniform on a scale larger than the proton gyroradius. During bow shock outbound crossings, MEX often observed cycloid distributions (two dimensional partial ring distributions in velocity phase space) of protons in a narrow channel of the IMA detector (only one azimuth for many polar angles). We show two such examples. Three different methods are used to derive the IMF orientation from the observed cycloid distributions. One method is intuitive (intuitive method), while the others derive the minimum variance direction of the velocity vectors for the observed ring ions. These velocity vectors are selected either manually (manual method) or automatically using simple filters (automatic method). While the intuitive method and the manual method provide similar IMF orientations by which the observed cycloid distribution is well arranged into a partial circle (representing gyration) and constant parallel velocity, the automatic method failed to arrange the data to the degree of the manual method, yielding about a 30° offset in the estimated IMF direction. The uncertainty of the derived IMF orientation is strongly affected by the instrument resolution. The source population for these ring distributions is most likely newly ionized hydrogen atoms, which are picked up by the solar wind.     

Coupling plasma plume of a low-power magnetically shielded Hall thruster with a hollow cathode

The coupling region of a Hall thruster with a hollow cathode is the region between the cathode and the thruster plume. The characteristics of plasma in that region are complicated and strongly associated with the thruster working conditions and the cathode position. In this paper, a laboratory 100 W class magnetically shielded Hall thruster was coupled with a hollow cathode. Optical imaging and electrostatic probe were employed to monitor and scan the plasma plume. Plume characteristics in the coupling region in non-self-sustained mode and self-sustained mode were compared. Evolution of the coupling plume with the cathode position was studied. Experiments show that, when turning the thruster into self-sustained mode or moving the cathode further away axially, the discharge current can be reduced by 6.4–10.6% restraining the electron current and improving ionization. In particular, when the cathode is moved further, the electron conduction near the channel walls is suppressed. The electron current is reduced by 27.4% and the ion beam current is increased by 7%. Overall, this work shows that the working mode of the thruster and the position of the cathode greatly affect the coupling plasma plume. Both play an important role in improving the utilizations of propellant and current.     

阳极层霍尔推力器内轮辐效应不稳定性研究

为研究圆柱形阳极层霍尔推力器内轮辐效应的不稳定性,利用高速相机和静电探针得到1-2-1模式、1-2-3-1模式和1-2-3-2-1模式的轮辐分裂与合并现象。随着磁感应强度由205Gs增加到225Gs,轮辐个数m由1增加到3。轮辐的分裂与合并模式增多,且轮辐的旋转频率随之由25kHz提高到40kHz～50kHz。轮辐效应的存在是电子密度分布函数的宏观体现,动理论方程中力F的波动引起了轮辐的分裂,随着轮辐个数m的增加,电子分布的低频大幅度波动逐渐演变为小幅度高频率的波动。电子密度分布函数的波动引起的轮辐效应产生了角向分布的电场强度与磁场共同作用,增强了电子轴向漂移运动。     

毛细管放电型脉冲等离子体推力器输出特性分析

为了研究毛细管放电型脉冲等离子体推力器输出特性,借助电学诊断手段展开实验研究,获得了推力器典型放电波形,系统研究了不同毛细管内径和施加电压对等离子体等效阻抗、沉积能量效率的影响规律。利用微冲量测量台架,测试了不同参数下毛细管推力器输出元冲量,并通过计算获得了推力器比冲、总体效率的变化规律。实验结果表明,当毛细管内径不断增大时,能量沉积效率不断下降,元冲量下降,比冲降低。主电容电压增大时,放电能量不断增大,能量沉积效率降低,元冲量和单次等效烧蚀质量不断增大,但推力器比冲和总体效率均先增加并趋于稳定。当毛细管腔体长度为16mm,内径3mm,主电容2.5μF,充电电压为2kV时,输出元冲量350.79±7.50μN?s,比冲531s,总体效率可达18.3%。