Electrolytic Passivation of Nitinol Shape Memory Alloy in Different Electrolytes

The corrosion behavior of the nitinol alloy was studied in various corrosion media of different Cl–ion concentrations. The results demonstrate that the Cl–ion concentration has significant influences on the corrosion behavior of the nitinol alloy. In order to enhance the corrosion resistance, protective films were generated on the surface of the nitinol alloy by means of the electrochemical passivation method, for which five different electrolytic solutions were investigated. The surface analysis indicates full growth of all samples pas-sivated in the different electrolytic solutions with layers, however, showing different morphological features. Without any defects like micro-cracks and pores, the surface of the samples passivated in the molybdate solution turns out smoother and denser than those pas-sivated in other solutions. It is shown that the electro-chemical passivation will reduce Ni content but increase Ti content in the surface, reaching the Mole ratio of Ti:Ni=9.01:1 on the outermost surface. Potentiodynamic polarization test demonstrates that the samples electrochemically passivated in the molybdate solution present a significant increase in breakdown potential due to titanium enrichment on the outermost surface.     

Deformation Behavior of Mg-8 wt%Li Alloy under High-speed Impact

Deformation behavior of the Mg-8 wt%Li alloy at high strain rate was studied by means of the Split Hopkinson Pressure Bar (with strain rate of 103 s-1). It is found that shear localization proves to be the main damage mode for the alloy during dynamic loading. Strain and strain rate are the two necessary parameters affecting the occurrence of deformation and shear bands. Deformation bands begin to form when the strain and strain rate reach 0.20 and 1 900 s-1 respectively and will develop gradually with the strain rate increasing. Be-sides, deformation bands will transform into shear bands when the strain and strain rate reach above 0.25 and 3 500 s-1 separately.     

热变形对高铌TiAl合金微观组织的影响

通过对Ti-45Al-8.0Nb-0.2W-0.2B-0.1Y(原子百分数)合金的热压缩分析发现,其变形温度和变形速率对合金的真实应力-应变曲线以及变形后的组织有显著的影响。在低的变形温度和高的变形速率下,随应变量的增加合金呈现明显的软化现象,变形后存在大量的流线型组织,当变形温度达到1250℃、变形速率降到1×10^-3s^-1时,合金变形后的组织逐渐得到充分的再结晶,铸态组织得到明显的细化。     

中国航空发动机涡轮叶片用材料力学性能状况分析

简述了国内外航空发动机涡轮叶片用材料的发展,对中国航空发动机涡轮叶片用材料中的变形高温合金和铸造高温合金的拉伸、持久、疲劳性能进行了比较,分析了目前中国航空发动机涡轮叶片用材料性能数据十分缺乏的现状。     

高深径比TC4钛合金筒形件普旋成型有限元数值模拟

采用有限元法对特定高深径比TC4钛合金筒形件普旋成型进行了数值模拟,分析了运动轨迹、旋压道次间距和间隙对成型的影响.结果表明普旋时坯料不同部位的应力应变状态不同,采用凹曲线轨迹,间隙为3.5 mm,首道次间距为9 mm,分6道次旋压成型效果好.同时在有限元数值模拟基础上,成功旋制了高精度试验件,说明有限元模拟对旋压具有很好指导意义.     

钛合金焊接件疲劳寿命估算

基于有限单元法理论，采用ANSYS有限元分析软件，对航空发动机中常用钛合金焊接试件进行应力应变分析，得到了焊接接头的等效应力场和应变场，并确定出试件等效应力集中系数Kf，运用局部应力-应变法对光滑焊接试件估算疲劳寿命，并采用成组试验法对计算结果进行验证和分析。     

铝合金与橡胶抗老化涂层接触腐蚀的影响因素研究

通过正交试验,研究了环境温度、相对湿度、时间、接触方式等因素对7A04-T6包铝及去包铝合金与橡胶抗老化涂层接触腐蚀的影响。研究结果显示:环境温度、相对湿度、铝合金与橡胶抗老化涂层接触的紧密程度都是铝合金腐蚀的显著影响因子;在高温、高湿的环境中,与橡胶抗老化涂层紧密接触会加剧铝合金腐蚀。     

Ti-6Al-4V电子束焊接焊缝区域精细组织特征

采用OM,XRD,EPMA,TEM分析了电子束焊接Ti-6Al-4V焊缝区域的精细组织结构特征。结果表明接头区域组织形态由基体等轴晶向焊缝柱状形态演化,焊缝区域呈现单一α′网篮状组织,TEM板束形态呈多向分布,焊缝区域的位错分布密度与基体母材相比呈现出减小的趋势,且熔合线附近存在V,Fe等β稳定元素浓度起伏现象。     

热处理对二次锻造高Nb-TiAl基合金组织的影响

研究了热处理对二次锻造高Nb-TiAl基合金组织的影响。通过对Ti-45Al-9(Nb,W,B,Y)金属间化合物进行不同的热处理,得到不同的显微组织。结果表明,经1310℃/20min+1250℃/2h/AC热处理后,β相被有效地消除,得到细小均匀的双态组织。此后直接加热到α单相区,得到条带状的全片层组织。增加在两相区的停留,得到相对比较均匀细小的全片层组织。将锻造组织先转变为近γ组织再进行全片层组织处理,得到最均匀细小的全片层组织。     

超塑变形对TC4 室温力学性能的影响

在T=880℃和ε=9.8 ×10-4 s-1下,进行了TC4圆筒件超塑成形试验,研究了超塑变形量对TC4室温强度、疲劳性能和金相组织的影响.结果表明:随着变形量的增加,晶粒尺寸增大.当超塑胀形延伸率e为55％时,晶粒尺寸由供应态的约8μm增加为约20 μm.随着e增加,TC4室温下的屈服强度、抗拉强度和条件疲劳强度降低.当e为55％时,材料的屈服强度、抗拉强度下降约7％;循环周期为106下的疲劳强度下降约10％.