换热器镀层工艺研究

通过理论分析和工艺试验等方式,探索了由性能差异较大的不同材料组成的换热器选择性电镀工艺方法.采用局部遮蔽、浸蚀溶液的选择、预镀工艺的确定等方式,保证了组合件上各型面、各材料上的镀层质量,换热器上局部镀覆层既满足钎焊性,同时又满足高温抗氧化性的功能要求,并顺利完成了钎焊和热试车.本研究成果已在多个结构复杂的换热器上得到推...     

片状Al及Al//Mg合金粉的制备及性能

针对金属/水推进剂对金属粉的要求,采用双向旋转球磨机制备了片状Al及Al/Mg合金粉.应用扫描电子显微镜(SEM)、X射线粉末衍射仪(XRD)、差示扫描量热仪(TG-DSC)、简易点火温度和水反应特性测试装置等手段分析了产物的形貌、结构及高温氧化过程、点火温度和水反应特性等.与球形Al对比结果表明,片状Al及Al/Mg合金粉总增重率大幅提高,初始放热峰温降低,活性增强,点火温度分别降低150℃和400 ℃以上.Al/Mg合金粉的水反应活性优于片状Al粉.     

盐雾腐蚀对NiCoCrAlY涂层性能的影响

利用中性盐雾试验对物理气相沉积制备的NiCoCrAlY防护涂层进行常温腐蚀,研究了常温盐雾腐蚀对NiCoCrAlY涂层的微观形貌以及高温性能的影响.试验结果表明:经过盐雾腐蚀的涂层表面的均匀性和完整性均被破坏,涂层表面产生了大量的腐蚀坑;高温循环氧化以后,表面形成的Al₂O₃氧化膜变得粗糙、破碎且不连续,而且氧化膜容易剥落,降低了涂层的高温抗氧化能力,缩短了涂层的使用寿命.      

Laser-induced oxidation assisted micro milling of high aspect ratio microgroove on WC-Co cemented carbide

Severe tool wear and poor surface quality are the main problems during micro machining of cemented carbide. In this work, an innovative hybrid process of laser-induced oxidation assisted micro milling (LOMM) was proposed to solve the problems. A nanosecond laser was utilized to induce oxidation of the WC-20%Co material, producing loose oxide which was easy to remove. The micro machinability of the material was improved by laser-induced oxidation. The oxidation mechanisms of cemented carbide were studied. A microgroove with a depth of 2.5 mm and aspect ratio of 5 was fabricated successfully. The milling force, surface quality and tool wear mechanisms were investigated. For comparison, a microgroove was also fabricated with conventional micro milling (COMM) using identical milling parameters. Results revealed that in LOMM the milling force and tool wear rate were extremely low during removing the oxide. The machined surface quality and dimensional accuracy achieved by LOMM were superior to those obtained by COMM. The surface roughness S_a of the microgroove bottom reached 88 nm in LOMM, while the cross-sectional geometry of the microgroove was a trapezoid. Perpendicularity of the microgroove sidewall machined by LOMM was better than that by COMM. The tool wear forms in LOMM were coating spalling and slight tool nose breakage. Compared with COMM, the tool life in LOMM was prolonged significantly. It indicates that the proposed hybrid process is an effective and efficient way to fabricate high aspect ratio micro-features with high dimensional accuracy.     

Fe^3＋／SO4^2-／TiO2光催化氧化苯酚研究

采用溶胶-凝胶法制备Fe^3＋／SO4^2-／TiO2光催化剂，以紫外光为光源，研究不同实验条件下对苯酚的光催化氧化。结果表明：催化剂投加量以2-3g／L为最佳范围；pH=6．7—9．0时苯酚去除率较高；溶液初始浓度越高。C0Dcr去除率越低；H2O2质量浓度为90mg/L时，光催化效果达到最佳；Cr^6＋浓度为8μg/mL时CODcr，去除率达到最大，Cr^6＋的还原率达90％以上；Hg^2＋对CDDcr去除率没有较大的影响，Hg^2＋的还原率99．5％。     

芬顿反应与TiO2光催化氧化甲基橙的研究

分别采用Fe^2＋及TiO2作为光催化剂，考察了它们对甲基橙的降解率。结果表明：在芬顿反应体系中加人NaOH时，可有效地阻止反应的进行；pH=4时，光催化氧化率最高；甲基橙溶液浓度越低，光催化氧化效果越好；改进后的光催化剂对甲基橙的分解率明显提高，不会生成草酸的铁盐沉淀；H2O2＋FeC2O4、H2O2＋FeSO4、TiO2三种体系的光催化性能大小依次为H2O2＋FeC2O4〉TiPO2〉H2O02＋FeSO4。     

Effects of Hybrid Voltages on Oxide Formation on 6061 Al-alloys During Plasma Electrolytic Oxidation

Plasma electrolytic oxidation (PEO) is carried out on 6061 Al-alloys in a weak alkaline electrolyte containing NaOH, Na₂SiO₃ and NaCl. Centered on the correlation of composition and structure, analyses by means of X-ray diffration (XRD), scanning electron microscope (SEM) and energy dispersive spectrometry (EDS) are conducted on the specimens, which have been PEO-treated under hybrid voltages of different direct current (DC) values (140-280 V) with constant alternate current (AC) amplitude (200 V). Attention is paid to the composition, properties and growth mechanism of oxide layers formed with hybrid voltages. Moreover, the main effects of DC value are discussed. Ceramic layers with a double-layer structure which combines hard outer and soft inner layers are found to be consist of α-Al₂O₃, γ-Al₂O₃ and mullite. With the DC values increasing, the growth of the ceramic layers tends to have increasingly obvious three-stage feature.     

电沉积烧结薄膜高温氧化性能研究

用电沉积烧结方法在１Ｃｒ１８Ｎｉ９Ｔｉ不锈钢表面形成铬、钇氧化物薄膜，通过研究比较不同沉积条件试样氧化层的高温氧化行为，发现１Ｃｒ１８Ｎｉ９Ｔｉ表面经铬、钇氧化物改性后抗高温氧化性能得到提高。     

脉冲频率对7050高强铝合金微弧氧化膜层的影响

在脉冲频率为50、250、500、750、1 000 Hz的条件下,应用微弧氧化（MAO）技术在7050高强铝合金表面制备了陶瓷膜层,并采用扫描电镜（SEM）、X射线衍射仪（XRD）、电化学工作站、摩擦磨损试验机等手段分别对陶瓷膜的表面形貌、相组成、耐腐蚀性、耐磨性等进行分析。结果表明,当脉冲频率过低时,MAO陶瓷膜层表面粗糙,影响膜层致密性;而当脉冲频率过高时,则不利于MAO陶瓷膜层生长,所得的膜层耐蚀性和耐磨性较差。当脉冲频率为250 Hz时,所制备的膜层具有最佳的耐磨性及耐蚀性。