环氧类外防热涂料延伸率的提高

为解决RT-Ⅲ环氧类外防热涂料在某产品上出现的裂纹、开裂、脱落等问题,将端羟基聚丁二烯黏合剂(HTPB)环氧化,并将其加入到RT-Ⅲ环氧类外防热涂料中,提高涂料的延伸率.增韧后涂料RT-Ⅳ的延伸率大幅提高,工艺性能有所改善,隔热性能等与增韧前的RT-Ⅲ环氧类外防热涂料基本相当,界面性能适当降低,并通过了飞行试验验证.通过提高RT-Ⅲ环氧类外防热涂料延伸率技术研究,发现在环氧类外防热涂料中适当加入环氧化的端羟基聚丁二烯黏合剂(EHTPB),可以达到提高涂料延伸率的目的.     

固体火箭发动机用新型涂料热防护设计和试验研究

介绍了某联合动力装置中的共底和环形点火器首次采用新研制的３５００Ｋ高温涂料进行热防护的配方设计、受热计算、涂层制备和试验考核。由环氧改性有机硅树脂基料、专用树脂固体体系和多种形状的硅酸盐填料制成的涂层具有优异的耐高温、隔热和抗烧蚀性能，还能常温固化成形，成功地解决了中型固体火箭发动机中大尺寸、薄壁、复杂型面零件的热防护和过烧蚀难题，有效地提高了发动机的工作可靠性。     

TC4钛合金与多层TiN/Ti涂层的砂尘冲蚀损伤试验

建了砂尘冲蚀试验系统,采用粒子成像测速方法获得了气体压力和砂尘速度之间的关系,并在砂尘质量浓度为28.91g/m3,速度为80m/s,冲蚀角度为30°的条件下,对TC4钛合金和多层TiN/Ti涂层进行了冲蚀试验.结果表明:TC4钛合金抗冲蚀损伤能力较差,平均质量损失率达0.7mg/min.多层TiN/Ti涂层可承受砂尘冲蚀200min以上,且TiN/Ti调制比为1:3涂层的抗冲蚀能力优于调制比为1:1的涂层.砂尘粒子垂直冲击速度分量引起的微区剥落是涂层冲蚀损伤的主要原因,增加多层涂层韧性是提高其抗冲蚀性能的关键.      

某型涡扇发动机防钛火阻燃涂层技术研究

针对某型涡扇发动机高压压气机存在的钛火风险,研究了采用电弧喷涂技术对该型发动机高压压气机1~3级工作环与整流器内表面喷涂阻燃涂层的方法,以提高发动机的使用可靠性。     

新型封严涂层高温高速磨耗试验机的研制

为模拟航空涡轮发动机气路封严配副在工作状态下的磨损磨耗现象,研究封严涂层的可磨耗性能,研制了1套新型的可磨耗性能评价试验器。该试验器采用叶片-涂层刮削式磨耗副,使用模拟轮盘带动叶片高速旋转实现叶尖的切线速度;采用封严涂层试样径向进给以模拟叶片刮削切入;使用压电石英晶体3向测力仪定量测量瞬态刮削力;采用高速高温火焰加热试样。考核结果表明:试验器能够完成叶尖切线速度为0~300 m/s、进给速率为1.5~2025μm/s、加热温度为20~800℃条件下的磨耗试验,试验效果良好,数据稳定可靠。     

CrON扩散阻挡层对NbCrAl涂层与Nb基高温合金元素互扩散的影响

利用磁控溅射技术在C103型Nb基高温合金上制备了含和不含CrON扩散阻挡层的NbCrAl涂层,对比研究了2种涂层分别经900℃和1000℃真空热处理后的元素扩散行为。结果表明:NbCrAl涂层以Cr₂Nb和AlNb₂相为主,含非晶态组织;真空热处理后生成了NbAl₃和(Nb,Cr)沉淀相。热处理温度由900℃升至1000℃时,NbCrAl涂层中元素扩散速度加快。不含扩散阻挡层样品中Cr和Al元素扩散至基体的含量分别为2.76wt%和1.21wt%,而含扩散阻挡层样品中Cr和Al元素扩散到基体的含量分别仅为2.52wt%和0.84wt%。扩散阻挡层保持连续,且与涂层及基体的界面结合良好,经高温处理后主要以密排六方结构的Cr₂O₃和Al₂O₃相为主,有效地抑制了元素互扩散。     

