新型碳化硅先驱体的制备及其性能研究

采用溶胶凝胶法，以正硅酸乙酯和酚醛树脂为原料，在草酸和六次甲基四胺的催化作用下，制备出了不含硫和氯等有害杂质的均相碳化硅先驱体，并在特定条件下，对所得先驱体进行烧结，使之转化为陶瓷。结果表明，溶胶凝胶法制得的先驱体呈黄色透明的玻璃态，其微观组成为几十纳米的微粒，树脂与SiO2可能通过氢键相互作用，有利于树脂在先驱体中均匀分布而形成均相先驱体，其陶瓷产率为78％；另外硝酸镍的加入对先驱体烧结过程中β-SiC的生成起到明显的促进作用。     

涂层刀具低温铣削SiCp/Al复合材料表面质量研究

在加工过程中,相反的两相特性增加了 SiCp/Al复合材料加工难度,难以获得良好的表面质量.为了提高其切削性能,本文开展20vol％SiCp/Al复合材料铣削加工试验研究,比较常温和低温条件下TiAlN涂层和TiAlSiN涂层两种铣刀的切削性能.结果表明,在低温条件下,两种刀具的切削力增加,铣削后表面铝基体的开裂及剥落...     

Elliptical vibration cutting of large-size thin-walled curved surface parts of pure iron by using diamond tool with active cutting edge shift

Large-size thin-walled curved surface parts of pure iron are crucial in aerospace, national defense, energy and precision physical experiments. However, the high machining accuracy and surface quality are difficult to achieve due to the serious tool wear and deformation when machining the parts with conventional cutting tools. In this paper, an elliptical vibration cutting (EVC) with active cutting edge shift (ACES) based on a long arbor vibration device is proposed for ultra-precision machining the pure iron parts by using diamond tool. Compared with cutting at a fixed cutting edge, the influence of ACES on the EVC was analyzed. Experiments in EVC of pure iron with ACES were conducted. The evolutions of the surface roughness, surface topography, and chip morphology with tool wear in EVC with ACES are revealed. The reasonable parameters of ultra-precision machining the pure iron parts by EVC with ACES were determined. It shows that the ACES has a slight influence on the machined surface roughness and surface topography. The diamond tool life can be significantly prolonged in EVC of pure iron with ACES than that with a fixed cutting edge, so that high profile accuracy and surface quality could be obtained even at higher nominal cutting speed. A typical thin-walled curved surface pure iron part with diameter ∅240 mm, height 122 mm, and wall thickness 2 mm was fabricated by the presented method, and its profile error and surface roughness achieved PV 2.2 μm and Ra less than 50 nm, respectively.     

超高温抗氧化碳陶复合材料研究进展

综述了国内外近年来陶瓷涂层抗氧化改性C/ C 复合材料和陶瓷基体抗氧化C/ C 复合材料研究

与应用的新进展, 主要包括1 800℃以下、1 800 ~2 200℃和2 200℃以上不同使用温度范围的抗氧化陶瓷涂层

以及SiC 陶瓷和超高温陶瓷基体改性复合材料。指出了目前高超声速飞行器2 200℃以上超高温抗氧化热防

护材料研究中存在的问题,提出了今后研究的方向。

     

熔融渗硅对不同类型C/C复合材料微观结构及性能的影响

选用了三种不同结构的C/C多孔体进行液硅熔渗,采用扫描电镜、X-射线衍射、微纳CT、压汞等方法表征了熔渗前后材料的微观形貌、物相组成及孔隙结构.结果 表明,熔渗后材料显气孔率均小于2％,实现了较好的致密化,C/C多孔体熔渗过程中可以采用高残碳树脂裂解形成的树脂碳或化学气相沉积形成的裂解碳进行保护,熔渗后其弯曲强度分别提...     

双氨源合成SiBN陶瓷前驱体及其裂解行为

以三氯化硼和甲基氢二氯硅烷为原料，通过与六甲基二硅氮烷和氨气的分步反应合成液态前驱体，在氨气中裂解脱碳得到SiBN陶瓷，改变投料比实现对前驱体陶瓷产率与元素组成的调控。采用NMR、FTIR、XRD、SEM、元素分析等方法对前驱体裂解过程及其不同温度陶瓷产物进行细致分析。结果表明，前驱体经过900 ℃氨气裂解完成陶瓷化过程，裂解产物中的硼含量超过13 %（w），经过1 400 ℃氮气或空气处理的陶瓷产物保持无定型态，具有良好的耐高温及抗氧化性。