聚合物基PTC材料稳定性的研究

提高导电复合材料的PTC(Positive Temperature Coefficient)强度和稳定室温电阻的重现性,是研究和使用聚合物基PTC材料所追求的目标.PTC材料经过在开关温度及其以上的较宽温度范围内重复热循环后,室温电阻升高,PTC强度降低.研究了辐射交联和在不同气氛中长时间热老化对聚合物基PTC复合材料的室温电阻、PTC强度、结晶度和开关温度等性能的影响.结果表明:辐射交联和氮气氛保护均有利于提高PTC材料的电性能稳定性,室温电阻和PTC强度的变化率相对较小.     

原位聚合法制备多壁碳纳米管-聚对苯撑苯并双噁唑纳米复合材料

采用强氧化性酸处理多壁碳纳米管(MWNTs),形成官能化的多壁碳纳米管(FMWNTs),用傅立叶红外光谱(FT-IR)、光电子能谱(XPS)对处理前后MWNTs的表面官能团进行了分析,并利用原位聚合法成功制备了FMWNTS-PBO纳米复合材料。结果表明,碳纳米管经过酸处理后,表面含有较多羰基和羟基的极性官能团,FMWNTs-PBO纤维的钩接强度比同条件下PBO纤维的钩接强度高出30%。文中给出了FMWNTs和PBO低聚物的聚合机理。     

碳化硅纤维增韧碳化硅陶瓷基复合材料的发展现状及其在航空发动机上的应用

碳化硅纤维增韧碳化硅陶瓷基复合材料(SiC/SiC CMC)具有低密度、高强高模、耐高温抗氧化、抗蠕变、抗热冲击、耐腐蚀、材料热膨胀系数小等性能优点,在航空发动机上具有巨大的应用潜力。从碳化硅纤维、制备工艺、界面相和涂层等方面综述了国内外SiC/SiC CMC的发展现状,并基于SiC/SiC CMC的性能特点对其在航空发动机燃烧室火焰筒、混合器、涡轮罩环/静子叶片/转子叶片、喷管调节片等热端部件上的应用情况进行了介绍。     

内绝热层材料结炭层强度的表征方法

利用改装的厚度计测试结炭层的针入深度,以此来表征材料结炭层的强度,分别考察了测试次数、圆锥针半顶角大小、测试区域和加载负荷对针入深度的影响,发现当测试次数为5次、圆锥针的半顶角为15°、测试区域为距烧蚀中心3 mm的圆形区域内、加载负荷为600~800 g时,所测针入深度数据分散性小、准确度高,能充分反映结炭层的强度。同时,结合不同芳纶用量时材料结炭层的针入深度和材料烧蚀速率分析,发现利用平均针入深度表征结炭层的强度,可科学地考察绝热层材料的耐烧蚀、抗冲蚀性能。     

高精度碳纤维复合材料反射面型面精度仿真分析

为全尺寸反射面的实际成型提供理论依据,本文通过建模仿真重点分析了外蒙皮装配偏差、自重及成型和使用温度差对反射面工作面型面精度（R. M. S）的影响。结果表明,当外蒙皮装配偏移量在0.5mm内时,其反射面工作面理论R. M. S值的变化量为0.47μm;在成型放置状态下,反射面11 kg自重其工作面理论R. M. S值变化量为0.55μm;反射面夹层结构的成型和使用温度差110℃,反射面工作面的理论R. M. S值变化量为17.79μm。     

碳/氰酸酯复合材料原子氧效应试验研究

选取具有良好应用前景的M40/DFA-1、M40/DFA-N3（添加TiO2纳米颗粒）碳纤维增强氰酸酯基复合材料为研究对象,开展航天器在轨原子氧环境地面模拟试验,通过表面/断口形貌观察、质量损失测试、层间剪切强度测试以及表面成分分析等方式,分析探讨了上述2种碳/氰酸酯基复合材料的原子氧损伤效应。结果表明,在原子氧的作用下,2种材料表面树脂均受到了一定程度的剥蚀,添加纳米颗粒的M40/DFA-N3质损率及原子氧剥蚀率相对更高,但层间剪切强度下降幅度相对较小,这可能是由于其氧化反应更加剧烈,生成的碳氧双键比例更高的结果。     

航空航天复合材料非热压罐成型研究进展

介绍了复合材料非热压罐成型的研究进展,包括非热罐成型用的树脂体系、预浸料技术、纤维自动铺放技术以及双真空袋成型工艺等,探讨了非热压罐技术的发展现状和前景。     

Thermal management for thermoset automated fiber placement based on infrared heater structure arrangement

Layup temperature is a vital factor that affects the production quality of automated fiber placement for thermoset composites. For high quality production, this paper proposes a new prediction model of layup temperature by considering the structure of infrared heater of automatic fiber placement equipment. The model was first verified by comparing with the temperature results of layup experiments. Then a prediction on the effects of heater structure arrangement on layup temperature was conducted...     

Tribological performance of hydrogenated diamond-like carbon coating deposited on superelastic 60NiTi alloy for aviation self-lubricating spherical plain bearings

It is imperative to develop a novel matching of metallic substrate and self-lubricating coating for aircraft spherical plain bearing in a wide range of service conditions. As a new type of superelastic material, 60NiTi alloy meets the performance requirements of aerospace bearing materials, but exhibits poor tribological performance, especially under the conditions of dry sliding friction. A Hydrogenated Diamond-Like Carbon (H-DLC) coating was deposited on the 60NiTi alloy to improve its tribological performance. The microstructure and mechanical behavior of the 60NiTi alloy and its H-DLC coating were explored. Results show that improvement of friction and wear performance of the H-DLC coating deposited on the 60NiTi substrate is mainly achieved by graphitization at the friction interface and the transfer film produced on the counterpart ball. The increased friction load leads to intensification of graphitization at the friction interface and formation of continuous and compact transfer film on the surface of the counterpart ball.     

Minimum quantity lubrication machining of aeronautical materials using carbon group nanolubricant: From mechanisms to application

It is an inevitable trend of sustainable manufacturing to replace flood and dry machining with minimum quantity lubrication(MQL) technology. Nevertheless, for aeronautical difficult-tomachine materials, MQL couldn’t meet the high demand of cooling and lubrication due to high heat generation during machining. Nano-biolubricants, especially non-toxic carbon group nano-enhancers(CGNs) are used, can solve this technical bottleneck. However, the machining mechanisms under lubrication of CGNs are uncl...