红外热成像技术在功能涂层缺陷研究中的应用

介绍了一种基于红外热成像技术的无损检测方法,用于检测涂层的内部缺陷。该方法是以高能闪光灯作为热激励装置,并通过红外热像仪记录样品的热扩散和冷却过程。使用这种方法成功地检测了两组带有人工缺陷的功能涂层样品。实验结果表明,在红外热图像上能够明显地识别出涂层内部缺陷的位置和尺寸。     

FeAlCrBSiNb非晶涂层形成机理和摩擦磨损行为

研发了一种FeAlCrBSiNb粉芯丝材,采用高速电弧喷涂技术在45钢基体上制备相应涂层.通过SEM,TEM和XRD表征涂层微观组织和相成分,阐述FeAlCrBSiNb非晶涂层的形成机理,利用显微硬度计,万能拉伸试验机和环-块式摩擦磨损试验机,分析涂层力学性能和摩擦磨损行为.结果表明:涂层主要由非晶相和弥散分布其中的α-(Fe),(Fe,Cr),CrB和Fe3Al微晶纳米晶相组成,非晶相体积含量大于91.3％;涂层呈层状结构,结构致密,总体孔隙率约为2％;平均显微硬度值为850 HV0.1,是基体45钢的4倍;优良的磨损抗力使其相对耐磨性是45钢的5倍,其磨损机制主要为剥落引起的剥落磨损.     

Investigation on a Sol-gel Coating Containing Inhibitors on 2024-T3 Aluminum Alloy

For a long time, chromate incorporated conversion coatings have been drawn special attention in corrosion protection of air-craft-used aluminum alloys. However,ever-increasing environmental pressures requires that non-chromate conversion coatings be developed because of the detrimental carcinogenic effects of the chromate compounds. In recent years, the sol-gel coatings doped with inhibitors were developed to replace chromate conversion coatings, and showed real promise. A sol-gel coating was prepared and its anti-corrosion behavior was investigated using the potentiodynamic scanning (PDS) and the electrochemical impedance spectroscopy (EIS). It is found that the sol-gel coating obtained by the hydrolysis and condensation of 3-glycidoxypropyltrimethoxysilane (GPTMS) and tetramethoxysilane (TMOS) is prone to form defects if cured at the room temperature, whereas if cured at a higher temperature (100 ℃), these flaws can be avoided. Furthermore, it can be seen that addition of anti-foam agents and surfactants will reduce the faults if cured at the room temperature. Effects of the corrosion inhibitors, CeCl3 and mercaptobenzothiazole (MBT), in the sol-gel coatings on 2024-T3 aluminum alloy were also investigated. Results show that the corrosion resistance of the sol-gel coatings containing CeCl3 proves to be better than that of the pure and MBT added sol-gel coatings by the electrochemical methods.     

Electrolytic Passivation of Nitinol Shape Memory Alloy in Different Electrolytes

The corrosion behavior of the nitinol alloy was studied in various corrosion media of different Cl^- ion concentrations. The results demonstrate that the Cl^- ion concentration has significant influences on the corrosion behavior of the nitinol alloy. In order to enhance the corrosion resistance, protective films were generated on the surface of the nitinol alloy by means of the electrochemical passivation method, for which five different electrolytic solutions were investigated. The surface analysis indicates full growth of all samples passivated in the different electrolytic solutions with layers, however, showing different morphological features. Without any defects like micro-cracks and pores, the surface of the samples passivated in the molybdate solution turns out smoother and denser than those passivated in other solutions. It is shown that the electro-chemical passivation will reduce Ni content but increase Ti content in the surface, reaching the Mole ratio of Ti：Ni = 9.01：1 on the outermost surface. Potentiodynamic polarization test demonstrates that the samples electrochemically passivated in the molybdate solution present a significant increase in breakdown potential due to titanium enrichment on the outermost surface.